Synthesis, Electrochemistry, and Imido Transfer Reactions of (TTP)Ti( 2-PhN=NPh)Steven D. Gray, Joseph L. Thorman, Victor A. Adamian, Karl M. Kadish, and L. Keith Woo pp 1 - 4; DOI: 10.1021/ic970952e |
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Facile Syntheses of Titanium(II), Tin(II), and Vanadium(II) Porphyrin Complexes through Homogeneous Reduction. Reactivity of trans-(TTP)TiL2 (L = THF, t-BuNC) Xiaotai Wang, Steve D. Gray, Jinyuan Chen, and L. Keith Woo pp 5 - 9; DOI: 10.1021/ic970961n |
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Heterotrinuclear Oxo-Bridged FeIIIORuIVOFeIII Complexes of Ruthenium Porphyrin and Borylated Low-Spin Iron Dioximes Isak Vernik and Dennis V. Stynes pp 10 - 17; DOI: 10.1021/ic9710162 |
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Novel Rubredoxin Model Tetrathiolato Iron(II) and Cobalt(II) Complexes Containing Intramolecular Single and Double NH···S Hydrogen Bonds Taka-aki Okamura, Satoshi Takamizawa, Norikazu Ueyama, and Akira Nakamura pp 18 - 28; DOI: 10.1021/ic970640b |
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Ru(phen)2dppz2+ Luminescence: Dependence on DNA Sequences and Groove-Binding Agents R. Erik Holmlin, Eric D. A. Stemp, and Jacqueline K. Barton pp 29 - 34; DOI: 10.1021/ic970869r |
Ruthenium Complexes Containing "Noninnocent" o-Benzoquinone Diimine/o-Phenylenediamide(2-) Ligands. Synthesis and Crystal Structure of the Nitrido-Bridged Complex [{LRu(o-C6H4(NH)2)}2( -N)](PF6)2·3CH3CN·C6H5CH3Thomas Jüstel, Jesper Bendix, Nils Metzler-Nolte, Thomas Weyhermüller, Bernhard Nuber, and Karl Wieghardt pp 35 - 43; DOI: 10.1021/ic970850o |
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Role of o-Methylene-Bridged Bis(aniline) as a Spectroscopic Probe for the Metal Coordination Environment William Lesueur, Andrew J. Rogers, Carlo Floriani, Angiola Chiesi-Villa and, and Corrado Rizzoli pp 44 - 49; DOI: 10.1021/ic9706010 |
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Dinuclear (d3-d3) Diolate Complexes of Molybdenum and Tungsten. 3.1 Bridging and Chelating Isomers of M2(NMe2)2(O~~CHMe~~O)2, Where O~~CHMe~~O Is the Dianion of 2,2'-Ethylidenebis(4,6-di-tert-butylphenol). Kinetic versus Thermodynamic Considerations Malcolm H. Chisholm, Kirsten Folting, William E. Streib, and De-Dong Wu pp 50 - 55; DOI: 10.1021/ic9708430 |
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A Homologous Series of Homoleptic Zinc Bis(1,4-di-tert-butyl-1,4-diaza-1,3-butadiene) Complexes: Kx[Zn(t-BuNCHCHN-t-Bu)2], Zn(t-BuNCHCHN-t-Bu)2, and [Zn(t-BuNCHCHN-t-Bu)2](OTf)x (x = 1, 2) Evelien Rijnberg, Bodo Richter, Karl-H. Thiele, Jaap Boersma, Nora Veldman, Anthony L. Spek, and Gerard van Koten pp 56 - 63; DOI: 10.1021/ic970698q |
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Crystal Structure, Physical Properties, and Hydrolysis Kinetics of [(O)(tmpa)VIV(-O)VV(tmpa)(O)]3+ Robert A. Holwerda, Bruce R. Whittlesey, and Mark J. Nilges pp 64 - 68; DOI: 10.1021/ic970983+ |
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Synthesis, Potentiometry, and NMR Studies of Two New 1,7-Disubstituted Tetraazacyclododecanes and Their Complexes Formed with Lanthanide, Alkaline Earth Metal, Mn2+, and Zn2+ Ions Laszlo Burai, Jimin Ren, Zoltan Kovacs, Erno Brücher, and A. Dean Sherry pp 69 - 75; DOI: 10.1021/ic970599c |
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[pyH]2[Cu(py)4(MX6)2] (MX6 = ZrF62-, NbOF52-, MoO2F42-; py = Pyridine): Rarely Observed Ordering of Metal Oxide Fluoride Anions Kevin R. Heier, Alexander J. Norquist, Christopher G. Wilson, Charlotte L. Stern, and Kenneth R. Poeppelmeier pp 76 - 80; DOI: 10.1021/ic970951m |
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Synthesis and Characterization of Novel V/O/SO4 Chains Incorporating 2,2'-Bipyridine Ligands: Crystal Structure of [V2O2(OH)2(SO4)(2,2'-bpy)2] M. Ishaque Khan, Sabri Cevik, Douglas Powell, Sichu Li, and Charles J. O'Connor pp 81 - 86; DOI: 10.1021/ic970971o |
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Synthesis and Crystal Structure of a New Type of Ionic Technetium(V) Dioxo Phosphine Complexes, [Tc(O)2(PR3)3]+. Reactions with Pyridine and Crystal Structures of trans,cis,cis-[Tc(O)2(PR3)2(py)2]+ Compounds Fernande D. Rochon, Robert Melanson, and Pi-Chang Kong pp 87 - 92; DOI: 10.1021/ic970573l |
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Conformational Preference and Donor Atom Interaction Leading to Hexacoordination vs Pentacoordination in Bicyclic Tetraoxyphosphoranes David J. Sherlock, A. Chandrasekaran, T. K. Prakasha, Roberta O. Day, and Robert R. Holmes pp 93 - 101; DOI: 10.1021/ic9704391 |
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New Metallacarborane Chemistry: Molybdenum and Tungsten Carbonyl Multidecker Sandwiches. Cluster Dimers Linked via Metal-Metal Bonds Michael A. Curtis, Eric J. Houser, Michal Sabat, and Russell N. Grimes pp 102 - 111; DOI: 10.1021/ic971297d |
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Synthesis and Structure of a Zirconium Dinitrogen Complex with a Side-On Bridging N2 Unit Jonathan D. Cohen, Michael D. Fryzuk, Thomas M. Loehr, Murugesapillai Mylvaganam, and Steven J. Rettig pp 112 - 119; DOI: 10.1021/ic9709786 |
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Catalytic Generation of Oxalate through a Coupling Reaction of Two CO2 Molecules Activated on [(Ir(5-C5Me5))2(Ir(4-C5Me5)CH2CN)(3-S)2] Koji Tanaka, Yoshinori Kushi, Kiyoshi Tsuge, Kiyotsuna Toyohara, Takanori Nishioka, and Kiyoshi Isobe pp 120 - 126; DOI: 10.1021/ic9702328 |
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Synthesis, Characterization, and Reactivity of Dicationic Dihydrogen Complexes of Osmium and Ruthenium Thomas A. Luther and D. Michael Heinekey pp 127 - 132; DOI: 10.1021/ic970975t |
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Hexanuclear Mercury-Silver Complexes. Novel Coordination for Bridging Mesityl and Triflate Groups M. Laguna and, M. D. Villacampa, M. Contel, and J. Garrido pp 133 - 135; DOI: 10.1021/ic970699i |
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Identification of the Products of the Reaction between Sulfur and Sodium Carbonate N. Gobeltz, A. Demortier, J. P. Lelieur, and C. Duhayon pp 136 - 138; DOI: 10.1021/ic970962f |
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Synthesis and DNA-Binding Properties of [Ru(NH3)4dppz]2+ Rajesh B. Nair, Emily S. Teng, Shalawn L. Kirkland, and Catherine J. Murphy pp 139 - 141; DOI: 10.1021/ic970432j |
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Thermal Dehydrogenation of Oxovanadium(IV) Complexes with Schiff Base Ligands Derived from meso-1,2-Diphenyl-1,2-ethanediamine in the Solid State Gakuse Hoshina, Masanobu Tsuchimoto, Shigeru Ohba, Kiyohiko Nakajima, Hidehiro Uekusa, Yuji Ohashi, Hiroyuki Ishida, and Masaaki Kojima pp 142 - 145; DOI: 10.1021/ic9705958 |
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Isolation of [Be3(-OH)3(H2O)6]3+. Synthesis, 9Be NMR Spectroscopy, and Crystal Structure of [Be3(-OH)3(H2O)6](picrate)3·6H2O Franco Cecconi, Carlo A. Ghilardi, Stefano Midollini, Annabella Orlandini, and Alfredo Mederos pp 146 - 148; DOI: 10.1021/ic970969x |
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Chain Complexes of Rhodium(II) Pivalate Dimers Formed by Ligation of C=C Double Bond and Carbonyl Oxygen of p-Quinone [{Rh2(O2CCMe3)4(p-Q)2}{Rh2(O2CCMe3)4}]n, p-Q = 1,4-Benzoquinone and 1,4-Naphthoquinone Makoto Handa, Tadahiro Nakao, Masahiro Mikuriya, Takanori Kotera, Ryoji Nukada, and Kuninobu Kasuga pp 149 - 152; DOI: 10.1021/ic970246d |
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Homo- (4f, 4f) and Heterodimetallic (4f, 4f') Complexes. The First Structurally Characterized Example of a Heterodimetallic (Yb, La) Complex (1'). Magnetic Properties of 1' and of a Homodinuclear (Gd, Gd) Analogue J.-P. Costes, F. Dahan, A. Dupuis, S. Lagrave, and J.-P. Laurent pp 153 - 155; DOI: 10.1021/ic9712481 |
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Synthesis and Structure of the One-Dimensional Polymer Li(NHCH2CH2NH2) Glen R. Kowach, Christopher J. Warren, Robert C. Haushalter, and Francis J. DiSalvo pp 156 - 159; DOI: 10.1021/ic970778u |
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Assembly of Three WS3Cu2 Cluster Units by 3-S Bridges: Synthesis of [PPh4][{(C5Me5)WS3Cu2}3S2] Jian-Ping Lang and Kazuyuki Tatsumi pp 160 - 162; DOI: 10.1021/ic970894x |
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Redetermination of the Zigzag Modification of Plumbocene at 173 K Jason S. Overby, Timothy P. Hanusa, and Victor G. Young, Jr. pp 163 - 165; DOI: 10.1021/ic970980x |
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Hydrophobic, Highly Conductive Ambient-Temperature Molten Salts Pierre Bonhôte, Ana-Paula Dias, Michel Armand, Nicholas Papageorgiou, Kuppuswamy Kalyanasundaram, and Michael Grätzel pp 166 - 166; DOI: 10.1021/ic971286k |
Issue 2
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Preparation, Spectroscopic Characterization, and Molecular Structure of Copper(I) Aliphatic Thiolate Complexes Kiyoshi Fujisawa, Sadako Imai, Nobumasa Kitajima, and Yoshihiko Moro-oka pp 168 - 169; DOI: 10.1021/ic971317b |
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Mixed Carboxylate/Catecholate Bridged Polynuclear Complexes. Tetranuclear Linear Arrays and Pentanuclear Clusters with [M4M'O8]3+ Cores (M = Fe2+, Mn+2; M' = Fe3+, Mn+3). Rare Examples of Dodecahedrally Coordinated, First Row, Trivalent Metal Ions R. A. Reynolds, III and D. Coucouvanis pp 170 - 171; DOI: 10.1021/ic971081b |
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A New Class of Carborane Compounds for Second-Order Nonlinear Optics: Ab Initio Molecular Orbital Study of Hyperpolarizabilities for 1-(1',X'-Dicarba-closo-dodecaborane-1'-yl)-closo-dodecaborate Dianion (X = 2, 7, 12) Jiro Abe, Nobukatsu Nemoto, Yu Nagase, Yasuo Shirai, and Tomokazu Iyoda pp 172 - 173; DOI: 10.1021/ic970809l |
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Gold Clustering at Hydroxylamine Upendra M. Tripathi, Wolfgang Scherer, Annette Schier, and Hubert Schmidbaur pp 174 - 175; DOI: 10.1021/ic9714448 |
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Substrate Oxidation in the Active Site of Xanthine Oxidase and Related Enzymes. A Model Density Functional Study Alexander A. Voityuk, Katrin Albert, Maria J. Romão, Robert Huber, and Notker Rösch pp 176 - 180; DOI: 10.1021/ic9707570 |
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Coordination Chemistry of Iron Porphycenes in the Presence of CO, CO2, and N-Methylimidazole: Electrochemical, ESR, and UV-Vis Study C. Bernard, Y. Le Mest, and J. P. Gisselbrecht pp 181 - 190; DOI: 10.1021/ic970472n |
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Spectroscopic Characterization of an Engineered Purple CuA Center in Azurin Michael T. Hay, Marjorie C. Ang, Daniel R. Gamelin, Edward I. Solomon, William E. Antholine, Martina Ralle, Ninian J. Blackburn, Priscilla D. Massey, Xiaotang Wang, Angela H. Kwon, and Yi Lu pp 191 - 198; DOI: 10.1021/ic971232a |
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Coordination of Zn(II), Cd(II), Hg(II), and Ag(I) by Bis(benzimidazole) Ligands Craig J. Matthews, William Clegg, Sarah L. Heath, Nicola C. Martin, M. N. Stuart Hill, and Joyce C. Lockhart pp 199 - 207; DOI: 10.1021/ic970381q |
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Synthesis, Characterization, and Protonation of an Amide-Containing Thiolate Complex of a Ruthenium Nitrosyl Porphyrin Geun-Bae Yi, Masood A. Khan, Douglas R. Powell, and George B. Richter-Addo pp 208 - 214; DOI: 10.1021/ic970957b |
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Iron(II) Polyamine Chemistry: Variation of Spin State and Coordination Number in Solid State and Solution with Iron(II) Tris(2-pyridylmethyl)amine Complexes Alain Diebold and Karl S. Hagen pp 215 - 223; DOI: 10.1021/ic971105e |
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Group 2 Complexes of 2,4,6-Trimercaptotriazine (TMT) Kevin Henke and David A. Atwood pp 224 - 227; DOI: 10.1021/ic970954z |
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A Novel Polymer of a Binuclear Nickel(II) Complex Bridged By 1,3-Diaminopropane: Structure and Magnetism Anbanandam Asokan, Babu Varghese, Andrea Caneschi, and Periakaruppan T. Manoharan pp 228 - 232; DOI: 10.1021/ic9711675 |
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Synthesis and Magnetic Properties of Four New (Cu-Ni)2 Tetranuclear Complexes of General Formula [Cu(oxpn)Ni(-NCS)(H2O)(aa)]2(X)2 (oxpn = N,N'-Bis(3-aminopropyl)oxamide; aa = Bidentate Amine; X = ClO4- or PF6-). Ferro- and Antiferromagnetic Alternation Joan Ribas, Carmen Diaz, Ramon Costa, Javier Tercero, Xavier Solans, Mercé Font-Bardía, and Helen Stoeckli-Evans pp 233 - 239; DOI: 10.1021/ic970899u |
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Comparative Crystallography. 5. Crystal Structures, Electronic Properties, and Structural Pathways of Five [Cu(phen)2Br][Y] Complexes, Y = [Br]-·H2O, [ClO4]-, [NO3]-·H2O, [PF6]-, and [BPh4]- Gillian Murphy, Cathal O'Sullivan, Brian Murphy, and Brian Hathaway pp 240 - 248; DOI: 10.1021/ic970458a |
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Synthesis and Crystal Structure of the Linear Chain Zirconium Organophosphonate (NH4)Zr[F2][H3{O3PCH2NH(CH2CO2)2}2]·3H2O·NH4Cl Baolong Zhang, Damodara M. Poojary, and Abraham Clearfield pp 249 - 254; DOI: 10.1021/ic970865m |
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Assembling Bi-, Tri- and Pentanuclear Complexes into Extended Structures Using a Desolvation Reaction: Synthesis, Structure, and Magnetic Properties of Manganese(III)-Schiff-Base-Hexacyanoferrate Polymeric Compounds and Their Derived Extended Structures Hitoshi Miyasaka, Hidenori Ieda, Naohide Matsumoto, Nazzareno Re, Raffaella Crescenzi, and Carlo Floriani pp 255 - 263; DOI: 10.1021/ic9709640 |
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X-ray Diffraction, EPR, and 6Li and 27Al MAS NMR Study of LiAlO2-LiCoO2 Solid Solutions R. Alcántara, P. Lavela, P. L. Relaño, J. L. Tirado, E. Zhecheva, and R. Stoyanova pp 264 - 269; DOI: 10.1021/ic9707220 |
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Synthesis, X-ray Structures, and Spectroscopic and Electrochemical Properties of (-Oxo)bis(-carboxylato)diruthenium Complexes Having Six Imidazole Bases as Terminal Ligands Chellamma Sudha, Sisir K. Mandal, and Akhil R. Chakravarty pp 270 - 278; DOI: 10.1021/ic970390z |
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Metal-Hydride and Hydride-Hydride Distances from Measurements of Selective and Nonselective 1H T1 Relaxation Times of Hydride Ligands: Relaxation in NbCp2H3 Vladimir I. Bakhmutov, Evgenii V. Vorontsov, Georgii I. Nikonov, and Dmitry A. Lemenovskii pp 279 - 282; DOI: 10.1021/ic970445x |
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Sodium and Potassium Triisopropylbenzenethiolates: Influence on Solid-State Structure by Metal and Donor Ulrich Englich, Scott Chadwick, and Karin Ruhlandt-Senge pp 283 - 293; DOI: 10.1021/ic970769l |
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CO2-Catalyzed One-Electron Oxidations by Peroxynitrite: Properties of the Reactive Intermediate Sergei V. Lymar and and James K. Hurst pp 294 - 301; DOI: 10.1021/ic970946i |
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Synthesis, Structures, and Electrochemical Properties of Nickel Complexes of Macrocyclic N2S2 Aminothioethers Ghezai Musie, Joseph H. Reibenspies, and Marcetta Y. Darensbourg pp 302 - 310; DOI: 10.1021/ic970526t |
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Spectroelectrochemical Characterization of the Two-Step Redox System {(-pz)[Os(CN)5]2}n- (n = 4, 5, 6; pz = Pyrazine). Similarities and Differences in Relation to the Creutz-Taube System Fridmann M. Hornung, Frank Baumann, Wolfgang Kaim, José A. Olabe, Leonardo D. Slep, and Jan Fiedler pp 311 - 316; DOI: 10.1021/ic970804o |
Electrochemical Reduction of Cobaltocenium in the Presence of  -CyclodextrinYun Wang, Sandra Mendoza, and Angel E. Kaifer pp 317 - 320; DOI: 10.1021/ic970702y |
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Synthesis and Characterization of [NH2C(I)=NH2]2ASnI5 with A = Iodoformamidinium or Formamidinium: The Chemistry of Cyanamide and Tin(II) Iodide in Concentrated Aqueous Hydriodic Acid Solutions David B. Mitzi, Kangning Liang, and Shumin Wang pp 321 - 327; DOI: 10.1021/ic971332g |
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Ligand Substitution Reactions of [Re6S8Br6]4-: A Basis Set of Re6S8 Clusters for Building Multicluster Assemblies Michael W. Willer, Jeffrey R. Long, Craig C. McLauchlan, and R. H. Holm pp 328 - 333; DOI: 10.1021/ic970926g |
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Multifaceted Reactions of P(CH2OH)3 with Rhenium(V) Precursors. Synthesis, Characterization, and X-ray Structural Studies of trans,trans,trans-[ReO2{P(CH2OH)3}2- (py)2]Cl, trans,cis,cis-[ReO2{P(CH2OH)3}2(py)2]Cl, and Novel Alkoxide [Re(O)(-O)- (P{CH2OH}3)(-2-P{CH2OH}2CH2O)]4 Douglas E. Berning, Kattesh V. Katti, Leonard J. Barbour, and Wynn A. Volkert pp 334 - 339; DOI: 10.1021/ic970828v |
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Lewis-Acid Properties of Technetium(VII) Dioxide Trifluoride, TcO2F3: Characterization by 19F, 17O, and 99Tc NMR Spectroscopy and Raman Spectroscopy, Density Functional Theory Calculations of TcO2F3, M+TcO2F4- [M = Li, Cs, N(CH3)4], and TcO2F3·CH3CN, and X-ray Crystal Structure of Li+TcO2F4- William J. Casteel Jr., David A. Dixon, Nicolas LeBlond, Hélène P. A. Mercier, and Gary J. Schrobilgen pp 340 - 353; DOI: 10.1021/ic9708935 |
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Chalcogen Diimides: Relative Stabilities of Monomeric and Dimeric Structures, [E(NMe)2]n (E = S, Se, Te; n = 1, 2) Nicole Sandblom, Tom Ziegler, and Tristram Chivers pp 354 - 359; DOI: 10.1021/ic970680f |
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Effect of Pressure on the Reversible Binding of Acetonitrile to the "Co(I)-CO2" Adduct To Form Cobalt(III) Carboxylate Etsuko Fujita and and Rudi van Eldik pp 360 - 362; DOI: 10.1021/ic971044k |
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Hexahydro-closo-hexaborate as a Ligand in Coordination Compounds: Synthesis and Crystal Structure of (n-Bu4N)2[Cd(3-B6H6)2]·2CH2Cl2 Tanja Schaper and Wilhelm Preetz pp 363 - 365; DOI: 10.1021/ic971039g |
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Conformational Analysis of Cobalt(III), Copper(II), and Nickel(II) Six-Membered-Ring Systems M. Fatima DaCruz and Marc Zimmer pp 366 - 368; DOI: 10.1021/ic970993a |
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Composition Space of the (CdO, 0.5Nb2O5)/(HF)x·Pyridine/H2O System. Structure and Synthesis of CdNb(py)4OF5 P. Shiv Halasymani, Kevin R. Heier, Alexander J. Norquist, Charlotte L. Stern, and Kenneth R. Poeppelmeier pp 369 - 371; DOI: 10.1021/ic971224u |
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Structural Characterization of Dirhenium(II) Complexes of the Type Re2Cl4(-PP)(PR3)2, Where PP Represents a Bridging Phosphine of the Type R2PCH2PR2 or R2PNHPR2 F. Albert Cotton and, Alexandre Yokochi, Michael J. Siwajek, and Richard A. Walton pp 372 - 375; DOI: 10.1021/ic971078s |
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Absence of Hydronium Ion Formation in a Ternary Crown Ether·Mineral Acid·Water Complex: X-ray Crystal Structure of 1,8-Oxybis(ethyleneoxyethyleneoxy)anthracene-9,10-dione·HNO3·3H2O Victor G. Young, Jr. and and Andrew G. Sykes pp 376 - 378; DOI: 10.1021/ic970839o |
Issue 3
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NaZr6Cl10.94I3.06B: A Second Structure Type in the Zr6X14Z-Family of Reduced Zirconium Halides. Perspectives for an Even Larger Cluster Chemistry Martin Köckerling pp 380 - 381; DOI: 10.1021/ic971009d |
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Tilt/Asymmetry in Nitrosyl Metalloporphyrin Complexes: The Cobalt Case Mary K. Ellison and W. Robert Scheidt pp 382 - 383; DOI: 10.1021/ic971109j |
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A Chiral N-Sulfonylphosphoramide: Synthesis and X-ray Crystal Structure of a 1,3,2-Oxazaphospholidin-5-one, a Trivalent Electron-Withdrawing Amino Acid-Derived Phosphorus Compound, and Synthesis of Its W(CO)5 Adduct William H. Hersh, Ping Xu, Cheslan K. Simpson, Thomas Wood, and Arnold L. Rheingold pp 384 - 385; DOI: 10.1021/ic9713801 |
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Equiatomic Quaternary Rare Earth Element Zinc Pnictide Oxides RZnPO and RZnAsO André T. Nientiedt and and Wolfgang Jeitschko pp 386 - 389; DOI: 10.1021/ic971058q |
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New Layered Zirconium Tellurides: Zr0.30ZrTe2, Zr0.29Zr2Te2As, and NaZr2Te2As Chwanchin Wang, Cahit Eylem, and Timothy Hughbanks pp 390 - 397; DOI: 10.1021/ic9709077 |
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Molecular Shapes, Orientation, and Packing of Polyoxometalate Arrays Imaged by Scanning Tunneling Microscopy Mahmoud S. Kaba, In K. Song, Dean C. Duncan, Craig L. Hill, and Mark A. Barteau pp 398 - 406; DOI: 10.1021/ic9705655 |
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Pressure-Induced Changes in the Structure and Band Gap of CsGeX3 (X = Cl, Br) Studied by Electronic Band Structure Calculations D.-K. Seo, N. Gupta, M.-H. Whangbo, H. Hillebrecht, and G. Thiele pp 407 - 410; DOI: 10.1021/ic970659e |
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Structure, Electrochemistry, and Properties of Bis(ferrocenecarboxylato)(phthalocyaninato)silicon(IV) and Its Implications for (Si(Pc)O)n Polymer Chemistry Jack Silver, Jose L. Sosa-Sanchez, and Christopher S. Frampton pp 411 - 417; DOI: 10.1021/ic970934x |
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Adducts of Titanium Tetrachloride with Alkylselenium Compounds: Molecular Precursors to Titanium Diselenide Films Peggy J. McKarns, T. Suren Lewkebandara, Glenn P. A. Yap, Louise M. Liable-Sands, Arnold L. Rheingold, and Charles H. Winter pp 418 - 424; DOI: 10.1021/ic970945q |
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Chemical and Electrochemical Studies of Cl2FeS2MS2FeCl2n- Clusters [M = Mo (n = 2), W (n = 2), V (n = 3)] Yanming Liu, Jinhai Chen, and Michael D. Ryan pp 425 - 431; DOI: 10.1021/ic9603114 |
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Tridentate Ligand Effects on Enthalpies of Protonation of (L3)M(CO)3 Complexes (M = W, Mo) Oltea P. Siclovan and Robert J. Angelici pp 432 - 444; DOI: 10.1021/ic970670e |
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Synthesis and Characterization of Rhenium(VI) cis-Dioxo Complexes and Examination of Their Redox Chemistry Darin D. DuMez and James M. Mayer pp 445 - 453; DOI: 10.1021/ic9710317 |
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Spectroscopy of Hydrothermal Reactions. 8. Kinetics of Aqueous NH4XCN (X = O, S) and OCS by Flow Reactor-Infrared Spectroscopy P. G. Maiella and T. B. Brill pp 454 - 458; DOI: 10.1021/ic970723s |
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Structure-Reactivity Relationships for Associative Displacement Reactions of Penta- and Hexacoordinate Cyclic Oxyphosphoranes with Catechols A. Chandrasekaran, Paul Sood, and Robert R. Holmes pp 459 - 466; DOI: 10.1021/ic970919s |
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Kinetics and Mechanism of the Dihydroxylation and Epoxidation of Conjugated Dienes with Hydrogen Peroxide Catalyzed by Methylrhenium Trioxide Haisong Tan and James H. Espenson pp 467 - 472; DOI: 10.1021/ic971073v |
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Gallophosphonates Containing Alkali Metal Ions. 2.1 Synthesis and Structure of Gallophosphonates Incorporating Na+ and K+ Ions Mrinalini G. Walawalkar, Ramaswamy Murugavel, Herbert W. Roesky, Isabel Usón, and Ralph Kraetzner pp 473 - 478; DOI: 10.1021/ic971441v |
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Mono- and Bis(hydrazine) Complexes of Osmium(II): Synthesis, Reactions, and X-ray Crystal Structure of the [Os(NH2NH2)2{P(OEt)3}4](BPh4)2 Derivative Gabriele Albertin, Stefano Antoniutti, Alessia Bacchi, Massimo Bergamo, Emilio Bordignon, and Giancarlo Pelizzi pp 479 - 489; DOI: 10.1021/ic970463e |
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Formation of Cage Compounds Containing Boron, Phosphorus, and Transition Metal Atoms Tuqiang Chen, Eileen N. Duesler, Robert T. Paine, and Heinrich Nöth pp 490 - 495; DOI: 10.1021/ic970965s |
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Cyclic Hydroborate Complexes of Metallocenes II: Reactivity of (-H)2(BC5H10)2 and Its Cyclic Derivative, [H2BC5H10]-; Synthesis of (5-C5H5)2MCl(-H)2BC5H10 (M = Zr, Hf) Jianping Liu, Edward A. Meyers, and Sheldon G. Shore pp 496 - 502; DOI: 10.1021/ic971275r |
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Monoalkyldecaborane(14) Syntheses via Nucleophilic Alkylation and Hydroboration Adam N. Bridges, Douglas R. Powell, Joel A. Dopke, John M. Desper, and Donald F. Gaines pp 503 - 509; DOI: 10.1021/ic971149n |
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Binary Si/N-[4.4]-Spirocycles with Two SiH2SiH2 Loops Marcus Söldner, Annette Schier, and Hubert Schmidbaur pp 510 - 515; DOI: 10.1021/ic9711022 |
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Structural and Magnetochemical Properties of Mono-, Di-, and Trinuclear Manganese(III) Dithiolate Complexes Jeffrey L. Seela, Michael J. Knapp, Kevin S. Kolack, Hsiu-Rong Chang, John C. Huffman, David N. Hendrickson, and George Christou pp 516 - 525; DOI: 10.1021/ic970587r |
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A Cobalt(III) Chiroporphyrin and Its Amine Adducts. A Potential Chiral NMR Shift Reagent for Amines Dawn Toronto, Françoise Sarrazin, Jacques Pécaut, Jean-Claude Marchon, Maoyu Shang, and W. Robert Scheidt pp 526 - 532; DOI: 10.1021/ic970995v |
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Nitrosylation of Octaethylporphyrin Osmium Complexes with Alkyl Nitrites and Thionitrites: Molecular Structures of Three Osmium Porphyrin Derivatives Li Chen, Masood A. Khan, and George B. Richter-Addo pp 533 - 540; DOI: 10.1021/ic9708576 |
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Supramolecular Multiporphyrin Architecture. Coordination Polymers and Open Networks in Crystals of Tetrakis(4-cyanophenyl)- and Tetrakis(4-nitrophenyl)metalloporphyrin R. Krishna Kumar, S. Balasubramanian, and Israel Goldberg pp 541 - 552; DOI: 10.1021/ic971259u |
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Tyrosinase Models. Synthesis, Structure, Catechol Oxidase Activity, and Phenol Monooxygenase Activity of a Dinuclear Copper Complex Derived from a Triamino Pentabenzimidazole Ligand Enrico Monzani, Luisa Quinti, Angelo Perotti, Luigi Casella, Michele Gullotti, Lucio Randaccio, Silvano Geremia, Giorgio Nardin, Paolo Faleschini, and Giovanni Tabbì pp 553 - 562; DOI: 10.1021/ic970996n |
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Noncovalent Interactions of Platinum(II) Square Planar Complexes Containing Ligands Out-of-Plane with DNA Matteo Cusumano, Maria Letizia Di Pietro, Antonino Giannetto, Francesco Nicolò, and Enrico Rotondo pp 563 - 568; DOI: 10.1021/ic9705406 |
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From the Single- to the Triple-Decker Sandwich. Effect of Stacking on the Redox and UV-Visible Spectroscopic Properties of Lutetium(III) 1,2-Naphthalocyaninate Complexes François Guyon, Annig Pondaven, Jean-Michel Kerbaol, and Maurice L'Her pp 569 - 576; DOI: 10.1021/ic9612111 |
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Self-Assembled Dinuclear Lanthanide Helicates: Substantial Luminescence Enhancement upon Replacing Terminal Benzimidazole Groups by Carboxamide Binding Units Noreen Martin, Jean-Claude G. Bünzli, Vickie McKee, Claude Piguet, and Gérard Hopfgartner pp 577 - 589; DOI: 10.1021/ic971401r |
Acylimido Complexes of Tungsten(IV) Formed by Oxygen Atom Transfer to Nitrile- 2N,C ComplexesSimon Thomas, Patrick J. Lim, Robert W. Gable, and Charles G. Young pp 590 - 593; DOI: 10.1021/ic9709178 |
Binuclear Aroyl and Carbamoyl Complexes of Iron: X-ray Crystal Structures of [Fe2(: ,'-OCR)2(CO)5(PPh3)] (R = C6H3Me2-2,6, NiPr2)Stephen Anderson, Anthony F. Hill, Alexandra M. Z. Slawin, Andrew J. P. White, and David J. Williams pp 594 - 597; DOI: 10.1021/ic970700d |
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A Thioketene Complex of Molybdenum(IV): Crystal Structure of [Mo{2-(C,S),-(S')- S=C=CRC(=O)S}(=O){HB(pz)3}] (R = C6H4Me-4, pz = Pyrazol-1-yl) Anthony F. Hill, John M. Malget, Andrew J. P. White, and David J. Williams pp 598 - 600; DOI: 10.1021/ic970712z |
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Isomeric Cyclic Disilanediyl Dimethylhydrazines Marcus Söldner, Jürgen Riede, Annette Schier, and Hubert Schmidbaur pp 601 - 603; DOI: 10.1021/ic9709638 |
Systematic Electrochemical Synthesis of Reduced Forms of the  -[S2Mo18O62]4- AnionDavid M. Way, John B. Cooper, Maruse Sadek, Truc Vu, Peter J. Mahon, Alan M. Bond, Robert T. C. Brownlee, and Anthony G. Wedd pp 604 - 604; DOI: 10.1021/ic9714192 |
Issue 4
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Water-Soluble Iron Porphyrin Complex-Catalyzed Epoxidation of Olefins with Hydrogen Peroxide and tert-Butyl Hydroperoxide in Aqueous Solution Sook Jung Yang and Wonwoo Nam pp 606 - 607; DOI: 10.1021/ic9710519 |
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Synthesis and Structure of {5-C5H5Cr}2{-6:6-(-1,2-C3H6-1,2-C2B4H4)}. An Unusual 24-Electron Triple-Decker Sandwich Complex Containing a Metal-Stabilized, Planar Tetraborabenzene Kazumori Kawamura, Maoyu Shang, Olaf Wiest, and Thomas P. Fehlner pp 608 - 609; DOI: 10.1021/ic9712784 |
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Novel Double-Stranded Chains vs Two-Layer Interwoven Sheets. Subtle Coligand Effects and Related Properties for [Co(Py2S)2X2]n (Py2S = 4,4'-Dipyridyl Sulfide; X = NCS, Cl) Ok-Sang Jung, Sung Ho Park, Dong Chan Kim, and Kwan Mook Kim pp 610 - 611; DOI: 10.1021/ic971415x |
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Iron(II) Complexes Containing the 1,2-Diphospholanoethane Ligand Leslie D. Field, Iain P. Thomas, Trevor W. Hambley, and Peter Turner pp 612 - 618; DOI: 10.1021/ic9701928 |
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Monomeric and Dimeric Tetrahydrofuran Complexes of Barium Bis[bis(dimethyl-tert-butylsilyl)arsanide] Matthias Westerhausen, Matthias H. Digeser, Jörg Knizek, and Wolfgang Schwarz pp 619 - 623; DOI: 10.1021/ic9710770 |
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Cationic Gold(I) Complexes of Xenon and of Ligands Containing the Donor Atoms Oxygen, Nitrogen, Phosphorus, and Sulfur Detlef Schröder, Helmut Schwarz, Jan Hru  ák, and Pekka Pyykköpp 624 - 632; DOI: 10.1021/ic970986m |
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Hemilabile Properties of the 3-Allyldiphenylphosphine (ADPP) Homophosphaallyl Ligand: Synthesis and Reactions of [(5-C5Me5)Ru(3-ADPP)(1-ADPP)][PF6] Luis P. Barthel-Rosa, Kalyani Maitra, and John H. Nelson pp 633 - 639; DOI: 10.1021/ic970634f |
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Influence of Hydrogen Bonding on the Spectroscopic Properties and on the Reactivity of Ruthenium Hydrido Dihydrogen Complexes Yannick Guari, José A. Ayllon, Sylviane Sabo-Etienne, Bruno Chaudret, and Bart Hessen pp 640 - 644; DOI: 10.1021/ic970872a |
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Isolation of Geometric Isomers within Diastereoisomers of Dinuclear Ligand-Bridged Complexes of Ruthenium(II) Bradley T. Patterson and F. Richard Keene pp 645 - 650; DOI: 10.1021/ic971080j |
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Crystal Structure of [Cu4(tu)7](SO4)2]·H2O and Vibrational Spectroscopic Studies of Some Copper(I) Thiourea Complexes Raymond C. Bott, Graham A. Bowmaker, Carol A. Davis, Gregory A. Hope, and Brian E. Jones pp 651 - 657; DOI: 10.1021/ic970910q |
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Spectroelectrochemistry of the Multistep Redox System {(-bpym)[Ru(NH3)4]2}n+, n = 2-6, in a Nonaqueous Medium Frank Baumann, Wolfgang Kaim, Mónica García Posse and, and Néstor E. Katz pp 658 - 660; DOI: 10.1021/ic971143y |
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Photochemistry of the Triangular Clusters Os3(CO)10(-diimine): Homolysis of an Os-Os Bond and Solvent-Dependent Formation of Biradicals and Zwitterions Jos Nijhoff, Maarten J. Bakker, Franti ek Hartl, Derk J. Stufkens, Wen-Fu Fu, and Rudi van Eldikpp 661 - 668; DOI: 10.1021/ic9707319 |
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Substituent Effects on the Spectroscopic Properties and Reactivity of Hexacoordinate Silicon(IV) Porphyrin Complexes Kevin M. Kane, Carrie R. Lorenz, David M. Heilman, and Frederick R. Lemke pp 669 - 673; DOI: 10.1021/ic9710925 |
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Theoretical Study of the Geometric and Electronic Structures and Spectra of trans-ME2(PH3)4 Complexes (M = Mo, W; E = S, Se, Te) Woo-Sung Kim and Nikolas Kaltsoyannis pp 674 - 678; DOI: 10.1021/ic9706515 |
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Magnetic Properties of the Two-Dimensional Bimetallic Compounds (NBu4)[MIIRuIII(ox)3] (NBu4 = Tetra-n-butylammonium; M = Mn, Fe, Cu; ox = Oxalate) Joulia Larionova, Bruno Mombelli, Joaquín Sanchiz, and Olivier Kahn pp 679 - 684; DOI: 10.1021/ic970531x |
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Copper Complexes Bearing Pendant, Protonatable Noncoordinating Groups: Synthesis, Characterization, and Protonation Chemistry Nydia D. Villanueva, Michael Y. Chiang, and Jeffrey R. Bocarsly pp 685 - 692; DOI: 10.1021/ic9703843 |
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Spectroscopic and Voltammetric Studies on Copper Complexes of 2,9-Dimethyl-1,10-phenanthrolines Bound to Calf Thymus DNA Sethuraman Mahadevan and Mallayan Palaniandavar pp 693 - 700; DOI: 10.1021/ic961066r |
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Ruthenium(II) Complexes with NS2 Pyridine-Based Dithia-Containing Ligands. Proposed Possible Structural Isomers and X-ray Confirmation of Their Existence Clara Viñas, Pilar Anglès, Glòria Sánchez, Natividad Lucena, Francesc Teixidor, Lluís Escriche, Jaume Casabó, Joan F. Piniella, Angel Alvarez-Larena, Raikko Kivekäs, and Reijo Sillanpää pp 701 - 707; DOI: 10.1021/ic970829n |
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Modification of Platinum(II) Antitumor Complexes with Sulfur Ligands. 1. Synthesis, Structure, and Spectroscopic Properties of Cationic Complexes of the Types [PtCl(diamine)(L)]NO3 and [{PtCl(diamine)}2(L-L)](NO3)2 (L = Monofunctional Thiourea Derivative; L-L = Bifunctional Thiourea Derivative) Ulrich Bierbach, Trevor W. Hambley, and Nicholas Farrell pp 708 - 716; DOI: 10.1021/ic970420y |
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Modification of Platinum(II) Antitumor Complexes with Sulfur Ligands. 2. Reactivity and Nucleotide Binding Properties of Cationic Complexes of the Types [PtCl(diamine)(L)]NO3 and [{PtCl(diamine)}2(L-L)](NO3)2 (L = Monofunctional Thiourea Derivative; L-L = Bifunctional Thiourea Derivative) in Relation to Their Cytotoxicity Ulrich Bierbach, John D. Roberts, and Nicholas Farrell pp 717 - 723; DOI: 10.1021/ic970421q |
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Stabilization of the Less Common (dxzdyz)4(dxy)1 Iron(III) Porphyrin Ground Electronic State: 1H NMR Investigations of Iron(III) 5,10,15,20-Tetracyclohexylporphyrin Stanis  aw Woowiec, Lechosaw Latos-Gra y ski, Dawn Toronto, and Jean-Claude Marchonpp 724 - 732; DOI: 10.1021/ic9707927 |
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Electronic Effects in Transition Metal Porphyrins. 9. Effect of Phenyl Ortho Substituents on the Spectroscopic and Redox Properties and Axial Ligand Binding Constants of Iron(III) Tetraphenylporphyrinates Richard Koerner, Joshua L. Wright, Xiao Dong Ding, Marlys J. M. Nesset, Kate Aubrecht, Reneé A. Watson, R. Andrew Barber, Larry M. Mink, Alicia Rene Tipton, Cynthia J. Norvell, Ken Skidmore, Ursula Simonis, and F. Ann Walker pp 733 - 745; DOI: 10.1021/ic970989z |
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Unusual Nitrite Complexes of Iron(III) and Iron(II) Stabilized by the Tris(3,5-dimethylpyrazolyl)borate Ligand Navamoney Arulsamy, D. Scott Bohle, Bernhard Hansert, Annie K. Powell, Andrew J. Thomson, and Sigrid Wocaldo pp 746 - 750; DOI: 10.1021/ic9709537 |
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Unusual Catalyst Concentration Effects in the Hydrolysis of Phenyl Phosphate Esters and of DNA: A Systematic Investigation of the Lanthanide Series Anne Roigk, Ronald Hettich, and Hans-Jörg Schneider pp 751 - 756; DOI: 10.1021/ic970297a |
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Design, Syntheses and Application of New Phosphine and Dithiophosphinate Complexes of Nickel: Catalyst Precursors for the Oligomerization of Ethylene Ronald G. Cavell, Beth Creed, Lucio Gelmini, David J. Law, Robert McDonald, Alan R. Sanger, and Arpad Somogyvari pp 757 - 763; DOI: 10.1021/ic970798w |
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Hydrolysis of Zirconium and Hafnium Siloxide Complexes. Isolation and Characterization of the Intermediate Aqua Complexes M[OSi(OtBu)3]4(H2O)n (M = Zr, Hf; n = 1, 2) Claus G. Lugmair and T. Don Tilley pp 764 - 769; DOI: 10.1021/ic971211g |
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Organosamarium-Mediated Transformations of CO2 and COS: Monoinsertion and Disproportionation Reactions and the Reductive Coupling of CO2 to [O2CCO2]2- William J. Evans, Christopher A. Seibel, and Joseph W. Ziller pp 770 - 776; DOI: 10.1021/ic971381t |
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Synthesis and Structure of CsNaLa6Br14N2 and La3Br6N: Rare-Earth-Metal Nitride Halides with Isolated Bitetrahedral La6N2 Units Michael Lulei pp 777 - 781; DOI: 10.1021/ic9711269 |
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Antiferromagnetic Alternating and Homogeneous Manganese-Azido Chains: Structural Characterization and Magnetic Behavior of Two New One-Dimensional [Mn(L)2(1,3-N3)2]n Compounds (L = 3-Ethylpyridine and 2-Hydroxypyridine) Albert Escuer, Ramon Vicente, Mohamed A. S. Goher, and Franz A. Mautner pp 782 - 787; DOI: 10.1021/ic971023q |
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Synthesis, Structural Characterization (X-ray and EXAFS), and Magnetic Properties of Polynuclear Manganese(II) Complexes with Chlorobenzoato Bridges Belen Albela, Montserrat Corbella, Joan Ribas, Isabel Castro, Jorunn Sletten, and Helen Stoeckli-Evans pp 788 - 798; DOI: 10.1021/ic970935p |
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Ammonium Iron(II,III) Phosphate: Hydrothermal Synthesis and Characterization of NH4Fe2(PO4)2 Sophie Boudin and Kwang-Hwa Lii pp 799 - 803; DOI: 10.1021/ic970655+ |
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To Bend or Not To Bend: Dilemma of the Edge-Sharing Binuclear Square Planar Complexes of d8 Transition Metal Ions Gabriel Aullón, Gregori Ujaque, Agustí Lledós, Santiago Alvarez, and Pere Alemany pp 804 - 813; DOI: 10.1021/ic9713386 |
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The Synthesis, Structure, and Bonding of Sc8Te3 and Y8Te3. Cooperative Matrix and Bonding Effects in the Solid State Paul A. Maggard and John D. Corbett pp 814 - 820; DOI: 10.1021/ic971107z |
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Synthesis and X-ray Crystal Structure of K4PbTe3·2(en) C. D. W. Jones, F. J. DiSalvo, and R. C. Haushalter pp 821 - 823; DOI: 10.1021/ic970882b |
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Rhodium Dithiocarbamate Compounds as Metalloligands: A Controlled Way for the Construction of Binuclear Complexes Anabel Elduque, Cristina Finestra, José A. López, Fernando J. Lahoz, Francisco Merchán, Luis A. Oro, and M. Teresa Pinillos pp 824 - 829; DOI: 10.1021/ic971053t |
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Electron Localization or Delocalization in the MLCT Excited States of Ru(bpy)32+ and Ru(phen)32+. Consequences to Their Photochemistry and Photophysics in Fluid Solution Cang Li and Morton Z. Hoffman pp 830 - 832; DOI: 10.1021/ic970959w |
Issue 5
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SrHg2O2Cl2, the First Strontium Mercury Oxychloride. Crystal Structure Determination by ab Initio Powder Methods William T. A. Harrison, Lumei Liu, Allan J. Jacobson, and Thomas Vogt pp 834 - 835; DOI: 10.1021/ic9706008 |
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Supramolecular Mn-Ca Aggregates as Models for the Photosynthetic Water Oxidation Complex Sergiu M. Gorun, Robert T. Stibrany, and Antonietta Lillo pp 836 - 837; DOI: 10.1021/ic9713083 |
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Reactivity of Osmium(VI) Nitrides with the Azide Ion Konstantinos D. Demadis, El-Sayed El-Samanody, Thomas J. Meyer, and Peter S. White pp 838 - 839; DOI: 10.1021/ic971336l |
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Structure and Magnetic Properties of (meso-Tetraphenylporphinato)manganese(III) Pentacyanopropenide, [MnIIITPP]+[C3(CN)5]-. An Unusual Asymmetric Bridge-Bonding Mode for -[C3(CN)5]- Michelle L. Yates, Atta M. Arif, Jamie L. Manson, Benjamin A. Kalm, Brian M. Burkhart, and Joel S. Miller pp 840 - 841; DOI: 10.1021/ic9713893 |
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Bimetallic Assemblies [Ni(L)2]3[Fe(CN)6]X2 (L = Ethylenediamine, Trimethylenediamine; X = PF6-, ClO4-) with a Three-Dimensional Network Extended through FeII-CN-NiII Linkages Nobuo Fukita, Masaaki Ohba, Hisashi  kawa, Kenji Matsuda, and Hiizu Iwamurapp 842 - 848; DOI: 10.1021/ic9711168 |
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Formation of Chain and Large-Ring Polymeric Metal Complexes by the "Extended Reach" Sulfur Donor Ligands N,N'-Ethylenebis(pyrrolidine-2-thione) and N,N'-p-Phenylenedimethylenebis(pyrrolidine-2-thione) Zeno Atherton, David M. L. Goodgame, Stephan Menzer, and David J. Williams pp 849 - 858; DOI: 10.1021/ic971180p |
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Preparation and Photophysical Characterization of a Y-Zeolite-Entrapped Ru(bpy)2(pypz)2+ Complex Witold S. Szulbinski and James R. Kincaid pp 859 - 864; DOI: 10.1021/ic971088t |
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Bonding Analysis in Inorganic Transition-Metal Cubic Clusters. 3. Metal-Centered Tetracapped M9(5-E)4Ln Species with a Tetragonal Distortion Bachir Zouchoune, François Ogliaro, Jean-François Halet, Jean-Yves Saillard, Jeffrey R. Eveland, and Kenton H. Whitmire pp 865 - 875; DOI: 10.1021/ic970715b |
Preparation and Characterization of a New 3-Dimensional Zirconium Hydrogen Phosphate,  -Zr(HPO4)2. Determination of the Complete Crystal Structure Combining Synchrotron X-ray Single-Crystal Diffraction and Neutron Powder DiffractionAnne Marie Krogh Andersen, Poul Norby and, Jonathan C. Hanson, and Tom Vogt pp 876 - 881; DOI: 10.1021/ic971060h |
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Smectogenic Copper(II) Complexes of N-Salicylideneaniline Derivatives. A Comparative Study of Homologous Series Carrying Alkoxy and/or Alkanoyloxy Substituents Naomi Hoshino, Kenta Takahashi, Toshinobu Sekiuchi, Hiromi Tanaka, and Yoshio Matsunaga pp 882 - 889; DOI: 10.1021/ic9710566 |
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Syntheses and Spectroscopic and Structural Characterization of Silver(I) Complexes Containing Tertiary Phosphines and Hydrotris(pyrazol-1-yl)-, Hydrotris(4-bromopyrazol-1-yl)-, Hydrotris(3,5-dimethypyrazol-1-yl)-, and Hydrotris(3-methyl-2-thioxo-1-imidazolyl)borates C. Santini, G. Gioia Lobbia, C. Pettinari, M. Pellei, G. Valle, and S. Calogero pp 890 - 900; DOI: 10.1021/ic9707624 |
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A Tetranuclear Niobium Oxo Acetate Complex. Synthesis, X-ray Crystal Structure, and Characterization by Solid-State and Liquid-State NMR Spectroscopy Nathalie Steunou, Christian Bonhomme, Clément Sanchez, Jacqueline Vaissermann, and Liliane G. Hubert-Pfalzgraf pp 901 - 910; DOI: 10.1021/ic971024i |
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Solution and Solid State Multinuclear NMR Investigation of the Structure of {(BuSn)12O14(OH)6}(O2PPh2)2 François Ribot, Clément Sanchez, Rudolph Willem, José C. Martins, and Monique Biesemans pp 911 - 917; DOI: 10.1021/ic971189r |
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Synthesis and Optical Spectroscopy of MnO42--Doped Crystals of Cs2CrO4, SrCrO4, CsBr, and CsI Ralph P. Schenker, Thomas C. Brunold, and Hans U. Güdel pp 918 - 927; DOI: 10.1021/ic971004g |
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Cluster Expansion Reactions of Group 6 Metallaboranes. Syntheses, Crystal Structures, and Spectroscopic Characterizations of (Cp*Cr)2B5H9, (Cp*Cr)2B4H8Fe(CO)3, (Cp*Cr)2B4H7Co(CO)3, and (Cp*Mo)2B5H9Fe(CO)3 Simon Aldridge, Hisako Hashimoto, Kazumori Kawamura, Maoyu Shang, and Thomas P. Fehlner pp 928 - 940; DOI: 10.1021/ic971251k |
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Polyamine Macrocycles Incorporating a Phenanthroline Unit: Their Synthesis, Basicity, and Cu(II) Coordination Carla Bazzicalupi, Andrea Bencini, Vieri Fusi, Claudia Giorgi, Piero Paoletti, and Barbara Valtancoli pp 941 - 948; DOI: 10.1021/ic9708428 |
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Reactivity of Dioxovanadium(V) Complexes with Hydrogen Peroxide: Implications for Vanadium Haloperoxidase Brent J. Hamstra, Gerard J. Colpas, and Vincent L. Pecoraro pp 949 - 955; DOI: 10.1021/ic9711776 |
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Iron(III) Complexes as Superoxide Dismutase Mimics: Synthesis, Characterization, Crystal Structure, and Superoxide Dismutase (SOD) Activity of Iron(III) Complexes Containing Pentaaza Macrocyclic Ligands DeLong Zhang, Daryle H. Busch, Patrick L. Lennon, Randy H. Weiss, William L. Neumann, and Dennis P. Riley pp 956 - 963; DOI: 10.1021/ic970861h |
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A Determination of the Reduction Potentials for Diferric and C- and N-Lobe Monoferric Transferrins at Endosomal pH (5.8) Daniel C. Kraiter, Olga Zak, Philip Aisen, and Alvin L. Crumbliss pp 964 - 968; DOI: 10.1021/ic970644g |
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2H NMR Investigation of [Fe3S4]0 Cluster in 7Fe8S Ferredoxin from Bacillus schlegelii Ivano Bertini, Claudio Luchinat, Giovanna Mincione, and Aileen Soriano pp 969 - 972; DOI: 10.1021/ic970920r |
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Electrochemical and Spectroscopic Characterization of Manganese(III) Dodecaphenylporphyrin Derivatives and X-ray Structural Determination of Chloro(5,10,15,20-tetrakis(pentafluorophenyl)-2,3,7,8,12,13,17,18-octaphenylporphyrinato)- manganese(III). Formation of a Manganese(IV) Species by Ozone and Electrochemical Oxidation Roger Guilard, Karine Perié, Jean-Michel Barbe, Daniel J. Nurco, Kevin M. Smith, Eric Van Caemelbecke, and Karl M. Kadish pp 973 - 981; DOI: 10.1021/ic970717w |
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Carbon Monoxide Production during the Oxygenation of Cobalt Complexes of Linear Tetrapyrroles. Formation and Characterization of CoII(tetraethylpropentdyopent anion)2 Richard Koerner, Marilyn M. Olmstead, Pamela M. Van Calcar, Krzysztof Winkler, and Alan L. Balch pp 982 - 988; DOI: 10.1021/ic971265q |
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Dinuclear Nickel(II) Complexes of Phenol-Based "End-Off" Compartmental Ligands and Their Urea Adducts Relevant to the Urease Active Site Takeichiro Koga, Hideki Furutachi, Takako Nakamura, Nobuo Fukita, Masaaki Ohba, Kazuhiro Takahashi, and Hisashi kawapp 989 - 996; DOI: 10.1021/ic971209p |
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Structure, Stability, and Redox Properties of MnII, FeII, CoII, and CoIII Complexes with 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol Michele Ghisletta, Lorenza Hausherr-Primo, Krisztina Gajda-Schrantz, Gábor Machula, László Nagy, Helmut W. Schmalle, Greti Rihs, Frank Endres, and Kaspar Hegetschweiler pp 997 - 1008; DOI: 10.1021/ic971242b |
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Encapsulation by a Chromium(III)-Containing Bicyclic Ligand Cage. Synthesis, Structures, and Physical Properties of Heterometal Complexes CrIIIMCrIII [M = (H+)2, Li(I), Mg(II), Cu(II), Ni(II), Ni(IV), Co(III), Fe(II), Fe(III), Mn(II)] Dirk Burdinski, Frank Birkelbach, Thomas Weyhermüller, Ulrich Flörke, Hans-Jürgen Haupt, Marek Lengen, Alfred X. Trautwein, Eckhard Bill, Karl Wieghardt, and Phalguni Chaudhuri pp 1009 - 1020; DOI: 10.1021/ic971101+ |
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Rapid, Catalytic Hydrolysis of Methionine-Containing Dipeptides by a Dinuclear Palladium(II) Complex Having Thiolate Bridging Ligands Gail B. Karet and Nenad M. Kosti  pp 1021 - 1027; DOI: 10.1021/ic970461u |
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Copper(II) and Nickel(II) Complexes of Dianionic and Tetraanionic Dinucleating Macrocycles Kausik K. Nanda, Anthony W. Addison, Neil Paterson, Ekkehard Sinn, Laurence K. Thompson, and Ushio Sakaguchi pp 1028 - 1036; DOI: 10.1021/ic9712434 |
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(5,10,15,20-Tetramethylporphyrinato)cobalt(II): A Remarkably Active Catalyst for the Electroreduction of O2 to H2O Chunnian Shi and Fred C. Anson pp 1037 - 1043; DOI: 10.1021/ic971255p |
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Systematic Tuning of the Photosubstitution Mechanism of M(CO)4(1,10-phenanthroline) by Variation of the Metal, Entering Nucleophile, Excitation Wavelength, and Pressure Wen-Fu Fu and Rudi van Eldik pp 1044 - 1050; DOI: 10.1021/ic9707366 |
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Atom Transfer Processes in Oxidative Quenching of Triplet State Tetrakis(-pyrophosphite-P,P')diplatinate(II) by Acidopentacyanocobaltate(III) Anions Alexander D. Kirk and Le-Zhen Cai pp 1051 - 1059; DOI: 10.1021/ic971096+ |
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Temperature-Dependent Photoluminescence Properties of Tl[Ag(CN)2]: Formation of Luminescent Metal-Metal-Bonded Inorganic Exciplexes in the Solid State Mohammad A. Omary and Howard H. Patterson pp 1060 - 1066; DOI: 10.1021/ic970823y |
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Calculated Properties of Lanthanocene Anions and the Unusual Electronic Structure of Their Neutral Counterparts Wenjian Liu, Michael Dolg, and Peter Fulde pp 1067 - 1072; DOI: 10.1021/ic9704703 |
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Polynuclear Complexes of Copper(I) and the 2-(3(5)-Pyrazolyl)-6-methylpyridine Ligand: Structures and Reactivity toward Small Molecules Kuljeet Singh, Jeffrey R. Long, and Pericles Stavropoulos pp 1073 - 1079; DOI: 10.1021/ic9708071 |
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Is CO a Special Ligand in Organometallic Chemistry? Theoretical Investigation of AB, Fe(CO)4AB, and Fe(AB)5 (AB = N2, CO, BF, SiO) Udo Radius, F. Matthias Bickelhaupt, Andreas W. Ehlers, Norman Goldberg, and Roald Hoffmann pp 1080 - 1090; DOI: 10.1021/ic970897+ |
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Synthesis and Copper Coordination Chemistry of Hindered 1,4,7-Triazacyclononane Ligands with Amide Appendages Lisa M. Berreau, Jason A. Halfen, Victor G. Young, Jr., and William B. Tolman pp 1091 - 1098; DOI: 10.1021/ic971115f |
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Heterocubane Phosphoraniminato Complexes of Cadmium Klaus Harms, Jan Merle, Cäciliä Maichle-Mössmer, Werner Massa, and Matthias Krieger pp 1099 - 1104; DOI: 10.1021/ic9710364 |
Synthesis and Characterization of Unsymmetrical (cis-(Phosphino-arsino)ethene)tetracarbonylmolybdenum Complexes: Hydroarsination Reactions of (H3CC CPPh2)Mo(CO)5 and [H2C=C=CH(DBP)]Mo(CO)5 and Hydrophosphination Reactions of (Ph2AsCH2CCH)Mo(CO)5Kalyani Maitra, Vincent J. Catalano, Jerry Clark, III, and John H. Nelson pp 1105 - 1111; DOI: 10.1021/ic9711170 |
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Spectroscopic Identification and Electrochemical Behavior of the Dihydride Tetrapalladium Cluster [Pd4(dppm)4(H)2]X2 (X = Cl, Br) Isabelle Gauthron, Jonathan Gagnon, Tianle Zhang, Dominic Rivard, Dominique Lucas, Yves Mugnier, and Pierre D. Harvey pp 1112 - 1115; DOI: 10.1021/ic970569+ |
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Mechanistic Insight from Energy and Volume Profiles for CO Binding to a Lacunar Iron(II) Cyclidene Complex Maria Buchalova, Daryle H. Busch, and Rudi van Eldik pp 1116 - 1120; DOI: 10.1021/ic9711426 |
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Coordination Compounds as Building Blocks: Single-Step Synthesis of Heteronuclear Multimetallic Complexes Containing RuII and OsII Patrick J. Connors, Jr., Dimitrios Tzalis, Alejandro L. Dunnick, and Yitzhak Tor pp 1121 - 1123; DOI: 10.1021/ic970911i |
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Intramolecular Electron Transfer in Tetraammine(L)ruthenium(III)-Modified Manganocytochromes c Ji Sun and James F. Wishart pp 1124 - 1126; DOI: 10.1021/ic971169p |
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Synthesis and Structure of a Novel Cu(II) Complex with a Monoprotic Tetradentate Schiff Base Ligand Hongyan Luo, Phillip E. Fanwick, and Mark A. Green pp 1127 - 1130; DOI: 10.1021/ic9708632 |
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A Discrete Chlorotellurate [Cl4Te-Mn(CO)5]-: Coordinative Addition of the Metalloanion [Mn(CO)5]- to TeCl4 Wen-Feng Liaw, Show-Jen Chiou, Gene-Hsiang Lee, and Shie-Ming Peng pp 1131 - 1134; DOI: 10.1021/ic9708677 |
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Equilibrium Dynamics in the Thallium(III)-Cyanide System in Aqueous Solution Ist  an Bányai, Julius Glaser, and Judit Losonczipp 1135 - 1135; DOI: 10.1021/ic9800536 |
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Photochemistry of the Triangular Clusters Os3(CO)10(-diimine): Homolysis of an Os-Os Bond and Solvent-Dependent Formation of Biradicals and Zwitterions Jos Nijhoff, Maarten J. Bakker, Franti ek Hartl, Derk J.Stufkens, Wen-Fu Fu, and Rudi van Eldikpp 1136 - 1136; DOI: 10.1021/ic980143a |
Issue 6
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Effect of Carboxamido N Coordination to Iron on the Redox Potential of Low-Spin Non-Heme Iron Centers with N,S Coordination: Relevance to the Iron Site of Nitrile Hydratase Juan C. Noveron, Marilyn M. Olmstead, and Pradip K. Mascharak pp 1138 - 1139; DOI: 10.1021/ic971388a |
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A New Transition Metal-Main Group Oxide Cluster in the Oxovanadium-Borate System: Hydrothermal Synthesis and Structure of (H3O)12[(VO)12{B16O32(OH)4}2]·28H2O Christopher J. Warren, David J. Rose, Robert C. Haushalter, and Jon Zubieta pp 1140 - 1141; DOI: 10.1021/ic971452o |
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Biphenyl-Strapped Diphenylporphyrins: Synthesis and Spectroscopic Characterization of a Series of Porphyrins with Ether-Linked Straps. Preliminary CO Binding Properties of Their Iron(II) Derivatives Laurent Jaquinod, Lionel Prévot, Jean Fischer, and Raymond Weiss pp 1142 - 1149; DOI: 10.1021/ic970705a |
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Synthesis and Characterization of a Series of Monometallo-, Bimetallo-, and Heterobimetallo-1,2-Ethene-Linked Cofacial Bisporphyrins Todd E. Clement, Daniel J. Nurco, and Kevin M. Smith pp 1150 - 1160; DOI: 10.1021/ic970774p |
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Synthesis and Characterization of an Octanuclear Mixed-Ligand Copper(II) Complex of the Immunosuppressant Thiopurine Drug Azathioprine Fu-chun Zhu, Helmut W. Schmalle, Berthold Fischer, and Erich Dubler pp 1161 - 1168; DOI: 10.1021/ic9706663 |
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NMR Coupling versus NMR Chemical Shift Information in Metallobiochemistry. High-Resolution One-Bond 1H-13C Coupling Constants Obtained by a Sensitive Reverse Detection Method Scott J. Moore, Marian Iwamoto, and Luigi G. Marzilli pp 1169 - 1174; DOI: 10.1021/ic971299y |
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A New Class of Complexes Possessing Cofacially-Oriented, Planar, Metal-Containing Subunits. Synthesis, Characterization, and Reactivity of [(MoO2)2(-O)]2+-Linked, Catechol-Functionalized, Tetraazamacrocyclic and Salicylideneamine Complexes Steven M. Malinak, Dell T. Rosa, and Dimitri Coucouvanis pp 1175 - 1190; DOI: 10.1021/ic9715916 |
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Synthesis and Characterization of Tetrachlorodiarylethyne-Linked Porphyrin Dimers. Effects of Linker Architecture on Intradimer Electronic Communication Jon-Paul Strachan, Steve Gentemann, Jyoti Seth, William A. Kalsbeck, Jonathan S. Lindsey, Dewey Holten, and David F. Bocian pp 1191 - 1201; DOI: 10.1021/ic970967c |
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Framework Bonding and Coordination Sphere Rearrangement in the M2X2 Cores of Synthetic Analogues of Oxyhemocyanin and Related Cu and Pt Complexes Xiang-Yang Liu, Ana A. Palacios, Juan J. Novoa, and Santiago Alvarez pp 1202 - 1212; DOI: 10.1021/ic970629b |
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A Dinuclear Nickel(II) Complex with Readily Accessible Coordination Sites and Additional N-Functional Groups in Proximity to the Bimetallic Core Franc Meyer, Albrecht Jacobi, Bernhard Nuber, Peter Rutsch, and Laszlo Zsolnai pp 1213 - 1218; DOI: 10.1021/ic971234v |
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Synthesis, Molecular Structure, and Reactivity of Dinuclear Copper(II) Complexes with Carboxylate-Rich Coordination Environments Richard C. Holz, John M. Bradshaw, and Brian Bennett pp 1219 - 1225; DOI: 10.1021/ic9707873 |
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Dicopper(II) Complexes of the Antitumor Analogues Acylbis(salicylaldehyde hydrazones) and Crystal Structures of Monomeric [Cu2(1,3-propanedioyl bis(salicylaldehyde hydrazone))(H2O)2]·(ClO4)2·3H2O and Polymeric [{Cu2(1,6-hexanedioyl bis(salicylaldehyde hydrazone))(C2H5OH)2}m]·(ClO4)2m·m(C2H5OH) John D. Ranford, Jagadese J. Vittal, and Yu M. Wang pp 1226 - 1231; DOI: 10.1021/ic970805g |
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Kinetic Lability, Structural Diversity, and Oxidation Reactions of New Oligomeric, Anionic Carboxylate-Pyridine Complexes R. A. Reynolds, III, W. R. Dunham, and D. Coucouvanis pp 1232 - 1241; DOI: 10.1021/ic971537p |
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Binding of Amino-Dialkylated Adenines to Rhenium(III) and Rhenium(IV) Centers Céline Pearson and André L. Beauchamp pp 1242 - 1248; DOI: 10.1021/ic970763w |
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A Proton-Induced N-1 to 2 Migration of the Fluxional Pyrazine in the [RuII(hedta)(pz)]- Complex Ya Chen and Rex E. Shepherd pp 1249 - 1256; DOI: 10.1021/ic961269f |
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Kinetics and Mechanism of the One-Electron Reduction of Iodine by [RuII(NH3)5isn]2+ in Aqueous Solution Jiafei Sun and David M. Stanbury pp 1257 - 1263; DOI: 10.1021/ic971033r |
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Interaction of Triphenyltin Hydride and Rhodium. Structure of [Rh(NCBPh3)(H)(SnPh3)(PPh3)2] and NMR (1H, 15N, 31P, 103Rh, 119Sn) Study of Pyridine-Containing Derivatives Laurence Carlton, Rosemarie Weber, and Demetrius C. Levendis pp 1264 - 1271; DOI: 10.1021/ic970662y |
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Matrix-Assisted Laser Desorption/Ionization Time-of-Flight Mass Spectrometry (MALDI-TOF MS) of Rhenium(III) Halides: A Characterization Tool for Metal Atom Clusters Nancy Carter Dopke, Paul M. Treichel, and Martha M. Vestling pp 1272 - 1277; DOI: 10.1021/ic971220p |
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13C and 15N NMR Mechanistic Study of Cyanide Exchange on Oxotetracyanometalate Complexes of Re(V), Tc(V), W(IV), Mo(IV), and Os(VI) Amira Abou-Hamdan, Andreas Roodt, and André E. Merbach pp 1278 - 1288; DOI: 10.1021/ic971239s |
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Monomeric Three- and Four-Coordinate Magnesium Amides Jennifer L. Sebestl, T. Timothy Nadasdi, Mary Jane Heeg, and Charles H. Winter pp 1289 - 1294; DOI: 10.1021/ic970905m |
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Heteroatom Derivatives of Cyclopentadienylaluminum: X-ray Crystal Structure of (5-C5H5)(2,6-t-Bu-4-Me-C6H2O)2Al James D. Fisher, Pamela J. Shapiro, P. M. H. Budzelaar, and Richard J. Staples pp 1295 - 1298; DOI: 10.1021/ic970376m |
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Halocarbonyltungsten(II) Complexes Containing Tripodal Tris(pyrazolyl)borate Ligands Charles G. Young, Simon Thomas, and Robert W. Gable pp 1299 - 1306; DOI: 10.1021/ic970838w |
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A Density Functional Study of [2+3] versus [2+2] Addition of Ethylene to Chromium-Oxygen Bonds in Chromyl Chloride Maricel Torrent, Liqun Deng, and Tom Ziegler pp 1307 - 1314; DOI: 10.1021/ic970896h |
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Syntheses of the Uranium Complexes [U{N(SiMe3)2}2{N(SiMe3)(SiMe2CH2B(C6F5)3)}] and [U{C(Ph)(NSiMe3)2}2{3-BH4}2]. Determination of Hydrogen Positions by Single-Crystal X-ray and Neutron Diffraction Matthias Müller, V. Cliff Williams, Linda H. Doerrer, Michael A. Leech, Sax A. Mason, Malcolm L. H. Green, and Keith Prout pp 1315 - 1323; DOI: 10.1021/ic970891k |
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Mixed Ruthenium-Rhodium Carbonyl Cluster Complexes. Synthesis of the Anions [Ru3Rh(CO)13]- and [RuRh3(CO)12]- and Crystal Structures of Their [N(PPh3)2]+ Salts Alessandro Fumagalli, Mascia Bianchi, Maria Carlotta Malatesta, Gianfranco Ciani, Massimo Moret, and Angelo Sironi pp 1324 - 1328; DOI: 10.1021/ic970862+ |
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Simultaneous Antiferromagnetic Order and Spin-Glass-like Behavior in MnAsO4 Miguel A. G. Aranda, J. Paul Attfield, Elaine Batchelor, Greg P. Shields, Sebastián Bruque, and Mercedes Gabás pp 1329 - 1335; DOI: 10.1021/ic970858y |
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Magneto-Structural Correlation Studies of A Ferromagnetically Coupled Dinuclear Vanadium(IV) Complex. Single-Crystal EPR Study Murugesan Velayutham, Babu Varghese, and Sankaran Subramanian pp 1336 - 1340; DOI: 10.1021/ic9707467 |
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- and -CuAlCl4: Framework Construction Using Corner-Shared Tetrahedral Metal-Halide Building Blocks James D. Martin, Brian R. Leafblad, Roger M. Sullivan, and Paul D. Boyle pp 1341 - 1346; DOI: 10.1021/ic971148v |
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One Step Forward to "Stapled" Bis(phthalocyanine) Metal Complexes: Synthesis, Characterization, and Redox Properties of Bis(phthalocyaninato)niobium(IV). X-ray Crystal Structure of the Monoelectronically Oxidized Species [Pc2Nb](I3)(I2)0.5(ClNP)3.5 (ClNP = 1-Chloronaphthalene) Maria Pia Donzello, Claudio Ercolani, Angiola Chiesi-Villa, and Corrado Rizzoli pp 1347 - 1351; DOI: 10.1021/ic970841f |
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Hafnium Germanate from a Hydrous Hafnium Germanium Oxide Gel P. M. Lambert pp 1352 - 1357; DOI: 10.1021/ic970523g |
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Synthesis and Structure of the Zintl-Phase K4Pb9 Containing Isolated Pb94- Clusters of Two Different Geometries Virginie Queneau and Slavi C. Sevov pp 1358 - 1360; DOI: 10.1021/ic971225m |
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Pulsed ENDOR and ESEEM Study of [Bis(maleonitriledithiolato)nickel]-: An Investigation into the Ligand Electronic Structure Jennifer E. Huyett, Suranjan B. Choudhury, David M. Eichhorn, Peter A. Bryngelson, Michael J. Maroney, and Brian M. Hoffman pp 1361 - 1367; DOI: 10.1021/ic9703639 |
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Structural Properties of M(dmit)2-Based (M = Ni, Pd, Pt; dmit2- = 2-Thioxo-1,3-dithiole-4,5-dithiolato) Molecular Metals. Insights from Density Functional Calculations Angela Rosa, Giampaolo Ricciardi, and Evert Jan Baerends pp 1368 - 1379; DOI: 10.1021/ic970452l |
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Crystal Structure, Electronic Structure, and Temperature-Dependent Raman Spectra of Tl[Ag(CN)2]: Evidence for Ligand-Unsupported Argentophilic Interactions Mohammad A. Omary, Thomas R. Webb, Zerihun Assefa, George E. Shankle, and Howard H. Patterson pp 1380 - 1386; DOI: 10.1021/ic970694l |
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The Spectroscopy of HMn(CO)5: A CASSCF/MRCI and CASPT2 ab Initio Study Michel R. J. Hachey and Chantal Daniel pp 1387 - 1391; DOI: 10.1021/ic9707523 |
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Comparison of Solid-State and Solution Photophysical Properties of a Platinum(II) Biphenyl Dicarbonyl Complex: A Multiple-State Emission Study Greg Y. Zheng and D. Paul Rillema pp 1392 - 1397; DOI: 10.1021/ic970594f |
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Isotope Exchange in Ionized O3/O2 Mixtures: The Role of O5+, a Unique On+ Complex Fulvio Cacace, Romano Cipollini, Giulia de Petris, Federico Pepi, Marzio Rosi, and Antonio Sgamellotti pp 1398 - 1400; DOI: 10.1021/ic970622u |
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Electronic State Structure and Optical Properties of Tb(oda)33- Complexes in Trigonal Na3[Tb(oda)3]·2NaClO4·6H2O Crystals Todd A. Hopkins, David H. Metcalf, and F. S. Richardson pp 1401 - 1412; DOI: 10.1021/ic971114n |
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Diruthenium(II,III) Carboxylate Compounds: Existence of both Polymeric and Ionic Forms in Solution and Solid State M. Carmen Barral, Reyes Jiménez-Aparicio, José L. Priego, Elia C. Royer, Francisco A. Urbanos, and Ulises Amador pp 1413 - 1416; DOI: 10.1021/ic9708024 |
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X-ray Structure and Raman Spectrum of [Ti4(3-O)2(2-OiPr)2(OiPr)8(acac)2]: Presence of a Ti4(3-O)2(2-OiPr)2 Ladder-like Core Paul D. Moran, Clifton E. F. Rickard, Graham A. Bowmaker, Ralph P. Cooney, John R. Bartlett, and James L. Woolfrey pp 1417 - 1419; DOI: 10.1021/ic970942d |
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Reactions of 6,9-Bis(dimethyl sulfide)- decaborane(14), 6,9-[(CH3)2S]2B10H12: Mechanistic Considerations Herbert Beall and and Donald F. Gaines pp 1420 - 1422; DOI: 10.1021/ic971262d |
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Syntheses of Titanium and Zirconium Chlorotrialkyl Complexes and Crystal Structure of Chlorotrineopentylzirconium Containing Unusual Linear Symmetric Metal-Chloride Polymeric Chains Lenore H. McAlexander, Liting Li, Yihui Yang, Jonathan L. Pollitte, and Ziling Xue pp 1423 - 1426; DOI: 10.1021/ic971407g |
Issue 7
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Synthesis and Structures of New Layered Ternary Manganese Tellurides: AMnTe2 (A = Li, Na) Joonyeong Kim, Chwanchin Wang, and Timothy Hughbanks pp 1428 - 1429; DOI: 10.1021/ic971245o |
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A Ferromagnetic Ring of Six Manganese(III) Ions with a S = 12 Ground State Gian Luca Abbati, Andrea Cornia, Antonio C. Fabretti, Andrea Caneschi, and Dante Gatteschi pp 1430 - 1431; DOI: 10.1021/ic971373c |
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Generation of an Unprecedented Excited State Oxidant in a Coordinately Unsaturated Platinum Complex Karl Base and Mark W. Grinstaff pp 1432 - 1433; DOI: 10.1021/ic971400z |
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Electron Transfer. 136. Decomposition of Peroxynitrite As Catalyzed by Sulfito-Bound Cobalt(III) Ahmad M. Al-Ajlouni, Pradip C. Paul, and Edwin S. Gould pp 1434 - 1437; DOI: 10.1021/ic971104m |
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Lariat Ether Carboxylic Acids as Ionizable Hosts in the Second Coordination Sphere of the Siderophore Ferrioxamine B in Chloroform I. Batini -Haberle, I. Spasojevi, Y. Jang, R. A. Bartsch, and A. L. Crumblisspp 1438 - 1445; DOI: 10.1021/ic970925o |
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Nitrones as Ligands in Complexes of Cu(II), Mn(II), Co(II), Ni(II), Fe(II), and Fe(III) with N-tert-Butyl--(2-pyridyl)nitrone and 2,5,5-Trimethyl-1-pyrroline-N-oxide Frederick A. Villamena, Michael H. Dickman, and DeLanson R. Crist pp 1446 - 1453; DOI: 10.1021/ic9709741 |
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Stabilization of a Nitroxide with a -Hydrogen by Metals: Structure and Magnetic Properties of Adducts of N-Oxy-N-tert-butyl-(2-pyridyl)phenylmethanamine with Mn(II), Ni(II), and Co(II) Hexafluoroacetylacetonates Frederick A. Villamena, Michael H. Dickman, and DeLanson R. Crist pp 1454 - 1457; DOI: 10.1021/ic971215l |
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Structural Characterization and Magnetic Properties of the First 2,2'-Bipyrimidine-Containing Iron(III) Complexes Giovanni De Munno, Walter Ventura, Guillaume Viau, Francesc Lloret, Juan Faus, and Miguel Julve pp 1458 - 1464; DOI: 10.1021/ic971110i |
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Spin Exchange Coupling in Heterobimetallic MIIVIVO (M = Cu, Ni, Co, Fe, Mn) Macrocyclic Complexes. Synthesis, Structure, and Properties Sasankasekhar Mohanta, Kausik K. Nanda, Laurence K. Thompson, Ulrich Flörke, and Kamalaksha Nag pp 1465 - 1472; DOI: 10.1021/ic971176d |
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Homo- and Heterometallic Mono-, Di-, and Trinuclear Co2+, Ni2+, Cu2+, and Zn2+ Complexes of the "Heteroscorpionate" Ligand (2-Hydroxyphenyl)bis(pyrazolyl)methane and Its Derivatives Timothy C. Higgs, Norman S. Dean, and Carl J. Carrano pp 1473 - 1482; DOI: 10.1021/ic9711630 |
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[Ca(dipicH2)(OH2)3][Ce(dipic)3]·5H2O: A One-Dimensional Coordination Polymer with Alternating CeN3O6 and CaNO7 Polyhedra (dipicH2 = Pyridine-2,6-dicarboxylic Acid) G. Swarnabala and M. V. Rajasekharan pp 1483 - 1485; DOI: 10.1021/ic971261l |
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A Reversible, Isosymmetric, High-Pressure Phase Transition in Na3MnF6 Stefan Carlson, Yiqiu Xu, Ulf Hålenius, and Rolf Norrestam pp 1486 - 1492; DOI: 10.1021/ic971171g |
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Polycyclic Bis(tert-butylamido)cyclodiphosph(III)azane Complexes of Lithium and Magnesium: Their Syntheses, Molecular Structures, and Relationships to Isoelectronic Cyclodisilazane Derivatives Ingo Schranz, Lothar Stahl, and Richard J. Staples pp 1493 - 1498; DOI: 10.1021/ic971201f |
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Preparation, Crystal Structures, and Magnetic and ESR Properties of Molecular Assemblies of Ferrocenium Derivatives and Paramagnetic Polyoxometalates Stéphane Golhen, Lahcène Ouahab, Daniel Grandjean, and Philippe Molinié pp 1499 - 1506; DOI: 10.1021/ic971221h |
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Coordination Intercalation of NbAsO5 with Alkali-Metal Chloride. Synthesis, Structure, and Spectroscopy of Two New Layered Niobium(V) Arsenate Compounds, ANbAsO5Cl (A = Rb, Cs) Mutlu Ulutagay, George L. Schimek, Shiou-Jyh Hwu, and Hanna Taye pp 1507 - 1512; DOI: 10.1021/ic9714347 |
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Electronic State of Nickel in Barium Nickel Oxide, BaNiO3 R. Gottschall, R. Schöllhorn, M. Muhler, N. Jansen, D. Walcher, and P. Gütlich pp 1513 - 1518; DOI: 10.1021/ic9709279 |
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Combined X-ray Diffraction and Density Functional Study of [Ni(NO)(5-Cp*)] in the Ground and Light-Induced Metastable States Dmitry V. Fomitchev, Thomas R. Furlani, and Philip Coppens pp 1519 - 1526; DOI: 10.1021/ic9713644 |
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Structure and Physical Properties of Trigonal Monopyramidal Iron(II), Cobalt(II), Nickel(II), and Zinc(II) Complexes Manabendra Ray, Brian S. Hammes, Glenn P. A. Yap, Arnold L. Rheingold, and A. S. Borovik pp 1527 - 1532; DOI: 10.1021/ic970831e |
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Tetrakis(thiadiazole)porphyrazines. 1. Syntheses and Properties of Tetrakis(thiadiazole)porphyrazine and Its Magnesium and Copper Derivatives P. A. Stuzhin, E. M. Bauer, and C. Ercolani pp 1533 - 1539; DOI: 10.1021/ic9609259 |
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Effect of Aliphatic Amine Bases on the Aggregation of Alkali Metal Salts of 3,5-Di-tert-butylsemiquinone (3,5-DBSQ) David A. Shultz, Andrew K. Boal, and Neil P. Campbell pp 1540 - 1543; DOI: 10.1021/ic971113v |
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Synthesis of Alkyl and Aryl Derivatives of closo-B12H122- by the Palladium-Catalyzed Coupling of closo-B12H11I2- with Grignard Reagents Toralf Peymann, Carolyn B. Knobler, and M. Frederick Hawthorne pp 1544 - 1548; DOI: 10.1021/ic9712075 |
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Preparation and Characterization of (iPrO)4WW(2-dmpe)2(CO), (1-O2CH)(iPrO)4WW(2-dmpe)2(H), [H(2-dmpe)WWO2]2(-O), and W2(O)4(-O)[W(2-dmpe)2CO]2 (dmpe = Bisdimethylphosphinomethane), Compounds with W-W Bonds between Metal Atoms in Greatly Differing Oxidation States Malcolm H. Chisholm, Kirsten Folting, Keith S. Kramer, and William E. Streib pp 1549 - 1554; DOI: 10.1021/ic9705249 |
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Protonation Reactions of trans-M(H)(SPh)(dppe)2 (M = Ru, Os) To Give Thiol and Dihydrogen Complexes. X-ray Crystal Structure Determination of trans-Ru(H)(SPh)(dppe)2 and trans-[Os(H)(O2)(dppe)2](O3SCF3) Tanya Y. Bartucz, Adina Golombek, Alan J. Lough, Patricia A. Maltby, Robert H. Morris, Ravindranath Ramachandran, and Marcel Schlaf pp 1555 - 1562; DOI: 10.1021/ic971050g |
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Dicompartmental Ligands with Hexa- and Tetradentate Coordination Sites: One-Step Synthesis of Ligands and Metal Complexes and Their X-ray Structure Analysis Elena V. Rybak-Akimova, Nathaniel W. Alcock, and Daryle H. Busch pp 1563 - 1574; DOI: 10.1021/ic9712737 |
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Synthesis of New Binucleating Cylindrical Macrotricyclic Ligands Where Two Cyclam Rings Are in a Face-to-Face Conformation. Characterization of Their Dicopper(II) and Dinickel(II) Complexes Mohammed Lachkar, Roger Guilard, Aziz Atmani, André De Cian, Jean Fischer, and Raymond Weiss pp 1575 - 1584; DOI: 10.1021/ic9708327 |
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Molecular Recognition with Lanthanide(III) Tris(-diketonate) Complexes: Extraction, Transport, and Chiral Recognition of Unprotected Amino Acids Hiroshi Tsukube, Satoshi Shinoda, Jun'ichi Uenishi, Tatsuya Kanatani, Hiroyuki Itoh, Mihoko Shiode, Tadashi Iwachido, and Osamu Yonemitsu pp 1585 - 1591; DOI: 10.1021/ic970103r |
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Design and Synthesis of a Transition Metal Responsive Semisynthetic Myoglobin-Bearing Iminodiacetic Acid Moiety Itaru Hamachi, Tomoaki Matsugi, Kengo Wakigawa, and Seiji Shinkai pp 1592 - 1597; DOI: 10.1021/ic961474v |
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Quenching of Guanine Oxidation by Oxoruthenium(IV): Effects of Divalent Cations on Chemical Nuclease Studies Suzanne A. Ciftan, Dimitrios P. Hondros, and H. Holden Thorp pp 1598 - 1601; DOI: 10.1021/ic9711372 |
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Comparative Kinetics of Oxo Transfer to Substrate Mediated by Bis(dithiolene)dioxomolybdenum and -tungsten Complexes Gregory C. Tucci, James P. Donahue, and R. H. Holm pp 1602 - 1608; DOI: 10.1021/ic971426q |
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Chelation Processes to an Oxorhenium(V) Center by N,N,N,O-Tetradentate and N,N,O-Tridentate Ligands As Verified by Structural and Mechanistic Studies of Intermediate Species J. Mattheus Botha, Keisuke Umakoshi, Yoichi Sasaki, and Gert J. Lamprecht pp 1609 - 1615; DOI: 10.1021/ic971477n |
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One-Electron Transfer Reactions of 10-Methyl-9,10-dihydroacridine and the Kinetic Isotope Effects for the Intervening Ionization and Protonation of a Carbon Acid Oleg Pestovsky, Andreja Bakac, and James H. Espenson pp 1616 - 1622; DOI: 10.1021/ic971244w |
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Unexpected Mechanism for Substitution of Coordinated Dihydrogen in trans-[FeH(H2)(DPPE)2]+ Manuel G. Basallote, Joaquín Durán, M. Jesús Fernández-Trujillo, Gabriel González, M. Angeles Máñez, and Manuel Martínez pp 1623 - 1628; DOI: 10.1021/ic970493h |
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New Stereoselective Routes to Macrocyclic Ligands Paul V. Bernhardt and and Philip C. Sharpe pp 1629 - 1636; DOI: 10.1021/ic971020d |
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Tightening the Hydrophobic Belt: Effects of Backbone and Donor Group Variation on Podand Ligand Complexes of the Lanthanides Mark P. Lowe, P. Caravan, Steven J. Rettig, and Chris Orvig pp 1637 - 1647; DOI: 10.1021/ic971488g |
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Wavelength-Dependent Photochemistry of W(CO)4(en) (en = Ethylenediamine): Evidence for Distinct Chemical Reactivities from Singlet and Triplet Ligand Field Excited States Rahul S. Panesar, Nicholas Dunwoody, and Alistair J. Lees pp 1648 - 1650; DOI: 10.1021/ic9707669 |
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Silver(I) Assisted Metal Exchange Reaction. A Generalized Synthesis of Tris-Chelated Copper(II) Complexes of Neutral N,N-Donors Partha Majumdar, Amit K. Ghosh, Larry R. Falvello, Shie-Ming Peng, and Sreebrata Goswami pp 1651 - 1654; DOI: 10.1021/ic970819m |
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Reactions of Diethylaminodimethylaluminum Dimer with the Tripodal Ligands CH3C(CH2NH2)2(CH2OH) and CH3C(CH2NH2)(CH2OH)(CH2SPh): Crystal Structure of [AlMe2]3Al[CH3C(CH2NH)2(CH2O)]2 Mung-Dar Li, Chung-Cheng Chang, Michael Y. Chiang, and Shiu-Tzung Liu pp 1655 - 1657; DOI: 10.1021/ic971084o |
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Synthesis and Properties of Osmium(II) Porphyrin Oligomers Linked by 3-Pyridylporphyrins Nobuko Kariya, Taira Imamura, and Yoichi Sasaki pp 1658 - 1660; DOI: 10.1021/ic971182+ |
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Polytopal Isomerism of the [Cd(S{O}CPh)3]- Anion Philip A. W. Dean and, Jagadese J. Vittal, Don C. Craig, and Marcia L. Scudder pp 1661 - 1664; DOI: 10.1021/ic971195n |
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Structure of Tetrameric Aqua Ruthenium(IV): an Investigation by Ruthenium K Edge EXAFS Julian R. Osman, Joe A. Crayston, and David T. Richens pp 1665 - 1668; DOI: 10.1021/ic9711271 |
Issue 8
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(Ph4P)4[Pd7As10S22]: A Sulfosalt with a Large Cluster Anion Whose Structure Resembles a Gondola Jason A. Hanko, Jun-Hong Chou, and Mercouri G. Kanatzidis pp 1670 - 1671; DOI: 10.1021/ic9801185 |
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Chemistry of Azoimidazoles: Synthesis, Spectral Characterization, Electrochemical Studies, and X-ray Crystal Structures of Isomeric Dichloro Bis[1-alkyl-2-(arylazo)imidazole] Complexes of Ruthenium(II) Tarun Kumar Misra, Debasis Das, Chittaranjan Sinha, Prasanta Ghosh, and Chandan Kumar Pal pp 1672 - 1678; DOI: 10.1021/ic970446p |
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Synthesis and Study of Monomeric and Dimeric Boronates by Spectroscopic Methods and X-ray Crystallography Herbert Höpfl, Mario Sánchez, Victor Barba, Norberto Farfán, Susana Rojas, and Rosa Santillan pp 1679 - 1692; DOI: 10.1021/ic970886g |
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Structure and Nonrigidity of B9H92- and B9H10-. Comparisons of BnHn2- and BnHn+1- Systems Alexander M. Mebel, Paul von Ragué Schleyer, Katayoun Najafian, and Oleg P. Charkin pp 1693 - 1703; DOI: 10.1021/ic970940t |
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Tellurium Compounds: Selective Inhibition of Cysteine Proteases and Model Reaction with Thiols Amnon Albeck, Hana Weitman, Benjamin Sredni, and Michael Albeck pp 1704 - 1712; DOI: 10.1021/ic971456t |
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A Family of (N-Salicylidene--amino acidato)vanadate Esters Incorporating Chelated Propane-1,3-diol and Glycerol: Synthesis, Structure, and Reaction Sujit Mondal, Sankar Prasad Rath, Kajal Krishna Rajak, and Animesh Chakravorty pp 1713 - 1719; DOI: 10.1021/ic971277b |
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Ethylene Ligand Structures of Os(CO)4(C2H4) and Os2(CO)8(C2H4) Determined by 1H NMR in Liquid Crystal Solvents Bruce R. Bender, Robert T. Hembre, Jack R. Norton, and E. Elliott Burnell pp 1720 - 1728; DOI: 10.1021/ic971637v |
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EPR Spectroscopic Studies on the Formation of Chromium(V) Peroxo Complexes in the Reaction of Chromium(VI) with Hydrogen Peroxide Lianbo Zhang and Peter A. Lay pp 1729 - 1733; DOI: 10.1021/ic971069j |
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Solid-State 199Hg MAS NMR Studies of Mercury(II) Thiocyanate Complexes and Related Compounds. Crystal Structure of Hg(SeCN)2 Graham A. Bowmaker, Andrei V. Churakov, Robin K. Harris, Judith A. K. Howard, and David C. Apperley pp 1734 - 1743; DOI: 10.1021/ic9700112 |
Nature and Strength of Metal-Chalcogen Multiple Bonds in High Oxidation State Complexes scar González-Blanco, Vicenç Branchadell, Kereen Monteyne, and Tom Zieglerpp 1744 - 1748; DOI: 10.1021/ic970613l |
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16- and 18-Electron Ruthenium(II) Complexes of the Neutral, Potentially Tridentate Triamine Ligand 2,6-[Bis(dimethylamino)methyl]pyridine (NN'N) Rob A. T. M. Abbenhuis, Ignacio del Río, Michel M. Bergshoef, Jaap Boersma, Nora Veldman, Anthony L. Spek, and Gerard van Koten pp 1749 - 1758; DOI: 10.1021/ic971061+ |
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Kinetic and Thermodynamic Studies of Iron(III) and Iron(IV) -Bonded Porphyrins. Formation and Reactivity of [(OEP)Fe(R)]n+, Where OEP Is the Dianion of Octaethylporphyrin (n = 0, 1, 2, 3) and R = C6H5, 3,4,5-C6F3H2, 2,4,6-C6F3H2, C6F4H, or C6F5 Karl M. Kadish, Eric Van Caemelbecke, Elena Gueletii, Shunichi Fukuzumi, Kenichi Miyamoto, Tomoyoshi Suenobu, Alain Tabard, and Roger Guilard pp 1759 - 1766; DOI: 10.1021/ic9714706 |
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Nitridocyanometalates of CrV, MnV, and MnVI Jesper Bendix, Karsten Meyer, Thomas Weyhermüller, Eckhard Bill, Nils Metzler-Nolte, and Karl Wieghardt pp 1767 - 1775; DOI: 10.1021/ic971377h |
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Thermal Behavior and X-ray Powder Diffraction Structures of Two Polymorphic Phases of Anhydrous Yb(ClO4)3 Frédéric Favier, Jean-Louis Pascal, Frédérique Cunin, Andrew N. Fitch and, and Gavin Vaughan pp 1776 - 1780; DOI: 10.1021/ic9712683 |
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Synthesis, Characterization, and Thermal Behavior of Polydentate Ligand Adducts of Barium Trifluoroacetate William A. Wojtczak, Mark J. Hampden-Smith, and Eileen N. Duesler pp 1781 - 1790; DOI: 10.1021/ic9613220 |
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Reversible Polymerization and Cis-Trans Isomerization Equilibria in [PdCl2{Ph2P(CH2CH2O)4CH2CH2PPh2-P,P'}] Metallacrown Ethers Dale C. Smith, Jr. and Gary M. Gray pp 1791 - 1797; DOI: 10.1021/ic971249t |
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Synthesis and Properties of Cyclic Ruthenium(II) Porphyrin Tetramers Kenji Funatsu, Taira Imamura, Akio Ichimura, and Yoichi Sasaki pp 1798 - 1804; DOI: 10.1021/ic970884w |
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Theoretical Study of Transition Metal Compounds with Molybdenum- and Tungsten-Phosphorus Triple Bonds Thomas Wagener and Gernot Frenking pp 1805 - 1811; DOI: 10.1021/ic971139m |
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Synthesis and Characterization of Polyoxovanadate-Pillared Zn-Al Layered Double Hydroxides: An X-ray Absorption and Diffraction Study C. Barriga, W. Jones, P. Malet, V. Rives, and M. A. Ulibarri pp 1812 - 1820; DOI: 10.1021/ic9709133 |
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Di-tert-butyl Phosphate Complexes of Titanium Claus G. Lugmair and T. Don Tilley pp 1821 - 1826; DOI: 10.1021/ic971347e |
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Polymorphism and Phase Transition in Nanotubular Uranyl Phenylphosphonate: (UO2)3(HO3PC6H5)2(O3PC6H5)2·H2O Miguel A. G. Aranda, Aurelio Cabeza, Sebastian Bruque, Damodara M. Poojary, and Abraham Clearfield pp 1827 - 1832; DOI: 10.1021/ic9712941 |
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Analysis of Transition-Metal Compounds Containing Tetrathiafulvalene Phosphine Ligands by Fast Atom Bombardment Mass Spectrometry: Limitations and the Development of Matrix Additives for the Desorption of Multiply Charged Complexes John M. Asara, Calvin E. Uzelmeier, Kim R. Dunbar, and John Allison pp 1833 - 1840; DOI: 10.1021/ic971123w |
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Manganese Microperoxidase-8 Donald W. Low, Sakena Abedin, Grace Yang, Jay R. Winkler, and Harry B. Gray pp 1841 - 1843; DOI: 10.1021/ic971166c |
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Synthesis and Characterization of Layered Zinc Biphenylylenebis(phosphonate) and Three Mixed-Component Arylenebis(phosphonate)/Phosphates Baolong Zhang, Damodara M. Poojary, and Abraham Clearfield pp 1844 - 1852; DOI: 10.1021/ic9712380 |
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Lone Pair Functionality in Divalent Lead Compounds Liat Shimoni-Livny, Jenny P. Glusker, and Charles W. Bock pp 1853 - 1867; DOI: 10.1021/ic970909r |
Cyanide Ligand Basicities in Cp'M(L)2CN Complexes (M = Ru, Fe). Correlation between Heats of Protonation and  CNChip Nataro, Jiabi Chen, and Robert J. Angelici pp 1868 - 1875; DOI: 10.1021/ic971124o |
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Binding of Luminescent Ruthenium(II) Molecular Probes to Vesicles Ajay Jain, Wenying Xu, J. N. Demas, and B. A. DeGraff pp 1876 - 1879; DOI: 10.1021/ic971043s |
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Metal-Ligand Coupling Elements and Antiferromagnetic Superexchange in Ruthenium Dimers Mark L. Naklicki, Christopher A. White, Lisa L. Plante, Christopher E. B. Evans, and Robert J. Crutchley pp 1880 - 1885; DOI: 10.1021/ic970728p |
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Solvation Structures and Kinetics of Solvent Exchange Reactions of the Manganese(II) Ion in Six Nitriles As Studied by X-ray Diffraction, EXAFS, and NMR Techniques Yasuhiro Inada, Takashi Sugata, Kazuhiko Ozutsumi, and Shigenobu Funahashi pp 1886 - 1891; DOI: 10.1021/ic970830m |
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Ba21Ge2O5H24 and Related Phases. A Corrected Structure Type and Composition for a Zintl Phase Stabilized by Hydrogen Baoquan Huang and John D. Corbett pp 1892 - 1899; DOI: 10.1021/ic971339y |
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Distance Dependence of Electron Transfer along Artificial -Strands at 298 and 77 K S. R. L. Fernando, Gennady V. Kozlov, and Michael Y. Ogawa pp 1900 - 1905; DOI: 10.1021/ic970369y |
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Molecular Recognition of Ferrioxamine B by Host-Guest Complex Formation with Lasalocid A in Chloroform Charles D. Caldwell and Alvin L. Crumbliss pp 1906 - 1912; DOI: 10.1021/ic971038o |
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Electron Localization and Delocalization in Mixed-Valence Transition Metal Clusters: Structural and Spectroscopic Studies of Oxo-Centered Trinuclear Complexes [Fe3O(OOCCMe3)6(py)3]+/0 and [Mn3O(OOCCMe3)6(py)3]+/0 Ruowen Wu, Mehmet Poyraz, Frank E. Sowrey, Christopher E. Anson, Sigrid Wocadlo, Annie K. Powell, Upali A. Jayasooriya, Roderick D. Cannon, Tadahiro Nakamoto, Motomi Katada, and Hirotoshi Sano pp 1913 - 1921; DOI: 10.1021/ic970451t |
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Linkage Isomerization of MSCN(CDOH)2(CDO)BMe to MNCS(CDOH)2(CDO)BMe (M = Tc, Re). Crystal Structures of TcNCS(CDOH)2(CDO)BMe, ReNCS(CDOH)2(CDO)BMe, and ReSCN(CDOH)2(CDO)BMe S. Jurisson, M. M. Halihan, J. D. Lydon, C. L. Barnes, D. P. Nowotnik, and A. D. Nunn pp 1922 - 1928; DOI: 10.1021/ic971145i |
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Tl2Ch22- (Ch = Se and/or Te) Anions: X-ray Crystal Structures and Raman Spectra of (2,2,2-crypt-K+)2Tl2Se22- and (2,2,2-crypt-K+)2Tl2Te22- and Solution 77Se, 203Tl, and 205Tl NMR Spectroscopic and Theoretical Studies of Tl2Ch22-, In2Se22-, and In2Te22- Horst Borrmann, Janette Campbell, David A. Dixon, Hélène P. A. Mercier, Ayaaz M. Pirani, and Gary J. Schrobilgen pp 1929 - 1943; DOI: 10.1021/ic9710465 |
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K2La6I12Os: A New Structure Type for Isolated Clusters That Is Generated by Cation Requirements S. Uma and John D. Corbett pp 1944 - 1948; DOI: 10.1021/ic971506u |
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Mixed Chloride/Phosphine Complexes of the Dirhenium Core. 2. New Reactions Involving Dimethylphenylphosphine F. Albert Cotton, Evgeny V. Dikarev, and Marina A. Petrukhina pp 1949 - 1958; DOI: 10.1021/ic971522r |
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Even-Odd Character and Dynamic Electronic State in the Binuclear Ferrocene Derivatives with Long Alkyl Substituents Satoru Nakashima, Shinsuke Nakazaki, Hiroshi Sakai, Masanobu Watanabe, Izumi Motoyama, and Masaru Sato pp 1959 - 1966; DOI: 10.1021/ic971179q |
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Chemical Etching of Molybdenum Trioxide: A New Tailor-Made Synthesis of MoO3 Catalysts H. C. Zeng pp 1967 - 1973; DOI: 10.1021/ic971269v |
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Effect of Ancillary Ligands on the Reactivity and Structure of Zinc Polysulfido Complexes Robert J. Pafford and Thomas B. Rauchfuss pp 1974 - 1980; DOI: 10.1021/ic971564f |
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Gas-Phase Reactivity of Coordinatively Unsaturated Transition Metal Complex Ions toward Molecular Oxygen Henrik Molina-Svendsen, Gustav Bojesen, and Christine J. McKenzie pp 1981 - 1983; DOI: 10.1021/ic970345r |
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Structural and Thermochemical ab Initio Studies of Lanthanide Trihalide Molecules with Pseudopotentials Laurent Joubert, Gérard Picard, and Jean-Jacques Legendre pp 1984 - 1991; DOI: 10.1021/ic970350v |
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Silicon and Zinc Coordination to Peripheral Catechol Sites of (2,3,9,10,16,17,23,24-Octahydroxyphthalocyaninato)nickel(II). Phthalocyanine Coordination Chemistry at the Edge Michael Ruf, Andrew M. Lawrence, Bruce C. Noll, and Cortlandt G. Pierpont pp 1992 - 1999; DOI: 10.1021/ic980036g |
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Competing Exchange Interactions and Ground-State Variability: Linear Homo- and Heterotrinuclear Manganese(III, IV) Complexes with Tris(dimethylglyoximato)metalate(II) Tetraanions as Bridging Ligands Frank Birkelbach, Ulrich Flörke, Hans-Jürgen Haupt, Christian Butzlaff, Alfred X. Trautwein, Karl Wieghardt, and Phalguni Chaudhuri pp 2000 - 2008; DOI: 10.1021/ic970362g |
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Metal Dependence of the Contributions of Low-Frequency Normal Coordinates to the Sterically Induced Distortions of Meso-Dialkyl-Substituted Porphyrins Xing-Zhi Song, Laurent Jaquinod, Walter Jentzen, Daniel J. Nurco, Song-Ling Jia, Richard G. Khoury, Jian-Guo Ma, Craig J. Medforth, Kevin M. Smith, and John A. Shelnutt pp 2009 - 2019; DOI: 10.1021/ic970465z |
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Synthesis of, Characterization of, and Photoinduced Processes in Polymetallic Triad Complexes Containing Fe(II), Ru(II), and Rh(III) Metal Centers Silvia E. Ronco, David W. Thompson, Sean L. Gahan, and John D. Petersen pp 2020 - 2027; DOI: 10.1021/ic970270r |
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Acidity of Neutral Buffered 1-Ethyl-3-methylimidazolium Chloride-AlCl3 Ambient-Temperature Molten Salts Peter Koronaios, Dawn King, and Robert A. Osteryoung pp 2028 - 2032; DOI: 10.1021/ic971345u |
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Influence of Solvent Effects on the Basicity of Pentaammine(pyrazine)ruthenium(II) and Pentacyano(pyrazine)ruthenate(II) Ions: A Density Functional Study O. Yasmine Hamra, Leonardo D. Slep, José A. Olabe, and Darío A. Estrin pp 2033 - 2038; DOI: 10.1021/ic9711224 |
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Luminescent Ru(phen)n(bps)3-n2n-4 Complexes (n = 0-3) as Probes of Electrostatic and Hydrophobic Interactions with Micellar Media James W. Hackett, II and Claudia Turro pp 2039 - 2046; DOI: 10.1021/ic970801b |
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Structures and Energies of Hexa-, Hepta-, and Octacoordinate Alonium Ions AlH6+, AlH72+, and AlH83+ and Related AlH4+, AlH52+, and AlH63+ Ions George A. Olah and and Golam Rasul pp 2047 - 2050; DOI: 10.1021/ic9614982 |
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Syntheses and Electrochemical, Photophysical, and Photochemical Properties of Ruthenium(II) 4,5-Diazafluorenone Complexes and Their Ketal Derivatives Youxiang Wang, Willie Perez, Greg Y. Zheng, and D. Paul Rillema pp 2051 - 2059; DOI: 10.1021/ic970987e |
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Crystal and Molecular Structures of a Neutral Pentanuclear Copper(I)-Iodide Complex Luis I. Victoriano, María Teresa Garland, Andrés Vega, and César Lopez pp 2060 - 2062; DOI: 10.1021/ic970114k |
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Decomposition of Coordinated Acetylacetonate in Lead Zirconate Titanate (PZT) Precursor Solutions Tim Kemmitt and and Marc Daglish pp 2063 - 2065; DOI: 10.1021/ic971131c |
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Metal Ion-Coordinating Properties of 2'-Deoxyguanosine 5'-Monophosphate (dGMP2-)1 in Aqueous Solution. Quantification of Macrochelate Formation Bin Song and and Helmut Sigel pp 2066 - 2069; DOI: 10.1021/ic971185m |
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The First Zwitterionic Dinuclear Germanium(IV) Complex with Pentacoordinate Germanium Atoms: Synthesis and Crystal Structure Analysis Reinhold Tacke, Joachim Heermann, and Brigitte Pfrommer pp 2070 - 2072; DOI: 10.1021/ic9713994 |
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Synthesis and X-ray Crystallography of Rh(I) Carbonyl Complexes of Amethyrin Jonathan L. Sessler, Andreas Gebauer, Anka Guba, Markus Scherer, and Vincent Lynch pp 2073 - 2076; DOI: 10.1021/ic971018m |
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Photogeneration of Monomeric Porphyrins from the (tetraphenylporphyrin)Rh-In(octaethylporphyrin) Dissociation of the Rh-In Bond: Investigation of Their Reactions in the Picosecond-Microsecond Time Domain A. G. Coutsolelos, D. Daphnomili, W. R. Scheidt, and G. Ferraudi pp 2077 - 2079; DOI: 10.1021/ic970476s |
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A New Synthesis of Tetrathiooxalate and Its Conversion to C3S52- and C4S62- Jonathan G. Breitzer, Jun-Hong Chou, and Thomas B. Rauchfuss pp 2080 - 2082; DOI: 10.1021/ic971327c |
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Synthesis, Structure, and Magnetic Properties of a Cyclic Dimer of Bis(hexafluoroacetylacetonato){1,3-bis(N-tert-butyl-N-oxylamino)-5-tert-butylbenzene}manganese(II) Gunter Görlitz, Takashi Hayamizu, Tetsuji Itoh, Kenji Matsuda, and Hiizu Iwamura pp 2083 - 2085; DOI: 10.1021/ic971398b |
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Bond Valence Sums in Coordination Chemistry Using Oxidation-State-Independent R0 Values. A Simple Method for Calculating the Oxidation State of Iron in Fe-O Complexes Scott M. Kanowitz and Gus J. Palenik pp 2086 - 2088; DOI: 10.1021/ic971342h |
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Synthesis, Characterization, and Luminescence of Europium(III) Schiff Base Complexes Ronald D. Archer and, Huiyong Chen, and Larry C. Thompson pp 2089 - 2095; DOI: 10.1021/ic960244d |
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Dynamic Behavior of [Pd(C6F5)2(SPPynPh3-n)] Complexes: Evidence for a Turnstile Mechanism in Intramolecular Exchange Juan A. Casares and Pablo Espinet pp 2096 - 2096; DOI: 10.1021/ic980054y |
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Structural Novelties in Anionic Cluster Halide Phases. Discrete Tetrahedral A4Br3+ Ions in Two New Zirconium Bromide Structures (A = Na-Cs) Ru-Yi Qi and John D. Corbett pp 2096 - 2096; DOI: 10.1021/ic9802000 |
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Low-Spin Iron(III) Chiroporphyrins: H NMR Studies of Cyanide and Substituted Imidazole Coordination Stanis aw Woowiec, Lechosaw Latos-Grayski, Marinella Mazzanti, and Jean-Claude Marchonpp 2096 - 2096; DOI: 10.1021/ic9802707 |
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Stabilization of the Less Common (dxzdyz)4(dxy)1 Iron(III) Porphyrin Ground Electronic State: 1H NMR Investigations of Iron(III) 5,10,15,20-Tetracyclohexylporphyrin Stanis aw Woowiec, Lechosaw Latos-Grayski, Dawn Toronto, and Jean-Claude Marchonpp 2096 - 2096; DOI: 10.1021/ic980271z |
Issue 9
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Flux Synthesis of K2Cu2P4Se10: A Layered Selenophosphate with a New Cyclohexane-like [P4Se10]4- Group Konstantinos Chondroudis and Mercouri G. Kanatzidis pp 2098 - 2099; DOI: 10.1021/ic971539+ |
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Molybdocene Porphyrazines: A Peripheral Dithiolene Metallacycle Fused to a Porphyrinic Core David P. Goldberg, Sarah L. J. Michel, Andrew J. P. White, David J. Williams, Anthony G. M. Barrett, and Brian M. Hoffman pp 2100 - 2101; DOI: 10.1021/ic971498h |
An Unusual Ligand Oxidation by a (-2:2-Peroxo)dicopper Compound: 1 > 3 C-H Bond Selectivity and a Novel Bis(-alkylperoxo)dicopper IntermediateJason A. Halfen, Victor G. Young, Jr., and William B. Tolman pp 2102 - 2103; DOI: 10.1021/ic971216d |
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Nonclassical Packing of Metal Dioximates. Superexchange through a Diamagnetic Metal Cation Victor I. Ovcharenko, Sergei V. Fokin, Vladimir A. Reznikov, Vladimir N. Ikorskii, Galina V. Romanenko, and Renad Z. Sagdeev pp 2104 - 2105; DOI: 10.1021/ic971523j |
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Monomeric Alanes: Synthesis, Structure, and Thermolysis of Mes*Al(H)N(SiMe3)2 and a One-Pot Synthetic Route to Mes*2AlH (Mes* = -C6H2-2,4,6-t-Bu3) Rudolf J. Wehmschulte and Philip P. Power pp 2106 - 2109; DOI: 10.1021/ic971442n |
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Aromaticity in X3Y3H6 (X = B, Al, Ga; Y = N, P, As), X3Z3H3 (Z = O, S, Se), and Phosphazenes. Theoretical Study of the Structures, Energetics, and Magnetic Properties Eluvathingal D. Jemmis and Boggavarapu Kiran pp 2110 - 2116; DOI: 10.1021/ic970737y |
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Substituent-Induced Perturbation Symmetries and Distortions of meso-tert-Butylporphyrins Xing-Zhi Song, Walter Jentzen, Laurent Jaquinod, Richard G. Khoury, Craig J. Medforth, Song-Ling Jia, Jian-Guo Ma, Kevin M. Smith, and John A. Shelnutt pp 2117 - 2128; DOI: 10.1021/ic9711978 |
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Observation of Spontaneous Magnetization in the Layered Perovskite Ferromagnet, (p-Chloroanilinium)2CuBr4 Taketoshi Sekine, Tsunehisa Okuno, and Kunio Awaga pp 2129 - 2133; DOI: 10.1021/ic970793z |
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Intramolecular Ligand Hydroxylation: Mechanistic Studies on the Reaction of a Copper(I) Schiff Base Complex with Dioxygen Sara Ryan, Harry Adams, David E. Fenton, Michael Becker, and Siegfried Schindler pp 2134 - 2140; DOI: 10.1021/ic971010c |
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Regioselective Cleavage by a Palladium(II) Aqua Complex of a Polypeptide in Different Overall Conformations Tatjana N. Parac and Nenad M. Kosti pp 2141 - 2144; DOI: 10.1021/ic970616y |
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Diastereoselective Formation and Photophysical Behavior of a Chiral Copper(I) Phenanthroline Complex Elvira C. Riesgo, Alberto Credi, Luisa De Cola, and Randolph P. Thummel pp 2145 - 2149; DOI: 10.1021/ic971267a |
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Steric Modulation of Electrocatalytic Benzyl Alcohol Oxidation by [Ru(trpy)(R2dppi)(O)]2+ Complexes Vincent J. Catalano, Ryan A. Heck, Chad E. Immoos, Anna Öhman, and Michael G. Hill pp 2150 - 2157; DOI: 10.1021/ic971027v |
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Syntheses, Crystal Structures, and NLO Properties of New Chiral Inorganic Chromophores for Second-Harmonic Generation Géraldine Lenoble, Pascal G. Lacroix, Jean Claude Daran, Santo Di Bella, and Keitaro Nakatani pp 2158 - 2165; DOI: 10.1021/ic970481w |
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Gas-Phase Reaction of Tetraborane(10) and Ethyne: Molecular Structure of nido-1,2-C2B3H7 in the Gas Phase Mark A. Fox, Robert Greatrex, Alireza Nikrahi, Paul T. Brain, Matthew J. Picton, David W. H. Rankin, Heather E. Robertson, Michael Bühl, Linda Li, and Robert A. Beaudet pp 2166 - 2176; DOI: 10.1021/ic971395z |
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Heterobimetallic (Imido)antimony/Lithium Cages Containing [Sb(NR)3]3- Trianions Michael A. Beswick, Nick Choi, Christopher N. Harmer, Alexander D. Hopkins, Mary McPartlin, Michael A. Paver, Paul R. Raithby, Alexander Steiner, Mustafa Tombul, and Dominic S. Wright pp 2177 - 2182; DOI: 10.1021/ic971090k |
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Charge Transfer Salts Based on Polyoxometalates and Seleno-Substituted Organic Donors. Synthesis, Structure, and Magnetic Properties of (BEST)3H[PMo12O40]·CH3CN·CH2Cl2 (BEST = Bis(ethylenediseleno)tetrathiafulvalene) Eugenio Coronado, José R. Galán-Mascarós, Carlos Giménez-Saiz, Carlos J. Gómez-García, Larry R. Falvello, and Pierre Delhaès pp 2183 - 2188; DOI: 10.1021/ic971497p |
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Computational Studies of Nido-8-Vertex Boranes, Carboranes, Heteroboranes, and the Lewis Base Adduct nido-B8H10L Andrew J. Tebben, Gang Ji, Robert E. Williams, and Joseph W. Bausch pp 2189 - 2197; DOI: 10.1021/ic971536x |
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Chemical Nuclease Activity of 1,10-Phenanthroline-Copper. Isotopic Probes of Mechanism Ottilie Zelenko, James Gallagher, Y. Xu, and David S. Sigman pp 2198 - 2204; DOI: 10.1021/ic971154r |
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Extension of the Fenske-Hall Molecular Orbital Approach to Tight-Binding Band Structure Calculations: Bulk and Surface Electronic Structure of MoS2 Agnes Tan and and Suzanne Harris pp 2205 - 2214; DOI: 10.1021/ic970874v |
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Electronic Structure of Rh2S3 and RuS2, Two Very Active Hydrodesulfurization Catalysts Agnes Tan and Suzanne Harris pp 2215 - 2222; DOI: 10.1021/ic971028n |
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Calculation of the Structural, Energetic, and Spectral Properties of Alumoxane and Aluminosilicate "Drum" Molecules J. A. Tossell pp 2223 - 2226; DOI: 10.1021/ic970674j |
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Preparation, Purification, and Characterization of Binuclear Ruthenium(II) Complexes: Bridging Ligands Based on Diazafluorenes Youxiang Wang, Willie J. Perez, Greg Y. Zheng, D. Paul Rillema, and Connie L. Huber pp 2227 - 2234; DOI: 10.1021/ic970534+ |
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Synthesis of Vinylene-Co,N-Linked Multi(porphyrin)s by the Addition of Free-Base Porphyrins to a C2H2 Complex of Cobalt(III) Porphyrin and Their Oxidative Rearrangement to Vinylene-N,N'-Linked Multi(porphyrin)s Jun-ichiro Setsune, Hirokazu Takeda, Shoji Ito, Yugo Saito, Yoshihiro Ishimaru, Koji Fukuhara, Yasushi Saito, Teijiro Kitao, and Tomohiro Adachi pp 2235 - 2246; DOI: 10.1021/ic970770k |
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Synthesis, Identification, and Reactivity Properties of Symmetrical MoFe3S4 Double Cubanes with Fe-S-Fe and Fe-O-Fe Bridges Jiesheng Huang and R. H. Holm pp 2247 - 2254; DOI: 10.1021/ic971353a |
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Comprehensive 2D 1H NMR Studies of Paramagnetic Lanthanide(III) Complexes of Anthracycline Antitumor Antibiotics Xiangdong Wei and Li-June Ming pp 2255 - 2262; DOI: 10.1021/ic970741+ |
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Synthesis and Characterization of a Series of Edge-Sharing Octahedral-Tetrahedral-Octahedral Linear Trinuclear Complexes [M3(L1O)4]2+, Where M = Mn2+, Co2+, Ni2+, Cu2+, and Zn2+ and L1OH Is the "Heteroscorpionate" Ligand (2-Hydroxyphenyl)bis(pyrazolyl)methane Timothy C. Higgs, K. Spartalian, Charles J. O'Connor, Berthold F. Matzanke, and Carl J. Carrano pp 2263 - 2272; DOI: 10.1021/ic970844s |
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Regiospecificity in the Exchange Coupling of the Spins of Copper(II) Ion Coordinated with the Ring Nitrogen Atoms and N-tert-Butylaminoxyl Radical Attached as a Substituent on the Pyridine and N-Phenylimidazole Rings Yoichiro Ishimaru, Makoto Kitano, Harumi Kumada, Noboru Koga, and Hiizu Iwamura pp 2273 - 2280; DOI: 10.1021/ic970602s |
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Quantitative Photochemistry of (5-C5H5)Fe(CO)2I in Solution: Effective Heterolytic Fe-I Dissociation upon Long-Wavelength Excitation Charlene E. Borja, Vladimír Jakúbek, and Alistair J. Lees pp 2281 - 2284; DOI: 10.1021/ic971231i |
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Structures of the Copper(I) and Copper(II) Complexes of 2,9-Diphenyl-1,10-phenanthroline: Implications for Excited-State Structural Distortion Mark T. Miller, Peter K. Gantzel, and Timothy B. Karpishin pp 2285 - 2290; DOI: 10.1021/ic971164s |
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Structure, Spectra, and Reaction Energies of the Aluminum-Nitrogen (HAl-NH)2 and (H2Al-NH2)2 Rings and the (HAl-NH)4 Cluster Randall D. Davy and Henry F. Schaefer, III pp 2291 - 2295; DOI: 10.1021/ic961499u |
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Electron Exchange and the Photophysics of Metal-Quinone Complexes. 1. Synthesis and Spectroscopy of Chromium-Quinone Dyads Daniel E. Wheeler and James K. McCusker pp 2296 - 2307; DOI: 10.1021/ic971306i |
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(Nitro)Iron(III) Porphyrins. EPR Detection of a Transient Low-Spin Iron(III) Complex and Structural Characterization of an O Atom Transfer Product Orde Q. Munro and W. Robert Scheidt pp 2308 - 2316; DOI: 10.1021/ic970855l |
Structural Characterization of [(2,6-Pri2C6H3)NC(Me)C(H)C(Me)N(2,6-Pri2C6H3)K·PhCH3] : A Heavy Alkali Metal Diazapentadienyl ComplexWilliam Clegg, Elaine K. Cope, Andrew J. Edwards, and Francis S. Mair pp 2317 - 2319; DOI: 10.1021/ic970956j |
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Spectroelectrochemical Analysis of the Intervalence Band in Mixed-Valence Di- and Tetranuclear Ru Complexes by the Flow-Through Method Masa-aki Haga, Md. Meser Ali, Hiroyasu Sato, Hideaki Monjushiro, Koichi Nozaki, and Kenji Kano pp 2320 - 2324; DOI: 10.1021/ic970794r |
Issue 10
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Electron Spin-Echo Envelope Modulation Study of Imidazole-Coordinated Oxovanadium(IV) Complexes Relevant to the Active Site Structure of Reduced Vanadium Haloperoxidases Kouichi Fukui, Hiroaki Ohya-Nishiguchi, and Hitoshi Kamada pp 2326 - 2327; DOI: 10.1021/ic971453g |
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Crown-Ether-Functionalized Nickel Salicylaldimine Complexes. Structural Characterization of Their Potassium, Cesium, and Hexylammonium Derivatives and Their Use in the Transport of Amino Acids Dell T. Rosaand and D. Coucouvanis pp 2328 - 2329; DOI: 10.1021/ic971502p |
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Linear Pentaiodide in the Radical Cation Salt of a Tetrathiafulvalene Bisannulated Macrocycle Tomoyuki Akutagawa, Yukako Abe, Yu-ichiro Nezu, Takayoshi Nakamura, Mitsutoshi Kataoka, Akio Yamanaka, Kuon Inoue, Tamotsu Inabe, Christian A. Christensen, and Jan Becher pp 2330 - 2331; DOI: 10.1021/ic971623p |
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K3CeP2S8: A New Cerium Thiophosphate with One-Dimensional Anionic Chains Gilles Gauthier, Stéphane Jobic, Raymond Brec, and Jean Rouxel pp 2332 - 2333; DOI: 10.1021/ic980091p |
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Theoretical Study of the Effect of a Lewis Acid on Hydrogen Exchange Coupling in a Trihydride Metallocene: The Cp2NbH3·AlH3 System Santiago Camanyes, Feliu Maseras, Miquel Moreno, Agustí Lledós, José M. Lluch, and Juan Bertrán pp 2334 - 2339; DOI: 10.1021/ic970813x |
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Se22-, Se52-, and Se72- Ligands in [NEt4]2[As2Se6], [enH][AsSe6]·2.2.2-cryptand, [NEt4][AsSe8], and [(en)2In(SeAs(Se)Se2)]·en Donna M. Smith, Michael A. Pell, and James A. Ibers pp 2340 - 2343; DOI: 10.1021/ic971181h |
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Electron-Transfer-Induced Geometrical Isomerization of the Dinitrile Complexes cis-[Re(NCR)2(Ph2PCH2CH2PPh2)2][BF4] (R = Aryl, Alkyl): Rates, Mechanism, and Ligand Effects M. Fátima C. Guedes da Silva, João J. R. Fraústo da Silva, Armando J. L. Pombeiro, Christian Amatore, and Jean-Noël Verpeaux pp 2344 - 2350; DOI: 10.1021/ic971257+ |
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Bonding and Electronic Properties of Cs3Te22 F. Boucher and and R. Rousseau pp 2351 - 2357; DOI: 10.1021/ic9714605 |
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Synthesis, Electrochemical, and Photophysical Study of Covalently Linked Porphyrin Dimers with Two Different Macrocycles Karl M. Kadish, Ning Guo, Eric Van Caemelbecke, Antonella Froiio, Roberto Paolesse, Donato Monti, Pietro Tagliatesta, Tristano Boschi, Luca Prodi, Fabrizio Bolletta, and Nelsi Zaccheroni pp 2358 - 2365; DOI: 10.1021/ic971443f |
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NMR, Voltammetric, and Photoelectrochemical Studies on the Dark and Light-Catalyzed Reactions of -[S2Mo18O62]4- with Aryl- and Alkylphosphines Alan M. Bond, John C. Eklund, Vanda Tedesco, Truc Vu, and Anthony G. Wedd pp 2366 - 2372; DOI: 10.1021/ic971406o |
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Modeling the Oxygen-Evolving Complex of Photosystem II. Synthesis, Redox Properties, and Core Interconversion Studies of Dimanganese Complexes Having {MnIII2(-O)(-OAc)2}2+, {MnIIIMnIV(-O)2(-OAc)}2+, and {MnIV2(-O)2(-OAc)}3+ Cores with MeL as a Terminal Ligand: A New Asymmetric Mixed-Valence Core Tapan Kumar Lal and Rabindranath Mukherjee pp 2373 - 2382; DOI: 10.1021/ic971514a |
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The Fe(III), Co(III), and V(III) Complexes of the "Heteroscorpionate" Ligand (2-Thiophenyl)bis(pyrazolyl)methane Timothy C. Higgs, David Ji, Roman S. Czernuszewicz, Berthold F. Matzanke, Volker Schunemann, Alfred X. Trautwein, Madeleine Helliwell, Wilfredo Ramirez, and Carl J. Carrano pp 2383 - 2392; DOI: 10.1021/ic971151e |
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Homoleptic Selenolates of Vanadium(II), -(III), and -(IV): Generation, Trapping, and Disproportionation of Tris[tris(trimethylsilyl)silylselenolate]vanadium Christopher P. Gerlach and and John Arnold pp 2393 - 2399; DOI: 10.1021/ic971431u |
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Preparation of (2R,4R,6R,8R)-1,9-Dihydroxy-3,5,7-trioxanonane-2,4,6,8-tetracarboxylic Acid and Its Complexation with Lanthanide(III) Cations, As Studied by Multinuclear Magnetic Resonance Spectroscopy Stefan J. H. F. Arts, Joop A. Peters, and Roger A. Sheldon pp 2400 - 2404; DOI: 10.1021/ic971156b |
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Electron Configuration and Spin Distribution in Low-Spin (meso-Tetraalkylporphyrinato)iron(III) Complexes Carrying One or Two Orientationally Fixed Imidazole Ligands Mikio Nakamura, Takahisa Ikeue, Hiroshi Fujii, Tetsuhiko Yoshimura, and Kunihiko Tajima pp 2405 - 2414; DOI: 10.1021/ic9801241 |
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Synthesis and Properties of Octaethylporphinato(arenethiolato)iron(III) Complexes with Intramolecular NH···S Hydrogen Bond: Chemical Function of the Hydrogen Bond Norikazu Ueyama, Nami Nishikawa, Yusuke Yamada, Taka-aki Okamura, Shigenori Oka, Hiromu Sakurai, and Akira Nakamura pp 2415 - 2421; DOI: 10.1021/ic971140l |
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Investigations of the Factors Affecting the Stability of Dihydrogen Adducts of Platinum(II) Shannon S. Stahl, Jay A. Labinger, and John E. Bercaw pp 2422 - 2431; DOI: 10.1021/ic970944y |
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Interactions of the Antitumor Agent Molybdocene Dichloride with Oligonucleotides Margaret M. Harding, George Mokdsi, Joel P. Mackay, Michael Prodigalidad, and Sallyanne Wright Lucas pp 2432 - 2437; DOI: 10.1021/ic971205k |
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Phosphine Boranes in Coordination Chemistry: An Efficient Method for the Synthesis of Chiral and Achiral Organophosphorus Pentacarbonyltungsten Complexes Nancy Brodie and Sylvain Jugé pp 2438 - 2442; DOI: 10.1021/ic980004t |
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Molecular Chromium(III)-Lanthanide(III) Compounds (Ln = La, Ce, Pr, Nd) with a Polymeric, Ladder-Type Architecture: A Structural and Magnetic Study Silvio Decurtins, Mathias Gross, Helmut W. Schmalle, and Sylvie Ferlay pp 2443 - 2449; DOI: 10.1021/ic971493k |
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Reactions of Phosphoric Acid Triesters with Aluminum and Gallium Amides Jiri Pinkas, Helge Wessel, Yu Yang, Mavis L. Montero, Mathias Noltemeyer, Michael Fröba, and Herbert W. Roesky pp 2450 - 2457; DOI: 10.1021/ic9713036 |
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Crystals Containing Conformers: A Rare Case in Which a Solid Closely Reflects a Solution Equilibrium Mixture Enzo Alessio, Ennio Zangrando, Romeo Roppa, and Luigi G. Marzilli pp 2458 - 2463; DOI: 10.1021/ic980066j |
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Laser Flash Photolysis Studies of Nitritomanganese(III) Tetraphenylporphyrin. Reactions of O2, NO, and Pyridine with Manganese(II) Tetraphenylporphyrin Mikio Hoshino, Yutaka Nagashima, Hiroshi Seki, Malcolm De Leo, and Peter C. Ford pp 2464 - 2469; DOI: 10.1021/ic971517n |
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Attachment of Sugar Phosphates and Nucleotide Derivatives to Pyrazolylborate-Zinc Units Karl Weis, Michael Rombach, and Heinrich Vahrenkamp pp 2470 - 2475; DOI: 10.1021/ic971403b |
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High-Spin Iron(III) Tetramethylchiroporphyrins: Structural, Magnetic, and 1H NMR Studies Marinella Mazzanti, Jean-Claude Marchon, Jacek Wojaczy ski, Stanisaw Woowiec, Lechosaw Latos-Grayski, Maoyu Shang, and W. Robert Scheidtpp 2476 - 2481; DOI: 10.1021/ic9711933 |
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Iconography of Icosahedra. Calculations of Metallic Energies and Relative Stabilities of Stereoisomers of Binary Icosahedral Clusters Boon K. Teo, Alex Strizhev, Ron Elber, and Hong Zhang pp 2482 - 2495; DOI: 10.1021/ic980006d |
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Syntheses and Molecular Structures of Bis(tert-butylamido)cyclodiphosph(III)azane Cage Complexes of Thallium(I) and Indium(II) Luke Grocholl, Ingo Schranz, Lothar Stahl, and Richard J. Staples pp 2496 - 2499; DOI: 10.1021/ic9716316 |
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Reduction and Anticancer Activity of Platinum(IV) Complexes Sunhee Choi, Catherine Filotto, Mark Bisanzo, Sarah Delaney, Daniel Lagasee, Jennifer L. Whitworth, Andrew Jusko, Chengruo Li, Nicole A. Wood, Jennifer Willingham, Amy Schwenker, and Kathleen Spaulding pp 2500 - 2504; DOI: 10.1021/ic971047x |
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Investigation of the Nitric Oxide Reduction of the Bis(2,9-Dimethyl-1,10-phenanthroline) Complex of Copper(II) and the Structure of [Cu(dmp)2(H2O)](CF3SO3)2 Dat Tran, Brian W. Skelton, Allan H. White, Leroy E. Laverman, and Peter C. Ford pp 2505 - 2511; DOI: 10.1021/ic9713137 |
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Trivalent Lanthanide Chalcogenolates: Ln(SePh)3, Ln2(EPh)6, Ln4(SPh)12, and [Ln(EPh)3]n (E = S, Se). How Metal, Chalcogen, and Solvent Influence Structure Jongseong Lee, Deborah Freedman, Jonathan H. Melman, Meggan Brewer, Lei Sun, T. J. Emge, F. H. Long, and John G. Brennan pp 2512 - 2519; DOI: 10.1021/ic9716161 |
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Hydride and Gold(triphenylphosphine) Derivatives of Hexarhenium Carbido Octadecacarbonyl Jozef L. Latten, Gishun Hsu, Timothy J. Henly, Scott R. Wilson, and John R. Shapley pp 2520 - 2524; DOI: 10.1021/ic9705756 |
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Synthesis and Photophysical Properties of Zeolite-Entrapped Bisterpyridine Ruthenium(II). Dramatic Consequences of Ligand-Field-State Destabilization Anwar A. Bhuiyan and James R. Kincaid pp 2525 - 2530; DOI: 10.1021/ic970950u |
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Kinetics and Mechanisms of the Oxidation of Hydrazine by Aqueous Iodine Rong Ming Liu and Dale W. Margerum pp 2531 - 2537; DOI: 10.1021/ic970753v |
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Organometallic Derivatives of Orotic Acid. CO-Labilizing Ability of the Amido Group in Chromium and Tungsten Carbonyl Complexes Donald J. Darensbourg, Jennifer D. Draper, David L. Larkins, Brian J. Frost, and Joseph H. Reibenspies pp 2538 - 2546; DOI: 10.1021/ic980233f |
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Synthesis and Thermolytic Behavior of Mixed-Valence Homo- and Heterometallic Group 14 Alkoxides D. J. Teff, C. D. Minear, D. V. Baxter, and K. G. Caulton pp 2547 - 2553; DOI: 10.1021/ic970618i |
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Hydrolytic Synthesis of Lead Oxo Isopropoxides and Their Reaction with M(OiPr)4 (M = Ti, Zr): Comparisons and Contrasts Daniel J. Teff and Kenneth G. Caulton pp 2554 - 2562; DOI: 10.1021/ic970709f |
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Molecular Mechanics in Crystalline Media Pierluigi Mercandelli, Massimo Moret, and Angelo Sironi pp 2563 - 2569; DOI: 10.1021/ic9713339 |
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Synthesis and Characterization of Unusual Dichloro(amido)-Bridged Zirconium Complexes. X-ray Crystal Structures of (Me2N)3Zr(-Cl)2(-NMe2)Zr(NMe2)2(THF) and Cl(Me2N)2Zr(-Cl)2(-NMe2)Zr(NMe2)2(THF) Zhongzhi Wu, Jonathan B. Diminnie, and Ziling Xue pp 2570 - 2574; DOI: 10.1021/ic980046h |
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Structural Aspects of the Aluminum-Carboxylate Interaction. Molecular Structure of the Tetranuclear [(AlMe2)2(-O2C)2-1,2-C6H4]2 Adduct Janusz Lewi ski, Janusz Zachara, and Iwona Justyniakpp 2575 - 2577; DOI: 10.1021/ic9713846 |
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Molecular Mechanics Modeling of the Cobaloximes and Reevaluation of the Parameters for Modeling of the Cobalt Corrins Helder M. Marques, Collette Warden, Moses Monye, Musa S. Shongwe, and Kenneth L. Brown pp 2578 - 2581; DOI: 10.1021/ic970800j |
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[P8Se18]6-: A New Oligomeric Selenophosphate Anion with P4+ and P3+ Centers and Pyramidal [PSe3] Fragments Konstantinos Chondroudis and Mercouri G. Kanatzidis pp 2582 - 2584; DOI: 10.1021/ic980024v |
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Interpretation of the Time-Resolved Resonance Raman Spectrum of [Ru(phen)3]2+* Jon R. Schoonover, Kristin M. Omberg, John A. Moss, Stefan Bernhard, Vicki J. Malueg, William H. Woodruff, and Thomas J. Meyer pp 2585 - 2587; DOI: 10.1021/ic9702936 |
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Direct Observation of a Metastable Solid Phase of Mg/Al/CO3-Layered Double Hydroxide by Means of High Temperature in Situ Powder XRD and DTA/TG Eiji Kanezaki pp 2588 - 2590; DOI: 10.1021/ic971543l |
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Crystallographic Studies of Organosilicon Porphyrins: Stereoelectronic Effects of Axial Groups on the Nonplanarity of the Porphyrin Ring Jian-Yu Zheng, Katsuaki Konishi, and Takuzo Aida pp 2591 - 2594; DOI: 10.1021/ic971266i |
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Formation of [Cp2Ti(2-F)2AlEt2]2 and [Cp(C5H4)Ti(2-H)AlEt2]2 in the Reaction of Cp2TiF2 with AlEt3. Structure of [Cp2Ti(2-F)2AlEt2]2 Peihua Yu, Mavis L. Montero, Craig E. Barnes, Herbert W. Roesky, and Isabel Usón pp 2595 - 2597; DOI: 10.1021/ic971160n |
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Time-Resolved Infrared Studies on Two Isomeric Ruthenium(II)/Rhenium(I) Complexes Containing a Nonsymmetric Quaterpyridine Bridging Ligand Jon R. Schoonover, Andrew P. Shreve, R. Brian Dyer, Rosemary L. Cleary, Michael D. Ward, and Carlo A. Bignozzi pp 2598 - 2601; DOI: 10.1021/ic9705305 |
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Synthesis and Structure of the Heterobimetallic Ladder Complex [{(MesNH)Sn(-Nma)}2(Li·2THF)2] (Mes = 2,4,6-Me3C6H2, ma = 2-MeOC6H4) Robert E. Allan, Michael A. Beswick, Neil Feeder, Michael Kranz, Marta E. G. Mosquera, Paul R. Raithby, Andrew E. H. Wheatley, and Dominic S. Wright pp 2602 - 2604; DOI: 10.1021/ic971093x |
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An Octacationic Carboxylate-Silver(I) Cluster Complex Pingrong Wei, Thomas C. W. Mak, and David A. Atwood pp 2605 - 2607; DOI: 10.1021/ic971276j |
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Photoinduced Electron Transfer in a Trinuclear Mixed-Valence Chromophore-Quencher Compound Brian W. Pfennig, Jacob K. Goertz, Daniel W. Wolff, and Jamie L. Cohen pp 2608 - 2611; DOI: 10.1021/ic971007t |
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An Alkoxo-Hydroxo-Bridged Octanuclear Copper(II) Complex with a Hydrophobic Exterior and a Hydrophilic Metallamacrobicyclic Core Showing Selective Hydrogen-Bonding Interactions Kannappan Geetha, Munirathinam Nethaji, and Akhil R.Chakravarty pp 2612 - 2612; DOI: 10.1021/ic980308f |
Issue 11
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Synthesis, Structural Characterization, and Extradiol Oxygenation of Iron-Catecholato Complexes with Hydrotris(pyrazolyl)borate Ligands Tamako Ogihara, Shiro Hikichi, Munetaka Akita, and Yoshihiko Moro-oka pp 2614 - 2615; DOI: 10.1021/ic9716215 |
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Ruthenium(II) MLCT Excited States. Stabilization toward Ligand Loss in Rigid Media Maik Adelt, Martin Devenney, Thomas J. Meyer, David W. Thompson, and Joseph A. Treadway pp 2616 - 2617; DOI: 10.1021/ic971121b |
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A New Class of Luminescent Polypyridine Complexes of Rhenium(I) Containing cis-Carbonyl Ligands Erick Schutte, Jeffrey B. Helms, Stephen M. Woessner, John Bowen, and B. Patrick Sullivan pp 2618 - 2619; DOI: 10.1021/ic971199s |
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Complexes of Strong Bidentate Lewis Acids Derived from 2,7-Bis(1,1-dimethylethyl)fluorene-1,8-diol Okba Saied, Michel Simard, and James D. Wuest pp 2620 - 2625; DOI: 10.1021/ic9715411 |
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Mononuclear Platinum(II) and Palladium(II) Dithiolate Complexes as Chelate Metalloligands for Preparation of Heterobimetallic d8-d8 Complexes Jorge Forniés-Cámer, Anna M. Masdeu-Bultó, Carmen Claver, and Christine J. Cardin pp 2626 - 2632; DOI: 10.1021/ic970557o |
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Structure and Reactivity of [Mo3-3S-(S2)3]4+ Complexes. Quantum Chemical Calculations, X-ray Structural Characterization, and Raman Spectroscopic Measurements María J. Mayor-López and, Jacques Weber, Kaspar Hegetschweiler, Marc D. Meienberger, Felix Joho, Stefano Leoni, Reinhard Nesper, Guido J. Reiss, Walter Frank, Boris A. Kolesov, Vladimir P. Fedin, and Vladimir E. Fedorov pp 2633 - 2644; DOI: 10.1021/ic971214t |
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Clathration of Two-Dimensional Coordination Polymers: Synthesis and Structures of [M(4,4'-bpy)2(H2O)2](ClO4)2·(2,4'-bpy)2·H2O and [Cu(4,4'-bpy)2(H2O)2](ClO4)4·(4,4'-H2Bpy) (M = CdII, ZnII and bpy = Bipyridine) Ming-Liang Tong, Bao-Hui Ye, Ji-Wen Cai, Xiao-Ming Chen, and Seik Weng Ng pp 2645 - 2650; DOI: 10.1021/ic9714293 |
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Ferromagnetic Interactions in the Mn(N3)4[Ni(en)2(NO2)]2 Trinuclear Compound. Crystal Structure and Physical Properties T. M. Rajendiran, Corine Mathonière, Stéphane Golhen, Lahcène Ouahab, and Olivier Kahn pp 2651 - 2654; DOI: 10.1021/ic9708531 |
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Synthesis and Spectral Properties of Bisaxially Coordinated (Octaphenyltetraazaporphyrinato)ruthenium(II) Complexes Pavel A. Stuzhin, Serguej I. Vagin, and Michael Hanack pp 2655 - 2662; DOI: 10.1021/ic970018j |
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Synthesis and Structural Characterization of Monomeric Selenolato Complexes of Zinc, Cadmium, and Mercury G. Mugesh, Harkesh B. Singh, Rajan P. Patel, and Ray J. Butcher pp 2663 - 2669; DOI: 10.1021/ic970714j |
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Ruthenium Nitrosyl Complexes with N-Heterocyclic Ligands Simone da S. S. Borges, Celso U. Davanzo, Eduardo E. Castellano, Julio Z-Schpector, Sebastião C. Silva, and Douglas W. Franco pp 2670 - 2677; DOI: 10.1021/ic951563s |
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Studies on the Synthetic System of V/Ag/S Cluster Compounds and Structural Characterizations of V2AgS4, V2Ag2S4, and V2O2(-S)2 Complexes Hongping Zhu, Qiutian Liu, Xiaoying Huang, Tingbin Wen, Changneng Chen, and Daxu Wu pp 2678 - 2686; DOI: 10.1021/ic9715310 |
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Molecular Structure of Chlorodifluoronitrosomethane, CClF2NO, As Determined in the Gas Phase by Electron Diffraction and ab Initio Calculations Bruce A. Smart, Paul T. Brain, Heather E. Robertson, and David W. H. Rankin pp 2687 - 2692; DOI: 10.1021/ic9714044 |
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Synthesis and Electrochemical Reactivity of -Bonded and N-Substituted Cobalt Porphycenes K. M. Kadish, P. L. Boulas, M. Kisters, E. Vogel, A. M. Aukauloo, F. D'Souza, and R. Guilard pp 2693 - 2700; DOI: 10.1021/ic971534c |
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Synthesis and Characterization of Organohydrazino Complexes of Technetium, Rhenium, and Molybdenum with the {M(1-HxNNR)(2-HyNNR)} Core and Their Relationship to Radiolabeled Organohydrazine-Derivatized Chemotactic Peptides with Diagnostic Applications David J. Rose, Kevin P. Maresca, Terrence Nicholson, Alan Davison, Alun G. Jones, John Babich, Alan Fischman, Wendy Graham, Jeffery R. D. DeBord, and Jon Zubieta pp 2701 - 2716; DOI: 10.1021/ic970352f |
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The Synthesis and Characterization of Two-Dimensional Ferromagnetic Extended Structures Containing High-Spin (S = 5/2) and Low-Spin (S = 1/2) Iron(III) Bridged by Cyanide Groups Nazzareno Re, Raffaella Crescenzi, Carlo Floriani, Hitoshi Miyasaka, and Naohide Matsumoto pp 2717 - 2722; DOI: 10.1021/ic971544d |
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Synthesis and Characterization of the Series of Compounds Ru2(O2CMe)x(admp)4-xCl (Hadmp = 2-Amino-4,6-dimethylpyridine, x = 3, 2, 1, 0) F. A. Cotton and and A. Yokochi pp 2723 - 2728; DOI: 10.1021/ic971428a |
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Triethylenetetramine-N,N,N',N'',N''',N'''-hexaacetic Acid (TTHA) and TTHA-Bis(butanamide) as Chelating Agents Relevant to Radiopharmaceutical Applications Benbrahim Achour, Judite Costa, Rita Delgado, Emmanuelle Garrigues, Carlos F. G. C. Geraldes, Nikolaus Korber, Françoise Nepveu, and M. Isabel Prata pp 2729 - 2740; DOI: 10.1021/ic970921j |
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Vibrational Spectra and Molecular Association of Titanium Tetraisopropoxide Paul D. Moran, Graham A. Bowmaker, Ralph P. Cooney, Kim S. Finnie, John R. Bartlett, and James L. Woolfrey pp 2741 - 2748; DOI: 10.1021/ic9709436 |
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Structural Aspects of Rubidium Ion Selectivity by Tribenzo-21-crown-7 Jeffrey C. Bryan, Richard A. Sachleben, Jérôme M. Lavis, Matthew C. Davis, John H. Burns, and Benjamin P. Hay pp 2749 - 2755; DOI: 10.1021/ic9714908 |
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Preparation and Photophysical Properties of Amide-Linked, Polypyridylruthenium-Derivatized Polystyrene Duane A. Friesen, Toru Kajita, Earl Danielson, and Thomas J. Meyer pp 2756 - 2762; DOI: 10.1021/ic9710420 |
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Synthesis, Characterization, Absorption Spectra, and Luminescence Properties of Organometallic Platinum(II) Terpyridine Complexes Giuseppe Arena, Giuseppe Calogero, Sebastiano Campagna, Luigi Monsù Scolaro, Vittorio Ricevuto, and Raffaello Romeo pp 2763 - 2769; DOI: 10.1021/ic9704896 |
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Bonding in Mo3M'S4 Cubane-Type Clusters: Variations in Electronic Structure When M' Is a Main Group or Transition Metal Christian S. Bahn, Agnes Tan, and Suzanne Harris pp 2770 - 2778; DOI: 10.1021/ic9712378 |
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Solution Photophysics, One-Electron Photooxidation, and Photoinitiated Two-Electron Oxidation of Molybdenum(III) Complexes Abdul K. Mohammed, Ralph A. Isovitsch, and Andrew W. Maverick pp 2779 - 2785; DOI: 10.1021/ic970955r |
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Plasticity of Cl-Te-Cl Fragments. Synthesis, Single-Crystal X-ray, and NBO Study of (1-Thia-2-tellura-1-phenyl-4-chloro)cyclopentane 2,2,2-Trichloride Markku R. Sundberg, Tarja Laitalainen, Jan Bergman, Rolf Uggla, Jorma Matikainen, and Seppo Kaltia pp 2786 - 2791; DOI: 10.1021/ic970406l |
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Structure and Magnetic Properties of Antiferromagnetic Manganese(III) Tetrakis(4- methoxyphenyl)porphyrin Tetracyanoethenide, [MnTOMePP][TCNE]·2PhMe, and Manganese(III) Tetrakis(2-fluorophenyl)porphyrin Tetracyanoethenide, [MnTFPP][TCNE]·2PhMe Erik J. Brandon, Atta M. Arif, Brian M. Burkhart, and Joel S. Miller pp 2792 - 2798; DOI: 10.1021/ic9710768 |
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A Basic Electronic Model for the Study of Optical Properties of Delocalized and Partially Localized Donor-Bridge-Acceptor Systems Alessandro Ferretti, Alessandro Lami, and Giovanni Villani pp 2799 - 2805; DOI: 10.1021/ic971159o |
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Charge-Transfer Processes in (4-Nitrobenzoate)Re(CO)3(azine)2 Complexes. Competitive Reductions of 4-Nitrobenzoate and Azine in Thermally and Photochemically Induced Redox Processes M. Feliz and G. Ferraudi pp 2806 - 2810; DOI: 10.1021/ic971241j |
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Bond Lengths and Bond Angles in Oxo, Hydroxo, and Alkoxo Molecules of Be, B, and C: A Close-Packed Nearly Ionic Model Ronald J. Gillespie, Ian Bytheway, and Edward A. Robinson pp 2811 - 2825; DOI: 10.1021/ic971588m |
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Synthesis and Structural Characterization of the Nitrido-Carbonyl Cluster Anion [Co10N2(CO)9(-CO)10]4- Having an Unprecedented Metal Cage Built of Three Condensed Trigonal Prisms Alessandro Fumagalli, Secondo Martinengo, Massimo Tasselli, Gianfranco Ciani, Piero Macchi, and Angelo Sironi pp 2826 - 2828; DOI: 10.1021/ic971329x |
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Electrochemistry at Very Positive Potentials in Liquid SO2. Mononuclear RuII and OsII Polypyridine Complexes Paola Ceroni, Francesco Paolucci, Sergio Roffia, Scolastica Serroni, Sebastiano Campagna, and Allen J. Bard pp 2829 - 2832; DOI: 10.1021/ic971423d |
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Controlled Formation of Tri- and Octanuclear Benzylthiolate Complexes of Zinc Rainer Burth, Michael Gelinsky, and Heinrich Vahrenkamp pp 2833 - 2836; DOI: 10.1021/ic971402j |
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Electroabsorption and Related Spectroscopic Studies of Bimetallic Tetraiminoethylenedimacrocyclic Complexes: Corroboration of Valence Electron Delocalization Laba Karki, Robert D. Williams, Joseph T. Hupp, Christian B. Allan, and Larry O. Spreer pp 2837 - 2840; DOI: 10.1021/ic970436o |
Issue 12
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Ground and Excited State Spectroscopic Probes of [(TMP)Fe(IV)=O]+: The First Magnetic Circular Dichroism Study of a Model Peroxidase Compound I Intermediate Robert Jones, Karupiah Jayaraj, Avram Gold, and Martin L. Kirk pp 2842 - 2843; DOI: 10.1021/ic970790m |
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A Solvothermal Elemental Reaction To Produce Nanocrystalline ZnSe Yadong Li, Yi Ding, Yitai Qian, Yue Zhang, and Li Yang pp 2844 - 2845; DOI: 10.1021/ic9800637 |
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External Coordination of Europium(III) Prior to Its Encapsulation within a Cyclen-Based Pendant Donor Macrocycle Peter Valente, Stephen F. Lincoln, and Kevin P. Wainwright pp 2846 - 2847; DOI: 10.1021/ic980012+ |
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Rb4Sn2Ag4(P2Se6)3: First Example of a Quinary Selenophosphate and an Unusual Sn-Ag s2-d10 Interaction Konstantinos Chondroudis and Mercouri G. Kanatzidis pp 2848 - 2849; DOI: 10.1021/ic971468e |
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Novel Stable Metallic Salts Based on a Donor Molecule Containing peri-Ditellurium Bridges, TMTTeN Emiko Arai, Hideki Fujiwara, Hayao Kobayashi, Akiko Kobayashi, Kazuo Takimiya, Tetsuo Otsubo, and Fumio Ogura pp 2850 - 2851; DOI: 10.1021/ic9802247 |
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Phosphine Adducts of Monomeric Zinc(bis-phenoxides): Solution and Solid-State Structures of (2,6-Di-tert-butylphenoxide)ZnL Complexes (L = PMePh2 and PCy3) Donald J. Darensbourg, Marc S. Zimmer, Patrick Rainey, and David L. Larkins pp 2852 - 2853; DOI: 10.1021/ic980185z |
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Compounds That Contract on Heating A. W. Sleight pp 2854 - 2860; DOI: 10.1021/ic980253h |
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Thermochemistry of Sulfur Atom Transfer. Enthalpies of Reaction of Phosphines with Sulfur, Selenium, and Tellurium, and of Desulfurization of Triphenylarsenic Sulfide, Triphenylantimony Sulfide, and Benzyl Trisulfide Kenneth B. Capps, Bodo Wixmerten, Andreas Bauer, and Carl D. Hoff pp 2861 - 2864; DOI: 10.1021/ic9715862 |
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1H NMR and EPR Studies of [M(NH3)5(H2O)](TFMS)3 (M = Ru, Os). Theory of the Paramagnetic Shift for Strong Field d5 Complexes B. R. McGarvey, N. C. Batista, C. W. B. Bezerra, M. S. Schultz, and D. W. Franco pp 2865 - 2872; DOI: 10.1021/ic9714394 |
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Metal Ion Binding to Octakis(dimethylamino)porphyrazine: Core Coordination of Mn(III) and Peripheral Coordination of Pd(II) David P. Goldberg, Antonio Garrido Montalban, Andrew J. P. White, David J. Williams, Anthony G. M. Barrett, and Brian M. Hoffman pp 2873 - 2879; DOI: 10.1021/ic970624e |
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Luminescent Photofragments of (1,1,1,5,5,5-Hexafluoro-2,4-pentanedionato) Metal Complexes in the Gas Phase David S. Talaga, Stephen D. Hanna, and Jeffrey I. Zink pp 2880 - 2887; DOI: 10.1021/ic971340x |
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Electrostatic Modulation of Ligand Binding and Electrochemical Properties of Myoglobin: The Role of Charge Compensation Emma Lloyd, Bertha C. King, Fred M. Hawkridge, and A. Grant Mauk pp 2888 - 2892; DOI: 10.1021/ic9710824 |
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Identification of the Limiting Species in the Plutonium(IV) Carbonate System. Solid State and Solution Molecular Structure of the [Pu(CO3)5]6- Ion David L. Clark, Steven D. Conradson, D. Webster Keogh, Phillip D. Palmer, Brian L. Scott, and C. Drew Tait pp 2893 - 2899; DOI: 10.1021/ic971190q |
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The First Trigonal Planar Transition Metal-Hydrogen Complex in NaBaPdH3 Malin Olofsson, Mikael Kritikos, and Dag Noréus pp 2900 - 2902; DOI: 10.1021/ic971386q |
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Influence of the Bridging Group of Cross-Conjugated Nitrogenous Bases on the Spectra and Structure of Solvatochromic Mixed-Ligand Copper(II) Chelates Containing -Ketoenols Chris Tsiamis, Antonis G. Hatzidimitriou, and Leandros C. Tzavellas pp 2903 - 2909; DOI: 10.1021/ic961475n |
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New Class of Oligonuclear Platinum-Thallium Compounds with a Direct Metal-Metal Bond. 2. Structural Characterization of the Complexes Mikhail Maliarik, Katja Berg, Julius Glaser, Magnus Sandström, and Imre Tóth pp 2910 - 2919; DOI: 10.1021/ic970667v |
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Hydroxamate-Bridged Dinuclear Nickel Complexes as Models for Urease Inhibition M. Arnold, David A. Brown, O. Deeg, W. Errington, W. Haase, K. Herlihy, T. J. Kemp, H. Nimir, and R. Werner pp 2920 - 2925; DOI: 10.1021/ic9711628 |
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The Mixed-Valence Double-Cubanoid Cluster [Fe8S12(ButNC)12]: Synthesis, Structure, and Exchange Coupling of a New Structural Array of Four Fe(III) Sites C. Goh, A. Nivorozhkin, S. J. Yoo, E. L. Bominaar, E. Münck, and R. H. Holm pp 2926 - 2932; DOI: 10.1021/ic980085t |
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Mono-, Bi-, and Trinuclear Metallocyclophanes Formed in Reactions between [Mo(NO){HB(3,5-Me2C3HN2)3}I2] and Xylenedithiols. The X-ray Crystal Structures of [Mo(NO){HB(3,5-Me2C3HN2)3}{1,4-(SCH2)2C6H4}n] (n = 2, 3) Helen A. Hinton, Hongli Chen, Thomas A. Hamor, Christopher J. Jones, Ferida S. McQuillan, and Malcolm S. Tolley pp 2933 - 2942; DOI: 10.1021/ic971357f |
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Functional Models for Catechol 1,2-Dioxygenase. Synthesis, Structure, Spectra, and Catalytic Activity of Certain Tripodal Iron(III) Complexes Rathinam Viswanathan, Mallayan Palaniandavar, Thailampillai Balasubramanian, and Thomas P. Muthiah pp 2943 - 2951; DOI: 10.1021/ic970708n |
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Characterization of Mercury(II) Complexes of Bis[(2-pyridyl)methyl]amine by X-ray Crystallography and NMR Spectroscopy Deborah C. Bebout, Anne E. DeLanoy, David E. Ehmann, Margaret E. Kastner, Damon A. Parrish, and Raymond J. Butcher pp 2952 - 2959; DOI: 10.1021/ic971499+ |
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(Pyrazolato)gold Complexes Showing Room-Temperature Columnar Mesophases. Synthesis, Properties, and Structural Characterization Joaquín Barberá, Anabel Elduque, Raquel Giménez, Fernando J. Lahoz, José A. López, Luis A. Oro, and José L. Serrano pp 2960 - 2967; DOI: 10.1021/ic971632y |
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Preparation and Characterization of Trimethylgermanium-Sulfur Compounds Derived from 2-Dithiocarbamoyl-3-dithiocarbonylthiopropionate. Crystal Structures of [NH4]3[S2CSCH2CH(NHCS2)CO2] and Me3GeO2C(-CHNHC(S)SCH2-) John E. Drake and and Jincai Yang pp 2968 - 2974; DOI: 10.1021/ic971331o |
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Protonation of Metal-Metal Bonds in Cp2Ru2(CO)3(PR3) and Cp2Mo2(CO)4(PR3)2 Chip Nataro and Robert J. Angelici pp 2975 - 2983; DOI: 10.1021/ic971516v |
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Oxidation of Iron(III) Tetramesitylporphyrin with Dimethyldioxirane Stanis aw Woowiec and Lechosaw Latos-Grayskipp 2984 - 2988; DOI: 10.1021/ic9715963 |
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Preparation, Structure, and Properties of the Arsenic-Containing Corner-Shared Double Cube [Mo6AsS8(H2O)18]8+: Metal-Metal Bonding and a Classification of Different Cluster Types Rita Hernandez-Molina, Andrew J. Edwards, William Clegg, and A. Geoffrey Sykes pp 2989 - 2994; DOI: 10.1021/ic971570b |
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Preparation, Structure, and Reactivity of Heterometallic Sn-Containing Single- and Double-Cube Derivatives of [Mo3Se4(H2O)9]4+ and [W3Se4(H2O)9]4+ Rita Hernandez-Molina, Danil N. Dybtsev, Vladimir P. Fedin, Mark R. J. Elsegood, William Clegg, and A. Geoffrey Sykes pp 2995 - 3001; DOI: 10.1021/ic980047+ |
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XeF2·2CrF4 and XeF5+CrF5-: Syntheses, Crystal Structures, and Some Properties Karel Lutar, Horst Borrmann, and Boris  emvapp 3002 - 3006; DOI: 10.1021/ic971580c |
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A Versatile Synthetic Approach to Rhodium(III) Diimine Metallointercalators: Condensation of o-Quinones with Coordinated cis-Ammines Hansruedi Mürner, Brian A. Jackson, and Jacqueline K. Barton pp 3007 - 3012; DOI: 10.1021/ic9800738 |
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Unusual Hydrogen Bonds with a Hydride Atom in Boron Hydrides Acting as Proton Acceptor. Spectroscopic and Theoretical Studies Lina M. Epstein, Elena S. Shubina, Ekaterina V. Bakhmutova, Liliya N. Saitkulova, Vladimir I. Bakhmutov, Anatolii L. Chistyakov, and Ivan V. Stankevich pp 3013 - 3017; DOI: 10.1021/ic971461x |
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Theory of d10-d10 Closed-Shell Attraction. III. Rings Pekka Pyykkö and Fernando Mendizabal pp 3018 - 3025; DOI: 10.1021/ic980121o |
Excited-State Enantiomer Interconversion Kinetics Probed by Time-Resolved Chiroptical Luminescence Spectroscopy. The Solvent and Temperature Dependence of  -Eu(dpa)33-   -Eu(dpa)33- Enantiomer Interconversion Rates in SolutionDeborah P. Glover-Fischer, David H. Metcalf, Todd A. Hopkins, Vincent J. Pugh, Sarah J. Chisdes, Jouko Kankare, and F. S. Richardson pp 3026 - 3033; DOI: 10.1021/ic9713700 |
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Ring Structure Formation in Transition-Metal Nitrido Chlorides by Donor-Acceptor Formation Wolfgang W. Schoeller and Andreas Sundermann pp 3034 - 3039; DOI: 10.1021/ic9712129 |
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A Novel Series of Heterotrinuclear Complexes Involving Imidazolate Bridging Schiff's Base Ligands. Synthesis, Crystal Structure, and Magnetic Properties Enrique Colacio, Jose Manuel Dominguez-Vera, Mustapha Ghazi, Raikko Kivekäs, Martti Klinga, and José María Moreno pp 3040 - 3045; DOI: 10.1021/ic970992i |
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A New Mononuclear Copper(II) Complex Containing Two Imidazolyl Moieties as Precursor of Self-Assembled and NiIICuIINiII Heterobimetallic Complexes Jose M. Dominguez-Vera, Fernando Camara, Jose M. Moreno, Enrique Colacio, and Helen Stoeckli-Evans pp 3046 - 3050; DOI: 10.1021/ic971055d |
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New Semiquinone/Catecholate Complexes That Exhibit Valence Tautomerism. Synthesis and Characterization of MnIII(thf)2(3,6-DBSQ)(3,6-DBCat) and Observations on the MnIV(3,6-DBSQ)2(3,6-DBCat)/MnIII(3,6-DBSQ)3 Equilibrium in the Solid State Attia S. Attia and Cortlandt G. Pierpont pp 3051 - 3056; DOI: 10.1021/ic971192a |
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Chemical Applications of Topology and Group Theory. 33. Symmetry-Forbidden Coordination Polyhedra for Spherical Atomic Orbital Manifolds R. B. King pp 3057 - 3059; DOI: 10.1021/ic9701569 |
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Synthesis of a Heptanuclear Rhenium-Iridium Carbido Carbonyl Cluster and of (Triphenylphosphine)gold(I) Derivatives Linqing Ma, Udo Brand, and John R. Shapley pp 3060 - 3065; DOI: 10.1021/ic9706109 |
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63Cu NMR Study of Copper(I) Carbonyl Complexes with Various Hydrotris(pyrazolyl)borates: Correlation between 63Cu Chemical Shifts and CO Stretching Vibrations Sadako Imai, Kiyoshi Fujisawa, Takako Kobayashi, Nobuhiko Shirasawa, Hiroshi Fujii, Tetsuhiko Yoshimura, Nobumasa Kitajima, and Yoshihiko Moro-oka pp 3066 - 3070; DOI: 10.1021/ic970138r |
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Ab Initio Study of the Relative Basicity of the External Oxygen Sites in M2W4O194- (M = Nb and V) Juan Miguel Maestre, Jose Pedro Sarasa, Carles Bo, and Josep M. Poblet pp 3071 - 3077; DOI: 10.1021/ic960222r |
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Ground-State Interactions between Ruthenium(II)-Diimine Complexes and Phenol and Monochlorophenols in Aqueous Solution Cang Li, Morton Z. Hoffman, Christine Pizzocaro, Gilles Maihot, and Michèle Bolte pp 3078 - 3082; DOI: 10.1021/ic971471y |
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51V Chemical Shielding and Quadrupole Coupling in Ortho- and Metavanadates from 51V MAS NMR Spectroscopy J  rgen Skibsted, Claus J. H. Jacobsen, and Hans J. Jakobsenpp 3083 - 3092; DOI: 10.1021/ic971503h |
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Nonradiative Transition of Phosphorescent Charge-Transfer States of Ruthenium(II)-to-2,2'-Biquinoline and Ruthenium(II)-to-2,2':6',2''-Terpyridine in the Solid State Ashraful Islam, Noriaki Ikeda, Akio Yoshimura, and Takeshi Ohno pp 3093 - 3098; DOI: 10.1021/ic9702429 |
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The Application of Density Functional Theory to Four Problems in Inorganic Chemistry: A Comparison to Traditional ab Initio Methods Lisa W. Mire, Sherrie D. Wheeler, Eugene Wagenseller, and Dennis S. Marynick pp 3099 - 3106; DOI: 10.1021/ic971230q |
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Electronic Structures of Nitridomanganese(V) Complexes Christopher J. Chang, William B. Connick, Donald W. Low, Michael W. Day, and Harry B. Gray pp 3107 - 3110; DOI: 10.1021/ic970598k |
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Spectroscopic Analysis of the Complexes of the Eu3+ Ion with 1-Hydroxyethane-1,1-diphosphonic Acid in the Solid State and in a 2 M NaNO3 Solution Pascale Martello, Willem D'Olieslager, and Christiane Görller-Walrand pp 3111 - 3115; DOI: 10.1021/ic971624h |
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Electron Distribution in the Two-Electron Reduced Isopolytungstate [W10O32]6- S. A. Borshch pp 3116 - 3118; DOI: 10.1021/ic971396r |
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[(-OCH3)VO(ma)]2, a Strongly Antiferromagnetic Oxovanadium(IV) Dimer Yan Sun, Marco Melchior, David A. Summers, Robert C. Thompson, Steven J. Rettig, and Chris Orvig pp 3119 - 3121; DOI: 10.1021/ic971549a |
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Reactions of the Dirhenium(II) Complexes Re2X4(-dppm)2 (X = Cl, Br; dppm = Ph2PCH2PPh2) with Isocyanides. 16.1 Complexes of the Type [Re2(-Br)2(-dppm)2Br(CO)(CNXyl)2]Y (Y = O3SCF3, PF6) That Exist in Isomeric Forms with Boat and Chair Conformations for the [Re2(-dppm)2] Unit Wengan Wu, Phillip E. Fanwick, and Richard A. Walton pp 3122 - 3126; DOI: 10.1021/ic971483j |
Issue 13
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Synthesis, Structure, and Characterization of the New [L(OH)Fe(-O)Fe(OH2)L]3+ Complex (L = N,N'-Dimethyl-N,N'-bis(2-pyridylmethyl)ethane-1,2-diamine). Detection of an Equilibrium with the Protonated Diamond Form [LFe(-O)(-OH)FeL]3+ in Acetonitrile Sandrine Poussereau, Geneviève Blondin, Michèle Cesario, Jean Guilhem, Geneviève Chottard, Florence Gonnet, and Jean-Jacques Girerd pp 3127 - 3132; DOI: 10.1021/ic971589e |
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A 1H NMR Study of the DNA Binding of Ruthenium(II) Polypyridyl Complexes J. Grant Collins, Andrew D. Sleeman, Janice R. Aldrich-Wright, Ivan Greguric, and Trevor W. Hambley pp 3133 - 3141; DOI: 10.1021/ic971194v |
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Polynuclear Nickel(II) Complexes: Preparation, Characterization, Magnetic Properties, and Quantum-Chemical Study of [Ni5(OH)(Rbta)5(acac)4(H2O)4] (RbtaH = Benzotriazole and 5,6-Dimethylbenzotriazole) Vasilis Tangoulis, Catherine P. Raptopoulou, Aris Terzis, Evangelos G. Bakalbassis, Eleanna Diamantopoulou, and Spyros P. Perlepes pp 3142 - 3153; DOI: 10.1021/ic9714091 |
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Synthesis, Unusual Trigonal Prismatic Geometry, and Theoretical Study of the Homoleptic Tris-(2,2'-biphosphinine) Complexes of Chromium, Molybdenum, and Tungsten Patrick Rosa, Louis Ricard, Pascal Le Floch, François Mathey, Gjergji Sini, and Odile Eisenstein pp 3154 - 3158; DOI: 10.1021/ic980042c |
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An EPR Spectroscopic Study of Chromium(V) Oxalato Complexes in Aqueous Solutions. Mechanism of the Chromium(VI) Oxidation of Oxalic Acid Rodney P. Farrell, Peter A. Lay, Aviva Levina, Ian A. Maxwell, Richard Bramley, Steven Brumby, and Ji-Ying Ji pp 3159 - 3166; DOI: 10.1021/ic971070i |
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Prediction of Magnetic Properties in Oxovanadium(IV) Phosphates: The Role of the Bridging PO4 Anions Manuel Roca, Pedro Amorós, Juan Cano, M. Dolores Marcos, Jaime Alamo, Aurelio Beltrán-Porter, and Daniel Beltrán-Porter pp 3167 - 3174; DOI: 10.1021/ic971210o |
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Hydroxylaminosilanes: Compounds with -Donor-Acceptor Bonds Udo Losehand and Norbert W. Mitzel pp 3175 - 3182; DOI: 10.1021/ic971508e |
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The Electronic Structure of the Tris(diaminophosphanyl)carbenium Ion. A Quantum Chemical Investigation Wolfgang W. Schoeller and Ulrike Tubbesing pp 3183 - 3185; DOI: 10.1021/ic9701524 |
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Synthesis of Various Cationic Ruthenium-Aqua Complexes with Hydrotris(3,5-diisopropylpyrazolyl)borate Ligand, TpiPrRu(OH2)n(L)3-n·(CF3SO3)(THF)x, and Their Structures Supported by Hydrogen-Bonding Networks Yoshiaki Takahashi, Munetaka Akita, Shiro Hikichi, and Yoshihiko Moro-oka pp 3186 - 3194; DOI: 10.1021/ic9801802 |
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Taking Advantage of Right Angles in N1,N7-Diplatinated Purine Nucleobases: Toward Molecular Squares, Rectangles, and Meanders Marc Sven Lüth, Eva Freisinger, Frank Glahé, Jens Müller, and Bernhard Lippert pp 3195 - 3203; DOI: 10.1021/ic980081o |
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(CN3H6)2·(VO2)3(PO4)(HPO4), a Layered Guanidinium Vanadium(V) Phosphate Related to Hexagonal Tungsten Oxide Zsolt Bircsak and William T. A. Harrison pp 3204 - 3208; DOI: 10.1021/ic9710216 |
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Tunable Radiationless Energy Transfer in Eu[Au(CN)2]3·3H2O by High Pressure Hartmut Yersin, Dietrich Trümbach, Johann Strasser, Howard H. Patterson, and Zerihun Assefa pp 3209 - 3216; DOI: 10.1021/ic980252p |
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Structural and Magnetic Properties of Dicopper(II) Complexes of Polydentate Diazine Ligands Laurence K. Thompson, Zhiqiang Xu, Andrés E. Goeta, Judith A. K. Howard, Howard J. Clase, and David O. Miller pp 3217 - 3229; DOI: 10.1021/ic9715198 |
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From Discrete Metal-Oxygen Clusters to Open-Framework Structure: Syntheses and Characterization of Cs2Mo2O5As2O7·H2O, Cs2Mo2O5(HAsO4)2·H2O, and Cs4Mo6O18(H2O)(HAsO4)2·2.5H2O Kuei-Fang Hsu and Sue-Lein Wang pp 3230 - 3235; DOI: 10.1021/ic971562v |
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Nitrogen Base Adducts with Silver(I) p-Toluenesulfonate: Syntheses and Single Crystal X-ray Characterizations of the Adducts with Pyridine (1:1), 2-Aminopyridine (1:2), 2-Aminopyrimidine (1:1), 4,6-Dimethyl-2-aminopyrimidine (2:3), and 3-Aminobenzoic Acid (1:2) and the Crystal Structure of the Parent Silver(I) p-Toluenesulfonate Graham Smith, Brett A. Cloutt, Daniel E. Lynch, Karl A. Byriel, and Colin H. L. Kennard pp 3236 - 3242; DOI: 10.1021/ic9706461 |
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Study of the Two-Dimensional [MM'(C3H2O4)2(H2O)4] (M = Ba, Sr and M' = Cu, Mn) Systems: Synthesis, Structure, Magnetic Properties, and Thermal Decomposition I. Gil de Muro, F. A. Mautner, M. Insausti, L. Lezama, M. I. Arriortua, and T. Rojo pp 3243 - 3251; DOI: 10.1021/ic9800132 |
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Crystal Structure and Raman Spectroscopy of FeVMoO7 and CrVMoO7 with Mo=O Double Bonds Xiandong Wang, Kevin R. Heier, Charlotte L. Stern, and Kenneth R. Poeppelmeier pp 3252 - 3256; DOI: 10.1021/ic980100u |
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Facile Reduction of Tungsten Halides with Nonconventional, Mild Reductants. I. Tungsten Tetrachloride: Several Convenient Solid-State Syntheses, a Solution Synthesis of Highly Reactive (WCl4)x, and the Molecular Structure of Polymeric Tungsten Tetrachloride Vladimir Kolesnichenko, Dale C. Swenson, and Louis Messerle pp 3257 - 3262; DOI: 10.1021/ic9801286 |
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Hybrid Sulfanuric-Phosphazene Ring Systems: Synthesis, Spectroscopic Characterization, and X-ray Structures of trans-Ph4P2N4[S(O)R]2 (R = Ph, Me), cis-Ph4P2N4[S(O)Me]2, and R4P2N4(SNMe2)2 (R = Ph, Et) Michele Brock, Tristram Chivers, and Masood Parvez pp 3263 - 3268; DOI: 10.1021/ic971620c |
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Syntheses and Characterizations of Alkyl- and Amidotin Porphyrin Complexes: Molecular Structure of trans-Bis(phenylacetylido)(meso-tetra-p-tolylporphyrinato)tin(IV) Jinyuan Chen and L. Keith Woo pp 3269 - 3275; DOI: 10.1021/ic980079x |
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Partial Insertion of the 9-BBN Unit into the nido-B10 Framework: Preparation and Structural Characterization of (9-BBN)B10H13 and [(9-BBN)B10H12]- Adam N. Bridges, Jianping Liu, Roman G. Kultyshev, Donald F. Gaines, and Sheldon G. Shore pp 3276 - 3283; DOI: 10.1021/ic980171t |
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Stabilization of High Oxidation States in Transition Metals. 2.1 WCl6 Oxidizes [WF6]-, but Would PtCl6 Oxidize [PtF6]-? An Electrochemical and Computational Study of 5d Transition Metal Halides: [MF6]z versus [MCl6]z (M = Ta to Pt; z = 0, 1-, 2-) Stuart A. Macgregor and Klaus H. Moock pp 3284 - 3292; DOI: 10.1021/ic9605736 |
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Cyclic Hydroborate Complexes of Metallocenes III. Syntheses and Structures of Zirconocene Boracyclohexane Derivatives Cp2Zr(X){(-H)2BC5H10} (X = H, CH3, H2BC5H10) Fu-Chen Liu, Jianping Liu, Edward A. Meyers, and Sheldon G. Shore pp 3293 - 3300; DOI: 10.1021/ic9803917 |
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The [Mn2(2-OHsalpn)2]2-,1-,0 System: An Efficient Functional Model for the Reactivity and Inactivation of the Manganese Catalases Andrew Gelasco, Stephan Bensiek, and Vincent L. Pecoraro pp 3301 - 3309; DOI: 10.1021/ic980022a |
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Molecular Mechanics Calculations and the Metal Ion Selective Extraction of Lanthanoids Peter Comba, Karsten Gloe, Katsutoshi Inoue, Torsten Krüger, Holger Stephan, and Kazuharu Yoshizuka pp 3310 - 3315; DOI: 10.1021/ic970673r |
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Electronic Spectroscopy of (CO)5W-Al[(R)Do2] Complexes Jurij Weiss, Roland A. Fischer, Yanick Pelletier, and Christian Reber pp 3316 - 3320; DOI: 10.1021/ic970614d |
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Cis,trans,cis or All-cis Geometry in d0 Octahedral Dioxo Complexes. An IMOMM Study of the Role of Steric Effects Guada Barea, Agusti Lledos, Feliu Maseras, and Yves Jean pp 3321 - 3325; DOI: 10.1021/ic971226e |
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Equilibrium Metal Binding of the Translational Activating Protein, COM Robert T. Witkowski, Gayathri Ratnaswamy, Kerry Larkin, George McLendon, and Stanley Hattman pp 3326 - 3330; DOI: 10.1021/ic960743e |
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Synthesis and Characterization of Rhenium Phosphinothiolate Complexes. Crystal and Molecular Structures of [HNEt3][Re{P(C6H4S)3}2], [ReOCl{OP(C6H5)2(C6H4S)}{(P(C6H5)2(C6H4S)}], [Re2O5{P(C6H5)2(C6H4S)}2], and [ReOCl{OP(C6H5)2(2-SC6H3-3-SiMe3)}2] Paulo Perez-Lourido, J. Romero, J. Garcia-Vazquez, Antonio Sousa, Kevin P. Maresca, David J. Rose, and Jon Zubieta pp 3331 - 3336; DOI: 10.1021/ic9715299 |
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Structural and Theoretical Analysis of M-H- - -H-M and M-H- - -H-C Intermolecular Interactions Dario Braga, Piero De Leonardis, Fabrizia Grepioni, Emilio Tedesco, and Maria José Calhorda pp 3337 - 3348; DOI: 10.1021/ic9710014 |
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Structure and Magnetic Properties of One-Dimensional PPh4[Ni(pn)2][M(CN)6]·H2O (M = Fe, Cr, Co) Bimetallic Assemblies Masaaki Ohba, Naoki Usuki, Nobuo Fukita, and Hisashi kawapp 3349 - 3354; DOI: 10.1021/ic9704748 |
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Dimethyl Sulfoxide as a Mild Oxidizing Agent for Porous Silicon and Its Effect on Photoluminescence Jae Hee Song and Michael J. Sailor pp 3355 - 3360; DOI: 10.1021/ic971587u |
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Synthesis, Structure, and Physical Properties of Nickel Bis(dithiolene) Metal Complexes, [Ni(dmit)2], with Highly Polar Cyanine Dyes Isabelle Malfant, Raquel Andreu, Pascal G. Lacroix, Christophe Faulmann, and Patrick Cassoux pp 3361 - 3370; DOI: 10.1021/ic971550+ |
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Specific Role of Water in Radiationless Transition from the Triplet MLCT States of Tris(polypyridine) Complexes of Osmium(II) Akiko Masuda and Youkoh Kaizu pp 3371 - 3375; DOI: 10.1021/ic980045p |
Ferrimagnetic Behavior of Multiple Phases and Solvates of (meso-Tetrakis(4-chlorophenyl)porphinato)manganese(III) Tetracyanoethenide, [MnTClPP]+[TCNE] -. Enhancement of Magnetic Coupling by Thermal AnnealingErik J. Brandon, Durrell K. Rittenberg, Atta M. Arif, and Joel S. Miller pp 3376 - 3384; DOI: 10.1021/ic971521z |
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New Condensed Cluster Structure with Triple Metal Layers: La2INi2 and La2ICu2. Synthesis, Structure, and Bonding Seung-Tae Hong, James D. Martin, and John D. Corbett pp 3385 - 3390; DOI: 10.1021/ic980119x |
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Enhancement of Molecular Quadratic Hyperpolarizabilities in Ruthenium(II) 4,4'-Bipyridinium Complexes by N-Phenylation Benjamin J. Coe, James A. Harris, Lisa J. Harrington, John C. Jeffery, Leigh H. Rees, Stephan Houbrechts, and André Persoons pp 3391 - 3399; DOI: 10.1021/ic971411s |
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Theoretical Study of Oxidative Addition and Reductive Elimination of 14-Electron d10 ML2 Complexes: A ML2 + CH4 (M = Pd, Pt; L = CO, PH3, L2 = PH'2CH2CH2PH2) Case Study Ming-Der Su and and San-Yan Chu pp 3400 - 3406; DOI: 10.1021/ic970320s |
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Assembly of a Porous Three-Dimensional Coordination Polymer: Crystal Structure of {[La2(adipate)3(H2O)4]6H2O}n Vangelis Kiritsis, Adonis Michaelides, Stavroula Skoulika, Stephane Golhen, and Lahcene Ouahab pp 3407 - 3410; DOI: 10.1021/ic980014u |
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A Two-Dimensional Network Constructed via Hydrogen-Bonded Cross-Linkages of Molybdenum Oxide Chains Pamela J. Zapf, Robert L. LaDuca, Jr., Randy S. Rarig, Jr., Kenneth M. Johnson, III, and Jon Zubieta pp 3411 - 3414; DOI: 10.1021/ic980151r |
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Novel Organically Templated Vanadyl(IV) Diarsenate and Monoarsenate with Chain Structures: Solvothermal Synthesis and Characterization of (H3NC2H4NH3)[VO(H2O)As2O7] and (H3NC2H4NH3)0.5[VO(H2O)AsO4] An-Hsiung Liu and Sue-Lein Wang pp 3415 - 3418; DOI: 10.1021/ic980061m |
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Valence Tautomerism in a Cobalt Complex of a Schiff Base Diquinone Ligand Andrea Caneschi, Andrea Cornia, and Andrea Dei pp 3419 - 3421; DOI: 10.1021/ic971083w |
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Investigation of Potassium Fluoride Supported on Alumina in the Deboronation of o-Carborane Thomas D. Getman pp 3422 - 3423; DOI: 10.1021/ic980222m |
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Syntheses and Structures of Nickel(II) and Copper(II) Complexes of 2,6-Bis[(2-acetylphenyl)carbamoyl]pyridine: Effects of Molecular Structure on Crystal Lattice Architecture T. Kawamoto, B. S. Hammes, R. Ostrander, A. L. Rheingold, and A. S. Borovik pp 3424 - 3427; DOI: 10.1021/ic9713184 |
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Polynuclear Aggregation of Manganese Dichloride. Syntheses, Properties, and Structures of Polymeric [MnCl2(THF)1.6], Dimeric [(THF)4Mg(-Cl)2MnCl2], and Ionic [Mg(H2O)2(THF)4][Mg(H2O)4(THF)2][MnCl4]2·2THF Compounds Piotr Sobota, Józef Utko, and Lucjan B. Jerzykiewicz pp 3428 - 3431; DOI: 10.1021/ic971513i |
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Synthesis and Rutilelike Structure of [Cd(tcm)(hmt)(H2O)](tcm) (tcm- = Tricyanomethanide, C(CN)3-; hmt = Hexamethylenetetramine) Stuart R. Batten, Bernard F. Hoskins, and Richard Robson pp 3432 - 3434; DOI: 10.1021/ic980059v |
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Synthesis and Molecular Structure of the Lithiated Triamidoamine [Li3{N(CH2CH2SiButMe2)3}(THF)n] Paul Roussel, Nathaniel W. Alcock, and Peter Scott pp 3435 - 3436; DOI: 10.1021/ic980167h |
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Synthesis and Single-Crystal Structure Analysis of [Ba(NH3)7]C60·NH3 Klaus Himmel and Martin Jansen pp 3437 - 3439; DOI: 10.1021/ic9715512 |
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Terminal Ligand Assignments Based on Trends in Metal-Ligand Bond Lengths of Cubane-Type [Fe4S4]2+,+ Clusters B. M. Segal, H. R. Hoveyda, and R. H. Holm pp 3440 - 3443; DOI: 10.1021/ic980092h |
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Electronic Structure of the Highly Reduced Polyoxoanion [PMo12O40(VO)2]5-: A DFT Study J. M. Maestre, J. M. Poblet, C. Bo, N. Casañ-Pastor, and P. Gomez-Romero pp 3444 - 3446; DOI: 10.1021/ic970195k |
Issue 14
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Synthesis of Reduced Transition-Metal Oxides with Hydroxylamine Hydrochloride V. Manivannan and J. B. Goodenough pp 3448 - 3449; DOI: 10.1021/ic9802754 |
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Synthesis and Crystal Structures of Lithium and Potassium Triazenide Complexes Peter Gantzel and Patrick J. Walsh pp 3450 - 3451; DOI: 10.1021/ic9802911 |
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The Novel Binuclear Hydroxyberyllate Species [Be2(OH)7]3- and the Hydroxide Hydrate Anion [H3O2]- as Components of Beryllate Equilibria Michael Schmidt, Annette Schier, Jürgen Riede, and Hubert Schmidbaur pp 3452 - 3453; DOI: 10.1021/ic980481b |
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Stability and Three-Dimensional Aromaticity of closo-Monocarbaborane Anions, CBn-1Hn-, and closo-Dicarboranes, C2Bn-2Hn Paul von Ragué Schleyer and Katayoun Najafian pp 3454 - 3470; DOI: 10.1021/ic980110v |
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Variation in the Mode of Coordination of Aryl Sulfonates to Zirconocene in the Solid State Nicola S. Hüsgen, Gerrit A. Luinstra, Frank Schaper, and Katrin Schmidt pp 3471 - 3474; DOI: 10.1021/ic971597v |
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Fluxionality and Isomerism of the Bis(dihydrogen) Complex RuH2(H2)2(PCy3)2: INS, NMR, and Theoretical Studies Venancio Rodriguez, Sylviane Sabo-Etienne, Bruno Chaudret, John Thoburn, Stefan Ulrich, Hans-Heinrich Limbach, Juergen Eckert, Jean-Claude Barthelat, Khansaa Hussein, and Colin J. Marsden pp 3475 - 3485; DOI: 10.1021/ic970697y |
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Preparation of the New Bis(phenanthroline) Ligand "Clip-Phen" and Evaluation of the Nuclease Activity of the Corresponding Copper Complex Marguerite Pitié, Bruno Donnadieu, and Bernard Meunier pp 3486 - 3489; DOI: 10.1021/ic980044x |
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Crystal Engineering in [(12C4)2Na][Cd(SCN)3]: First Example of an Anionic Cadmium Thiocyanate Coordination Solid with a Sandwich [(12C4)2Na]+ Cation as Spacer/Controller, Resulting in a Hexagonal Arrangement of Antiparallel Zigzag [Cd(SCN)3-] Chains Hong Zhang, Ximin Wang, Kecong Zhang, and Boon K. Teo pp 3490 - 3496; DOI: 10.1021/ic971487o |
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The Preparation, Stereochemistry and Reactions of Some [Co(cyclen)(NH3)X]3+/2+ Complexes (X = OH2, Cl, N3, OH) David A. Buckingham, Charles R. Clark, Andrew J. Rogers, and Jim Simpson pp 3497 - 3504; DOI: 10.1021/ic971029f |
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Mid-Infrared Spectrum of [Ru(phen)3]2+* Kristin M. Omberg, Jon R. Schoonover, Stefan Bernhard, John A. Moss, Joseph A. Treadway, Edward M. Kober, R. Brian Dyer, and Thomas J. Meyer pp 3505 - 3508; DOI: 10.1021/ic971554e |
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Structural and 99Tc NMR Investigations of Complexes with fac-[Tc(CO)3]+ Moieties and Macrocyclic Thioethers of Various Ring Sizes: Synthesis and X-ray Structure of the Complexes fac-[Tc(9-ane-S3)(CO)3]Br, fac-[Tc2(tosylate)2(18-ane-S6)(CO)6], and fac-[Tc2(20-ane-S6-OH)(CO)6][tosylate]2 Roger Schibli, Roger Alberto, Ulrich Abram, Sonja Abram, André Egli, P. August Schubiger, and Thomas A. Kaden pp 3509 - 3516; DOI: 10.1021/ic980112f |
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The Synthesis, NMR Spectroscopy, and X-ray Structure of a New Rhenium N2S2 Chelate Complex R. A. Bell, B. E. McCarry, and J. F. Valliant pp 3517 - 3520; DOI: 10.1021/ic970654h |
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[CuCN·Me3SnCN·0.5bpy] (bpy = 4,4'-Bipyridine): A Novel Supramolecular Assembly Involving the No Longer Unusual {Cu2(-CN)2(CN)2} Motif Amany M. A. Ibrahim, Eric Siebel, and R. Dieter Fischer pp 3521 - 3525; DOI: 10.1021/ic971532s |
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Calixarenes Derivatized with Sulfur-Containing Functionalities as Selective Extractants for Heavy and Precious Metal Ions Alexander T. Yordanov, Bruce R. Whittlesey, and D. Max Roundhill pp 3526 - 3531; DOI: 10.1021/ic9709988 |
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A Convenient Synthetic Strategy toward Heavy Alkali Metal Bis(trimethylsilyl)phosphides: Crystal Structures of the Ladder-Type Polymers [A(thf)P(SiMe3)2] (A = K, Rb, Cs) Ulrich Englich, Karl Hassler, Karin Ruhlandt-Senge, and Frank Uhlig pp 3532 - 3537; DOI: 10.1021/ic9801950 |
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Tris(benzylthiolato)bismuth. Efficient Precursor to Phase-Pure Polycrystalline Bi2S3 Philip Boudjouk, Michael P. Remington, Jr., Dean G. Grier, Bryan R. Jarabek, and Gregory J. McCarthy pp 3538 - 3541; DOI: 10.1021/ic971463h |
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Synthesis, X-ray Structure, Spectroscopic Characterization, and Theoretical Prediction of the Structure and Electronic Spectrum of Eu(btfa)3·bipy and an Assessment of the Effect of Fluorine as a -Diketone Substituent on the Ligand-Metal Energy Transfer Process Hélcio J. Batista, Antônio V. M. de Andrade, Ricardo L. Longo, Alfredo M. Simas, Gilberto F. de Sá, Nao K. Ito, and Larry C. Thompson pp 3542 - 3547; DOI: 10.1021/ic971602v |
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Transition Metal Ion Initiated Chain Reactions between tert-Butyl Hydroperoxide and Rhodium Hydrides. Rapid Hydrogen Atom Abstraction from Rhodium Hydrides by Methyl Radicals Andreja Bakac pp 3548 - 3552; DOI: 10.1021/ic980089y |
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Zigzag-Chain and Cyclic-Tetrameric Compounds Derived by Deprotonation of Mononuclear Copper(II) Complexes with N,N'-Bis(2-substituted-imidazol-4-ylmethyl- idene)-1,4-diaminobutane (2-Substituent = H, Me): Synthesis, Characterization, Structure, Substituent Effect, and Interconvertibility Masaaki Mimura, Toshihiro Matsuo, Toshio Nakashima, and Naohide Matsumoto pp 3553 - 3560; DOI: 10.1021/ic971609c |
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Reactions of H3Al·NMe3 with E(SiMe3)3 (E = P, As). Structural Characterization of the Trimer [H2AlP(SiMe3)2]3 and Base-Stabilized Adduct [H2AlAs(SiMe3)2]·NMe3 and Their Thermal Decomposition toward Nanocrystalline AlP and AlAs, Respectively Jerzy F. Janik, Richard L. Wells, and Peter S. White pp 3561 - 3566; DOI: 10.1021/ic980218a |
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Raman Spectroscopy of Three Average-Valence Dicopper Cryptates: Evidence for Copper-Copper Bonding Ala Al-Obaidi, Goran Baranovi  , Joanne Coyle, Colin G. Coates, John J. McGarvey, Vickie McKee, and Jane Nelsonpp 3567 - 3574; DOI: 10.1021/ic971274z |
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A Tridentate-Bridged Ruthenium-Rhodium Complex as a Stereochemically Defined Light-Absorber-Electron-Acceptor Dyad Jae-Duck Lee, Lisa M. Vrana, Elizabeth R. Bullock, and Karen J. Brewer pp 3575 - 3580; DOI: 10.1021/ic970892c |
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Synthesis and Characterization of Neutral Hexanuclear Iron Sulfur Clusters Containing Stair-like [Fe6(3-S)4(2-SR)4] and Nest-like [Fe6(3-S)2(2-S)2(4-S)(2-SR)4] Core Structures Frank Osterloh, Wolfgang Saak, Siegfried Pohl, Monika Kroeckel, Christian Meier, and Alfred X. Trautwein pp 3581 - 3587; DOI: 10.1021/ic980039t |
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Forbidden Electronic Transitions between the Singlet Ground State and the Triplet Excited State of Pt(II) Complexes Greg Y. Zheng, D. Paul Rillema, Jeff DePriest, and Clifton Woods pp 3588 - 3592; DOI: 10.1021/ic980324c |
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A Steeply Pyramidal Silylamine: N,O-Dimethyl-N-silylhydroxylamine Norbert W. Mitzel and Heinz Oberhammer pp 3593 - 3598; DOI: 10.1021/ic980323k |
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Synthesis and Characterization of [MnIII6(N-formylsalicylhydrazidate)6(MeOH)6]: A New Type of Macrocyclic Hexanuclear Manganese Cluster Byunghoon Kwak, Hakjune Rhee, Soonheum Park, and Myoung Soo Lah pp 3599 - 3602; DOI: 10.1021/ic971538h |
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Tetranuclear Tetrapyrido[3,2-a:2',3'-c:3'',2''-h:2''',3'''-j]phenazineruthenium Complex: Synthesis, Wide-Angle X-ray Scattering, and Photophysical Studies Eléna Ishow, André Gourdon, Jean-Pierre Launay, Pierre Lecante, Marc Verelst, Claudio Chiorboli, Franco Scandola, and Carlo-Alberto Bignozzi pp 3603 - 3609; DOI: 10.1021/ic9715815 |
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Reactivity of Osmium(VI) Nitrides with the Azide Ion. A New Synthetic Route to Osmium(II) Polypyridyl Complexes Konstantinos D. Demadis, Thomas J. Meyer, and Peter S. White pp 3610 - 3619; DOI: 10.1021/ic9800280 |
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Spiral Dinuclear Complexes of Tetradentate N4 Diazine Ligands with Mn(II), Fe(II), Fe(III), Co(III), and Ni(II) Salts Zhiqiang Xu, Laurence K. Thompson, David O. Miller, Howard J. Clase, Judith A. K. Howard, and Andrés E. Goeta pp 3620 - 3627; DOI: 10.1021/ic9715761 |
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New Metal-Intercalated Layered Vanadyl Phosphates, MxVOPO4·yH2O (M = Ag, Cu, Zn) P. Ayyappan, A. Ramanan, and C. C. Torardi pp 3628 - 3634; DOI: 10.1021/ic980228b |
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Thermochromism and Structure of Piperazinium Tetrachlorocuprate(II) Complexes Mark J. Riley, Debora Neill, Paul V. Bernhardt, Karl A. Byriel, and Colin H. L. Kennard pp 3635 - 3639; DOI: 10.1021/ic971612w |
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New Polyether-Substituted Metallacarboranes as Extractants for 137Cs and 90Sr from Nuclear Wastes Clara Viñas, Sílvia Gomez, Josep Bertran, Francesc Teixidor, Jean-François Dozol, and Hélène Rouquette pp 3640 - 3643; DOI: 10.1021/ic971467m |
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Chlorination of a Pyrazole Ligand in Vanadium(V)alkoxo Complexes Holger Glas, Eberhardt Herdtweck, Georg R. J. Artus, and Werner R. Thiel pp 3644 - 3646; DOI: 10.1021/ic9715355 |
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Chiral H- and J-Type Aggregates of meso-Tetrakis(4-sulfonatophenyl)porphine on -Helical Polyglutamic Acid Induced by Cationic Porphyrins Roberto Purrello, Luigi Monsu' Scolaro, Emanuele Bellacchio, Sergio Gurrieri, and Andrea Romeo pp 3647 - 3648; DOI: 10.1021/ic971432m |
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Reaction of Organolithium Reagents with Tetracarbonyl[2-(phenyl-C2'),pyridine-N]rhenium(I): Isolation and Structural Characterization of Acyl Rhenate Species Jean-Pierre Djukic, Karl Heinz Dötz, Michel Pfeffer, André De Cian, and Jean Fischer pp 3649 - 3651; DOI: 10.1021/ic980016e |
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Characterization of a Dinuclear (-Hydroxo)(-pyrazolato)dimanganese(II) Complex and Hydrolytic Equilibrium of the Bridging Pyrazolate Ligand Hidehito Komatsuzaki, Shinobu Ichikawa, Shiro Hikichi, Munetaka Akita, and Yoshihiko Moro-oka pp 3652 - 3656; DOI: 10.1021/ic971622x |
Issue 15
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Experimental Observation of Excited-State Electron Transfer Quenching Involving Exchange-Coupled Dinuclear FeIII Complexes James P. Kirby, Brandon T. Weldon, and James K. McCusker pp 3658 - 3659; DOI: 10.1021/ic980561f |
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Facile Reduction of Tungsten Halides with Nonconventional, Mild Reductants. 2. Four Convenient, High-Yield Solid-State Syntheses of the Hexatungsten Dodecachloride Cluster W6Cl12 and Cluster Acid (H3O)2[W6(3-Cl)8Cl6](OH2)x, Including New Cation-Assisted Ternary Routes Vladimir Kolesnichenko and Louis Messerle pp 3660 - 3663; DOI: 10.1021/ic980232n |
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Electrochemical Properties of Bis(dicarbollide)uranium Dibromide Francis M. de Rege, Wayne H. Smith, Brian L. Scott, Jon B. Nielsen, and Kent D. Abney pp 3664 - 3666; DOI: 10.1021/ic9712838 |
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Temperature and pH Dependence XAFS Study of Gd(DOTA)- and Gd(DTPA)2- Complexes: Solid State and Solution Structures Simone Bénazeth, Juris Purans, Marie-Cécile Chalbot, M. Kim Nguyen-van-Duong, Louisette Nicolas, Françoise Keller, and Alain Gaudemer pp 3667 - 3674; DOI: 10.1021/ic9707321 |
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Heterometallic Homo- and Heteroleptic Porphyrinate Dimers with a Rhodium-Thallium Bond Dimitra Daphnomili, W. Robert Scheidt, Jaroslav Zajicek, and Athanassios G. Coutsolelos pp 3675 - 3681; DOI: 10.1021/ic971393e |
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Synthesis, Chemical-Physical Characterization, and Redox Properties of a New Mixed-Ligand Heterobimetallic N-Bridged Dimer: (-Nitrido)[((tetraphenylporphyrinato)manganese)((phthalocyaninato)iron)] Maria Pia Donzello, Claudio Ercolani, Karl M. Kadish, Zhongping Ou, and Umberto Russo pp 3682 - 3688; DOI: 10.1021/ic971585+ |
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Syntheses and Characterizations of a Series of Tetradecanuclear Molybdenum(Tungsten)/Copper/Sulfur Heterobimetallic Cluster Compounds Jun Guo, Tianlu Sheng, Wenjian Zhang, Xintao Wu, Ping Lin, Quanming Wang, and Jiaxi Lu pp 3689 - 3697; DOI: 10.1021/ic970900p |
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Mixed-Valent Diruthenium Long-Chain Carboxylates. 2. Magnetic Properties Fabio D. Cukiernik, Dominique Luneau, Jean-Claude Marchon, and Pascale Maldivi pp 3698 - 3704; DOI: 10.1021/ic971366o |
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Structural, EPR, and Electrochemical Studies of Binuclear Copper(II) Complexes of Bis(pentadentate) Ligands Derived from Bis(1,4,7-triazacyclonane) Macrocycles Suzanne J. Brudenell, Leone Spiccia, Alan M. Bond, Peter Comba, and David C. R. Hockless pp 3705 - 3713; DOI: 10.1021/ic971634i |
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Proton NMR Study of Oxo-Bridged Dimanganese(III) Complexes: Solution State Structures and an Isotropic Shift/Magnetic Exchange Correlation David W. Wright, Henry J. Mok, Christopher E. Dubé, and William H. Armstrong pp 3714 - 3718; DOI: 10.1021/ic960646l |
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Density Functional Description of the Ferromagnetic Exchange Interactions between Semiquinonato Radicals Mediated by Diamagnetic Metal Ions Alessandro Bencini, Ilaria Ciofini, Elisa Giannasi, Claude A. Daul, and Karel Doclo pp 3719 - 3725; DOI: 10.1021/ic970906e |
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Characterization of Calcium Aluminate Hydrates and Related Hydrates of Cement Pastes by 27Al MQ-MAS NMR P. Faucon, T. Charpentier, D. Bertrandie, A. Nonat, J. Virlet, and J. C. Petit pp 3726 - 3733; DOI: 10.1021/ic9800076 |
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Synthesis and Characterization of Dimeric, Trimeric, and Tetrameric Gallophosphonates and Gallophosphates Mark R. Mason, Alisa M. Perkins, R. Mark Matthews, James D. Fisher, Mark S. Mashuta, and Ashwani Vij pp 3734 - 3746; DOI: 10.1021/ic980132h |
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Increased Coordination via Sulfur Donor Action in Cyclic Pentaoxyphosphoranes and the Parent Cyclic Phosphite. Influence of Pentafluorophenoxy Ligands Paul Sood, A. Chandrasekaran, Roberta O. Day, and Robert R. Holmes pp 3747 - 3752; DOI: 10.1021/ic971593q |
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Dithiocarbamate-Functionalized Dendrimers as Ligands for Metal Complexes Quentin J. McCubbin, Fiona J. Stoddart, Thomas Welton, Andrew J. P. White, and David J. Williams pp 3753 - 3758; DOI: 10.1021/ic980067b |
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Structure and Magnetic Properties of a Mixed-Valence Heptanuclear Manganese Cluster Gian Luca Abbati, Andrea Cornia, Antonio C. Fabretti, Andrea Caneschi, and Dante Gatteschi pp 3759 - 3766; DOI: 10.1021/ic9800029 |
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van der Waals Radii of Pt(II) and Pd(II) in Molecular Mechanics Models and an Analysis of Their Relevance to the Description of Axial M···H(-C), M···H(-N), M···S, and M···M (M = Pd(II) or Pt(II)) Interactions Trevor W. Hambley pp 3767 - 3774; DOI: 10.1021/ic971392m |
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Synthesis and Structure of the New Ternary Nitride SrTiN2 D. H. Gregory, M. G. Barker, P. P. Edwards, and D. J. Siddons pp 3775 - 3778; DOI: 10.1021/ic971556z |
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Kinetic Study on the Substitution of Dimethylacetamide for the Terminal Aqua Ligands in the Trinuclear Chromium(III) Complexes [Cr3(3-O)(-RCO2)6(H2O)3]+ (R = H, CH3, CH3CH2, CH2Cl, CHCl2, CH3OCH2, (CH3)3C, CH2ClCH2, (CH3CH2)2CH). Elucidation of the Mechanism from the Activation Volumes and the Substituent Effects of Bridging Carboxylate Ligands Takashi Fujihara, Jun Aonahata, Shigekazu Kumakura, Akira Nagasawa, Kazuhiro Murakami, and Tasuku Ito pp 3779 - 3784; DOI: 10.1021/ic980001g |
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Phosphorescence and Structure of a Tetrameric Copper(I)-Amide Cluster Alicia M. James, Ravi K. Laxman, Frank R. Fronczek, and Andrew W. Maverick pp 3785 - 3791; DOI: 10.1021/ic971341p |
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New Lanthanide Selenophosphates. Influence of Flux Composition on the Distribution of [PSe4]3-/[P2Se6]4- Units and the Stabilization of the Low-Dimensional Compounds A3REP2Se8, and A2(RE)P2Se7 (A = Rb, Cs; RE = Ce, Gd) Konstantinos Chondroudis and Mercouri G. Kanatzidis pp 3792 - 3797; DOI: 10.1021/ic980025n |
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Syntheses, Crystal Structures, and Physical Properties of the New Thorium Chalcogenides CuTh2Te6 and SrTh2Se5 Amy A. Narducci and James A. Ibers pp 3798 - 3801; DOI: 10.1021/ic971594i |
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Electronic Structure of Face- and Edge-Shared Bioctahedral Systems: A Comparison of M2Cl93- and M2Cl104-, M = Cr, Mo, W John E. McGrady, Robert Stranger, and Timothy Lovell pp 3802 - 3808; DOI: 10.1021/ic970553j |
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Electronic Structure of Luminescent d0 Niobium and Tantalum Imido Compounds cis,mer-M(NR)Cl3L2 Darryl S. Williams and Andrey V. Korolev pp 3809 - 3819; DOI: 10.1021/ic9800740 |
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First Examples of Dinickel Complexes Containing the N3Ni(2-SR)3NiN3 Core. Synthesis and Crystal Structures of [L2Ni2][BPh4]2 and [L3Ni2][BPh4]2 (L = 2,6-Di(aminomethyl)-4-tert-butyl-thiophenolate) Berthold Kersting and Dieter Siebert pp 3820 - 3828; DOI: 10.1021/ic980131p |
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Facile Routes to NiF62-, AgF4-, AuF6-, and PtF6- Salts Using O2+ as a Source of O2F in Anhydrous HF G. M. Lucier, C. Shen, S. H. Elder, and N. Bartlett pp 3829 - 3834; DOI: 10.1021/ic971603n |
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Synthesis of Indium Amide Compounds Jungsook Kim, Simon G. Bott, and David M. Hoffman pp 3835 - 3841; DOI: 10.1021/ic971138u |
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Ground State and Excited Stated Properties of Hexaamminechromium(III) Ion: A Density Functional Study Karel Doclo, David De Corte, Claude Daul, and Hans-Ueli Güdel pp 3842 - 3847; DOI: 10.1021/ic9715207 |
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Structural Determination and Acidolysis Reactions of Ortho-Metalated Rhenium Tetrahydride Compounds Prepared from Reactions of ReH7(PPh3)2 with Benzylic Imines Gregory A. Moehring, Christopher C. Williams, Jeff Buford, Mansoor Kaviani, Jennifer Sulko, and Phillip E. Fanwick pp 3848 - 3852; DOI: 10.1021/ic971281n |
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Preparation, Structure, and Electronic Properties of a Low-Spin Iron(II) Hexaamine Compound Heidi Börzel, Peter Comba, Hans Pritzkow, and Achim F. Sickmüller pp 3853 - 3857; DOI: 10.1021/ic971552u |
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Structural, Magnetic, and Ion-Exchange Properties of RbMnHP3O10 A. J. Wright and J. P. Attfield pp 3858 - 3861; DOI: 10.1021/ic980212l |
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Molecular Structures of Three-, Four-, and Five-Coordinate Phosphorus Compounds Containing Salicylate Ligands Natalya V. Timosheva, A. Chandrasekaran, Roberta O. Day, and Robert R. Holmes pp 3862 - 3867; DOI: 10.1021/ic980288h |
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Intense Photosensitized Emission from Stoichiometric Compounds Featuring Mn2+ in Seven- and Eightfold Coordination Environments Howard O. N. Reid, Ishenkumba A. Kahwa, Andrew J. P. White, and David J. Williams pp 3868 - 3873; DOI: 10.1021/ic980035o |
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The Existence of Two Oxidized Mn(III)Mn(III) Forms of Thermus thermophilus Manganese Catalase Isabelle Michaud-Soret, Lilian Jacquamet, Noële Debaecker-Petit, Laurent Le Pape, Vladimir V. Barynin, and Jean-Marc Latour pp 3874 - 3876; DOI: 10.1021/ic9712176 |
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Two-Dimensional Sheets of Rugged Hexagonal Grids of [Cu6(trans-oxen)3(3-OH)2(H2O)2]n4n+ with Copper(II) Bridged by trans-Oxamidate (oxen) and 3-OH- Groups Zhong-Ning Chen, Hua-Xin Zhang, Cheng-Yong Su, Zhong-Yuan Zhou, Kang-Cheng Zheng, and Bei-Sheng Kang pp 3877 - 3880; DOI: 10.1021/ic9714246 |
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Structure, Spectra, and Redox Behavior of a -Dimethoxo-Bridged Diferric Complex with an Asymmetric Fe2O2 Bridge Rathinam Viswanathan, Mallayan Palaniandavar, P. Prabakaran, and P. Thomas Muthiah pp 3881 - 3884; DOI: 10.1021/ic961492c |
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The Magnetic Structures of the Layer Ferri- magnets P(C6D5)4MIIFe(C2O4)3 (MII = Mn, Fe) Christopher J. Nuttall and Peter Day pp 3885 - 3888; DOI: 10.1021/ic980201s |
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Deltahedral Clusters in Neat Solids: Synthesis and Structure of the Zintl Phase Cs4Pb9 with Discrete Pb94- Clusters Evgeny Todorov and Slavi C. Sevov pp 3889 - 3891; DOI: 10.1021/ic980266v |
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Synthesis, Structure, and Reactivity of Potassium Pyrazolato Complexes: The First Structurally Documented 2-Pyrazolato Coordination by a Main Group Metal Carlos Yélamos, Mary Jane Heeg, and Charles H. Winter pp 3892 - 3894; DOI: 10.1021/ic980248d |
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Molecular Structure and Conformation of Dimethyltrisulfane, CH3SSSCH3, As Determined by ab Initio Molecular Orbital Calculations and Gas-Phase Electron Diffraction Quang Shen, Christopher Wells, and Kolbj rn Hagenpp 3895 - 3898; DOI: 10.1021/ic9803208 |
Issue 16
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Synthesis and Characterization of Cp*3Ru3B3H8, Cp* = 5-C5Me5, Exhibiting a Capped Nido Geometry. Cluster Geometry Driven by Hydrogen Bridging Xinjian Lei, Maoyu Shang, and Thomas P. Fehlner pp 3900 - 3901; DOI: 10.1021/ic980470i |
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Dicarbaheteroborane Chemistry. Representatives of Two Eleven-Vertex Dicarbaazaundecaborane Families: nido-10,7,8-NC2B8H11, Its N-Substituted Derivatives, and arachno-1,8,11-NC2B8H13 Jaromír Ple ek, Bohumil  tíbr, Drahomír Hnyk, Tomá Jelínek, Stanislav He mánek, John D. Kennedy, Matthias Hofmann, and Paul v. R. Schleyerpp 3902 - 3909; DOI: 10.1021/ic971526w |
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Studies of Copper Complexes Displaying N3S Coordination as Models for CuB Center of Dopamine -Hydroxylase and Peptidylglycine -Hydroxylating Monooxygenase Frédéric Champloy, Nourredine Benali-Chérif, Pascale Bruno, Ingrid Blain, Marcel Pierrot, Marius Réglier, and Alain Michalowicz pp 3910 - 3918; DOI: 10.1021/ic9709281 |
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Dipyridocatecholate-Bridged Complexes of Platinum and Ruthenium Diimine Chromophores Witold Paw, William B. Connick, and Richard Eisenberg pp 3919 - 3926; DOI: 10.1021/ic971447k |
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Spectral and Electrochemical Behavior of Copper(II)-Phenanthrolines Bound to Calf Thymus DNA. [(5,6-dimethyl-OP)2Cu]2+ (5,6-dimethyl-OP = 5,6-Dimethyl-1,10-phenanthroline) Induces a Conformational Transition from B to Z DNA Sethuraman Mahadevan and Mallayan Palaniandavar pp 3927 - 3934; DOI: 10.1021/ic9711067 |
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Thermodynamic and Steady-State Fluorescence Emission Studies on Metal Complexes of Receptors Containing Benzene Subunits M. Alexandra Bernardo, Fernando Pina, Enrique García-España, Julio Latorre, Santiago V. Luis, José M. Llinares, José A. Ramírez, and Conxa Soriano pp 3935 - 3942; DOI: 10.1021/ic970840n |
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Mechanism of Decomposition of Peroxynitric Ion (O2NOO-): Evidence for the Formation of O2- and NO2 Radicals Sara Goldstein, Gidon Czapski, Johan Lind, and Gabor Merenyi pp 3943 - 3947; DOI: 10.1021/ic980051l |
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High-Pressure Oxygen-17 NMR Study of the Dihydroxo-Bridged Rhodium(III) Hydrolytic Dimer. Mechanistic Evidence for Limiting Dissociative Water Exchange Pathways Alexander Drljaca, Achim Zahl, and Rudi van Eldik pp 3948 - 3953; DOI: 10.1021/ic971074n |
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Hydrogen Bonding and Isomerism Arising from the Coordination Modes of Bridging Benzimidazole-2-thiolate Ligands in Tetranuclear Rhodium Complexes Cristina Tejel, B. Eva Villarroya, Miguel A. Ciriano, Andrew J. Edwards, Fernando J. Lahoz, Luis A. Oro, Maurizio Lanfranchi, Antonio Tiripicchio, and Marisa Tiripicchio-Camellini pp 3954 - 3963; DOI: 10.1021/ic971376p |
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GG versus AG Platination: A Kinetic Study on Hairpin-Stabilized Duplex Oligonucleotides Franck Legendre, Ji í Kozelka, and Jean-Claude Chottardpp 3964 - 3967; DOI: 10.1021/ic980008y |
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Crystal Structures of AuCN and AgCN and Vibrational Spectroscopic Studies of AuCN, AgCN, and CuCN Graham A. Bowmaker, Brendan J. Kennedy, and Jason C. Reid pp 3968 - 3974; DOI: 10.1021/ic9714697 |
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Oxidation of Complexes by (O2CPh)2 and (ER)2 (E = S, Se), Including Structures of Pd(CH2CH2CH2CH2)(SePh)2(bpy) (bpy = 2,2'-Bipyridine) and MMe2(SePh)2(L2) (M = Pd, Pt; L2 = bpy, 1,10-Phenanthroline) and C···O and C···E Bond Formation at Palladium(IV) Allan J. Canty, Hong Jin, Brian W. Skelton, and Allan H. White pp 3975 - 3981; DOI: 10.1021/ic9715005 |
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Transition Metal Complexes with Sulfur Ligands. 130.1 Synthesis, Structure, and Reactivity of the Sulfur-Rich Ruthenium Hydride Complexes [Ru(H)(PR3)('S4')]- and the 2-H2 Complex [Ru(H2)(PCy3)('S4')] (R = Ph, iPr, Cy; 'S4'2- = 1,2-Bis((2-mercaptophenyl)thio)ethane(2-)) Dieter Sellmann, Torsten Gottschalk-Gaudig, and Frank W. Heinemann pp 3982 - 3988; DOI: 10.1021/ic971068r |
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Effect of Mixed Pendent Groups on the Solution and Catalytic Properties of Europium(III) Macrocyclic Complexes: Bifunctional and Monofunctional Amide and Alcohol Pendents in Septadentate or Octadentate Ligands Lara L. Chappell, David A. Voss, Jr., William DeW. Horrocks, Jr., and Janet R. Morrow pp 3989 - 3998; DOI: 10.1021/ic980191v |
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Kinetics and Mechanism of Metal Substitution and the Irving-Williams Series: Anion-Catalyzed Substitution of Nickel for Copper in Cu(amben) [=(N,N'-Ethylenebis(2-aminobenzaldiminato))copper(II)] Susanne Busse, Horst Elias, Jürgen Fischer, Markus Poggemann, Klaus J. Wannowius, and Roman Boca pp 3999 - 4005; DOI: 10.1021/ic9716262 |
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A5TaAs4Tl2 (A = Rb, K). Transition-Metal Zintl Phases with a Novel Complex Ion: Synthesis, Structure, and Bonding DaPing Huang and John D. Corbett pp 4006 - 4010; DOI: 10.1021/ic9802395 |
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Paramagnetic Cluster Ions [B6HalnHal'6-n]- (Hal, Hal' = Cl, Br, I). EPR Evidence for Radical Stabilization through Electronic Effects of the Halogen Substituents Volker Lorenzen, Wilhelm Preetz, Frank Baumann, and Wolfgang Kaim pp 4011 - 4014; DOI: 10.1021/ic9802698 |
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Charge-Transfer Salts of Octamethylferrocenyl Thioethers and [M(mnt)2]- Complexes (M = Ni, Co, Pt). Synthesis, Structure, and Physical Properties Stefan Zürcher, Volker Gramlich, Dieter von Arx, and Antonio Togni pp 4015 - 4021; DOI: 10.1021/ic9802045 |
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Structural, Spectroscopic, Thermodynamic and Kinetic Properties of Copper(II) Complexes with Tripodal Tetraamines Florian Thaler, Colin D. Hubbard, Frank W. Heinemann, Rudi van Eldik, Siegfried Schindler, István Fábián, Andreas M. Dittler-Klingemann, F. Ekkehardt Hahn, and Chris Orvig pp 4022 - 4029; DOI: 10.1021/ic971295t |
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Crystallographic, Electrochemical, and Pulsed EPR Study of Copper(II) Polyimidazole Complexes Relevant to the Metal Sites of Copper Proteins Christophe Place, Jean-Luc Zimmermann, Etienne Mulliez, Geneviève Guillot, Claudette Bois, and Jean-Claude Chottard pp 4030 - 4039; DOI: 10.1021/ic9715660 |
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Halide Effects in the Synthesis of Mixed Uranium(IV) Aryloxide-Halide Compounds Steven D. McKee, Carol J. Burns, and Larry R. Avens pp 4040 - 4045; DOI: 10.1021/ic9803309 |
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Synthesis and Characterization of Two New Copper Tellurites, Ba2Cu4Te4O11Cl4 and BaCu2Te2O6Cl2, in Supercritical H2O Christopher R. Feger and Joseph W. Kolis pp 4046 - 4051; DOI: 10.1021/ic971264y |
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Methylation of Tethered Thiolates in [(bme-daco)Zn]2 and [(bme-daco)Cd]2 as a Model of Zinc Sulfur-Methylation Proteins Craig A. Grapperhaus, Thawatchai Tuntulani, Joseph H. Reibenspies, and Marcetta Y. Darensbourg pp 4052 - 4058; DOI: 10.1021/ic971599f |
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Synthesis, Crystal Structures, and Magnetic Properties of a Series of Linear Pentanickel(II) Complexes: [Ni5(5-tpda)4X2] (X = Cl-, CN-, N3-, NCS-) and [Ni5(5-tpda)4(CH3CN)2]- (PF6)2 (tpda2- = the Tripyridyldiamido Dianion) Chih-Chieh Wang, Wei-Chung Lo, Chin-Chang Chou, Gene-Hsiang Lee, Jin-Ming Chen, and Shie-Ming Peng pp 4059 - 4065; DOI: 10.1021/ic971608k |
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Further Study of Very Close Nonbonded CuI-CuI Contacts. Molecular Structure of a New Compound and Density Functional Theory Calculations F. Albert Cotton, Xuejun Feng, and Daren J. Timmons pp 4066 - 4069; DOI: 10.1021/ic980137e |
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Binuclear Copper(II) Chelates of Amide-Based Cyclophanes Michiko B. Inoue, Enrique F. Velazquez, Felipe Medrano, Karen L. Ochoa, J. C. Galvez, Motomichi Inoue, and Quintus Fernando pp 4070 - 4075; DOI: 10.1021/ic980238c |
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Synthesis and Characterization of Mononuclear and Dinuclear Ruthenium Complexes with Tris(2-pyridylmethyl)amine and Tris(5-methyl-2-pyridylmethyl)amine Takahiko Kojima, Takayuki Amano, Youichi Ishii, Masaaki Ohba, Yoshihiro Okaue, and Yoshihisa Matsuda pp 4076 - 4085; DOI: 10.1021/ic971049h |
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Pentacoordinate (-Oxo)diiron(III) Thiolate Complexes and Dimeric Iron(II) Precursors Ghezai Musie, Chia-Huei Lai, Joseph H. Reibenspies, Lloyd W. Sumner, and Marcetta Y. Darensbourg pp 4086 - 4093; DOI: 10.1021/ic980475f |
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Stereochemistry of Ruthenium Bis-chelate Disulfoxide Complexes. A Molecular Mechanics Investigation Silvano Geremia, Lidia Vicentini, and Mario Calligaris pp 4094 - 4103; DOI: 10.1021/ic980031j |
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Structure and Dynamics of a Trinuclear Gadolinium(III) Complex: The Effect of Intramolecular Electron Spin Relaxation on Its Proton Relaxivity Éva Tóth, Lothar Helm, André E. Merbach, Roman Hedinger, Kaspar Hegetschweiler, and András Jánossy pp 4104 - 4113; DOI: 10.1021/ic980146n |
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Reductive Quenching of Photoexcited Cu(dipp)2+ and Cu(tptap)2+ by Ferrocenes (dipp = 2,9-Diisopropyl-1,10-phenanthroline and tptap = 2,3,6,7-Tetraphenyl-1,4,5,8-tetraazaphenanthrene) Kurstan L. Cunningham and David R. McMillin pp 4114 - 4119; DOI: 10.1021/ic980213d |
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Molecular Mechanics (MM3*) Parameters for Ruthenium(II)-Polypyridyl Complexes Peter Brandt, Thomas Norrby, Björn Åkermark, and Per-Ola Norrby pp 4120 - 4127; DOI: 10.1021/ic980021i |
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Ni2Mo3N: A New Ternary Interstitial Nitride with a Filled -Manganese Structure P. Subramanya Herle, M. S. Hegde, K. Sooryanarayana, T. N. Guru Row, and G. N. Subbanna pp 4128 - 4130; DOI: 10.1021/ic980211t |
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Weak Ferromagnetism in Chiral 3-Dimensional Oxalato-Bridged Cobalt(II) Compounds. Crystal Structure of [Co(bpy)3][Co2(ox)3]ClO4 María Hernández-Molina, Francesc Lloret, Catalina Ruiz-Pérez, and Miguel Julve pp 4131 - 4135; DOI: 10.1021/ic980306v |
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Synthesis and Crystal Structure of the Nickel(II) Phosphoranide Complex trans-(PMe3)2[(C4H6O3)2P-P]NiCl Richard Faw, Craig D. Montgomery, Steven J. Rettig, and Bryn Shurmer pp 4136 - 4138; DOI: 10.1021/ic980193f |
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Synthesis and Characterization of (Di-tert-butylbipyridine)bis(pyridine-4-thiolato)platinum(II), Pt(dbbpy)(S-4-py)2: A Synthon for Supramolecular Systems Containing the Platinum Diimine Bis(Thiolate) Chromophore Witold Paw, Rene J. Lachicotte, and Richard Eisenberg pp 4139 - 4141; DOI: 10.1021/ic971557r |
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Modification of Mesoporous Silica by Direct Template Ion Exchange Using Cobalt Complexes Ali-Reza Badiei and Laurent Bonneviot pp 4142 - 4145; DOI: 10.1021/ic971633q |
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Copper Complexes Generated from Ferrocene-Bipyridyl Metallo-Synthons Mihai Buda, Jean-Claude Moutet, Eric Saint-Aman, André De Cian, Jean Fischer, and Raymond Ziessel pp 4146 - 4148; DOI: 10.1021/ic971573o |
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Bond Valence Sums in Coordination Chemistry. A Simple Method for Calculating the Oxidation State of Cobalt in Complexes Containing Only Co-O Bonds Richard M. Wood and Gus J. Palenik pp 4149 - 4151; DOI: 10.1021/ic980176q |
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Structural and Spectroscopic Characterization of a Metal-Metal Bonded Ruthenium Porphyrin Dimer Cation James P. Collman and Steven T. Harford pp 4152 - 4153; DOI: 10.1021/ic9714798 |
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Mechanism of the Uncatalyzed Dissociative Cis-Trans Isomerization of Bis(pentafluorophenyl)bis(tetrahydrothiophene): A Refinement Arturo L. Casado, Juan A. Casares, and Pablo Espinet pp 4154 - 4156; DOI: 10.1021/ic980101m |
Issue 17
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Structural Studies of a Borane-Modified Phosphate Diester Linkage: Ab Initio Calculations on the Dimethylboranophosphate Anion and the Single-Crystal X-ray Structure of Its Diisopropylammonium Salt Jack S. Summers, Diana Roe, Paul D. Boyle, Michael Colvin, and Barbara Ramsay Shaw pp 4158 - 4159; DOI: 10.1021/ic971435z |
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Synthesis of New Stanna- and Germaundecaboranes Joel A. Dopke, Douglas R. Powell, Randy K. Hayashi, and Donald F. Gaines pp 4160 - 4161; DOI: 10.1021/ic980111n |
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Cubane Clusters Containing Lanthanide Ions: (py)8Yb4Se4(SePh)4 and (py)10Yb6S6(SPh)6 Deborah Freedman, Jonathan H. Melman, T. J. Emge, and J. G. Brennan pp 4162 - 4163; DOI: 10.1021/ic9805832 |
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Hydantoin Derivatives as Spacers for Crystal Engineering in the Chemistry of Heavy Alkali Metal Ions: Synthesis and Crystal Structure of Layered (CsLOH) (L = 5,5-Dimethyl-4-oxoimidazolidine-2-thione) Massimiliano Arca, Francesco Demartin, Francesco A. Devillanova, Alessandra Garau, Francesco Isaia, Vito Lippolis, and Gaetano Verani pp 4164 - 4165; DOI: 10.1021/ic980368l |
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Protonation and Alkylation of a Dinuclear Nickel Thiolate Complex Christian B. Allan, Gerard Davidson, Suranjan B. Choudhury, Zhijie Gu, Kurethara Bose, Roberta O. Day, and Michael J. Maroney pp 4166 - 4167; DOI: 10.1021/ic9804465 |
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Aluminum Phenylphosphonates: A Fertile Family of Compounds Aurelio Cabeza, Miguel A. G. Aranda, Sebastian Bruque, Damodara M. Poojary, Abraham Clearfield, and Jesus Sanz pp 4168 - 4178; DOI: 10.1021/ic9802350 |
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Organonickel Complexes of 21,23-Dioxaporphyrin. Identification of the Paramagnetic Organonickel(II) Complex with Two 1-Phenyl Ligands Piotr J. Chmielewski and Lechos aw Latos-Grayskipp 4179 - 4183; DOI: 10.1021/ic971387i |
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Attempted Syntheses of Transition Metal and Lanthanide (Dialkylamino)squarates. The Hydrolysis Problem Hazel-Ann Hosein, Lincoln A. Hall, Alan J. Lough, William Desmarais, Michael J. Vela, and Bruce M. Foxman pp 4184 - 4189; DOI: 10.1021/ic9801490 |
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Crystal Structure and Magnetic Behavior of Two New Dinuclear Carbonato-Bridged Copper(II) Compounds. Superexchange Pathway for the Different Coordination Modes of the Carbonato Bridge in Polynuclear Copper(II) Compounds Albert Escuer, Franz A. Mautner, Evaristo Peñalba, and Ramon Vicente pp 4190 - 4196; DOI: 10.1021/ic980247l |
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Rhenium(V)-Salen Complexes: Configurational Control and Ligand Exchange Kjeld J. C. van Bommel, Willem Verboom, Huub Kooijman, Anthony L. Spek, and David N. Reinhoudt pp 4197 - 4203; DOI: 10.1021/ic980125t |
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The Early Phase of the Iron(III)-Sulfite Ion Reaction. Formation of a Novel Iron(III)-Sulfito Complex Gábor Lente and István Fábián pp 4204 - 4209; DOI: 10.1021/ic971617t |
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Dimeric Osmium Phthalocyanine Organized in Discrete Columnarly Stacked Assemblies: Structure, Magnetism, and Electrical Conductivity Properties Ruggero Caminiti, Maria Pia Donzello, Claudio Ercolani, and Claudia Sadun pp 4210 - 4213; DOI: 10.1021/ic980202k |
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Aminotriazines as Locking Fragments in Macrocyclic Synthesis Paul V. Bernhardt and Elizabeth J. Hayes pp 4214 - 4219; DOI: 10.1021/ic980243g |
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Synthesis and Structure of [(1R,2R)-C6H10(NH3)2][Ga(OH)(HPO4)2]·H2O, the First Metal Phosphate Containing a Chiral Amine Hsiu-Mei Lin and Kwang-Hwa Lii pp 4220 - 4222; DOI: 10.1021/ic980294d |
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Structural and Kinetic Studies on the Formation of Platinum(II) and Palladium(II) Complexes with L-Cysteine-Derived Ligands Tobias Rau, Ralf Alsfasser, Achim Zahl, and Rudi van Eldik pp 4223 - 4230; DOI: 10.1021/ic9711574 |
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Sulfur-Bridged Sandwich Cubane-Type Molybdenum-Antimony Cluster. Synthesis, X-ray Structure, and 121Sb Mössbauer Spectra of [(H2O)9Mo3S4SbS4Mo3(H2O)9](CH3C6H4SO3)8·24H2O Genta Sakane, Kouichi Hashimoto, Masashi Takahashi, Masuo Takeda, and Takashi Shibahara pp 4231 - 4234; DOI: 10.1021/ic971628m |
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Molecular Structures of the Heavier Alkali Metal Salts of Supermesitylphosphane: A Systematic Investigation Gerd W. Rabe, Henrike Heise, Glenn P. A. Yap, Louise M. Liable-Sands, Ilia A. Guzei, and Arnold L. Rheingold pp 4235 - 4245; DOI: 10.1021/ic971178y |
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Ferro- and Antiferromagnetic Exchange in Decamethylbimetallocenes Harald Hilbig, Peter Hudeczek, Frank H. Köhler, Xiulan Xie, Pierre Bergerat, and Olivier Kahn pp 4246 - 4257; DOI: 10.1021/ic980332t |
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Electronic Absorption Spectra and Phosphorescence of Oxygen-Containing Molybdenum(IV) Complexes Ralph A. Isovitsch, A. Scott Beadle, Frank R. Fronczek, and Andrew W. Maverick pp 4258 - 4264; DOI: 10.1021/ic971186e |
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Synthesis and Complexation Properties of the Anions (5-C5Me5)Ru(PR2O)32- as Ligands Thomas Rüther, Ulli Englert, and Ulrich Koelle pp 4265 - 4271; DOI: 10.1021/ic971319w |
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Silicon-29 NMR Studies of Tetraalkylammonium Silicate Solutions. 1. Equilibria, 29Si Chemical Shifts, and 29Si Relaxation Stephen D. Kinrade, Christopher T. G. Knight, David L. Pole, and Raymond T. Syvitski pp 4272 - 4277; DOI: 10.1021/ic971629e |
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Silicon-29 NMR Studies of Tetraalkylammonium Silicate Solutions. 2. Polymerization Kinetics Stephen D. Kinrade, Christopher T. G. Knight, David L. Pole, and Raymond T. Syvitski pp 4278 - 4283; DOI: 10.1021/ic971630d |
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Syntheses, Structures, and Reactivity of Polynuclear Pyrazolato Copper(I) Complexes, Including an ab-Initio XRPD Study of [Cu(dmnpz)]3 (Hdmnpz = 3,5-Dimethyl-4-nitropyrazole) G. Attilio Ardizzoia, Sergio Cenini, Girolamo La Monica, Norberto Masciocchi, Angelo Maspero, and Massimo Moret pp 4284 - 4292; DOI: 10.1021/ic970875n |
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Syntheses and Thermal and Chemical Behaviors of Tartrate and Succinate Intercalated Zn3Al and Zn2Cr Layered Double Hydroxides V. Prevot, C. Forano, J. P. Besse, and F. Abraham pp 4293 - 4301; DOI: 10.1021/ic9801239 |
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Alcoholysis of Urea Catalyzed by Palladium(II) Complexes Natalia V. Kaminskaia and Nenad M. Kosti pp 4302 - 4312; DOI: 10.1021/ic980065r |
Structural Aspects of the Dehydration and Dehydroxylation of  -Titanium Phosphate, -Ti(PO4)(H2PO4)·2H2OAnne Marie Krogh Andersen and Poul Norby pp 4313 - 4320; DOI: 10.1021/ic9801894 |
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Mechanism of Chlorine Dioxide and Chlorate Ion Formation from the Reaction of Hypobromous Acid and Chlorite Ion Christopher S. Furman and Dale W. Margerum pp 4321 - 4327; DOI: 10.1021/ic980262q |
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Preparation and Properties of Group 13 (Ga, In, Tl) Heterometallic Single and Corner-Shared Double Cube Derivatives of [Mo3S4(H2O)9]4+ and Related Studies Rita Hernandez-Molina, Vladimir P. Fedin, Maxim N. Sokolov, David M. Saysell, and A. Geoffrey Sykes pp 4328 - 4334; DOI: 10.1021/ic980314b |
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Solution Structures of Mono- and Ditriangular Chini Clusters of Nickel and Platinum. An X-ray Scattering and Quantum Chemical Study L. Bengtsson-Kloo, C. M. Iapalucci, G. Longoni, and S. Ulvenlund pp 4335 - 4343; DOI: 10.1021/ic971229r |
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Interaction of Carbon Dioxide with Transition-Metal-Substituted Heteropolyanions in Nonpolar Solvents. Spectroscopic Evidence for Complex Formation Steven H. Szczepankiewicz, Calogero M. Ippolito, Brian P. Santora, Thomas J. Van de Ven, Giuseppe A. Ippolito, Louise Fronckowiak, Fred Wiatrowski, Tom Power, and Mariusz Kozik pp 4344 - 4352; DOI: 10.1021/ic980162k |
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Four-Coordinate Gold(I), Silver(I), and Copper(I) Complexes with a Large-Span Chiral Ditertiary Phosphine Ligand Angela Bayler, Annette Schier, and Hubert Schmidbaur pp 4353 - 4359; DOI: 10.1021/ic980385a |
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Molecular Magnets Based on Nickel(II) Complexes with 3-Imidazoline Nitroxides and Alcohols Vladimir N. Ikorskii, Victor I. Ovcharenko, Yurii G. Shvedenkov, Galina V. Romanenko, Sergei V. Fokin, and Renad Z. Sagdeev pp 4360 - 4367; DOI: 10.1021/ic9801847 |
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Synthesis, Characterization, and Photochemical/Photophysical Properties of Ruthenium(II) Complexes with Hexadentate Bipyridine and Phenanthroline Ligands Ruth F. Beeston, W. Stephen Aldridge, Joseph A. Treadway, Michael C. Fitzgerald, Benjamin A. DeGraff, and Shannon E. Stitzel pp 4368 - 4379; DOI: 10.1021/ic971322f |
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Design and Semisynthesis of Photoactive Myoglobin Bearing Ruthenium Tris(2,2'-bipyridine) Using Cofactor-Reconstitution Itaru Hamachi, Shigeaki Tanaka, Shinya Tsukiji, Seiji Shinkai, and Shigero Oishi pp 4380 - 4388; DOI: 10.1021/ic971507m |
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Helical Figure-of-Eight Loop Dicopper(I) Compounds: Syntheses, Structures, and Dynamics Peter Comba, Andreas Fath, Trevor W. Hambley, Andreas Kühner, David T. Richens, and Annette Vielfort pp 4389 - 4401; DOI: 10.1021/ic980216q |
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Axial Coordination and Conformational Heterogeneity of Nickel(II) Tetraphenylporphyrin Complexes with Nitrogenous Bases Song-Ling Jia, Walter Jentzen, Mayou Shang, Xing-Zhi Song, Jian-Guo Ma, W. Robert Scheidt, and John A. Shelnutt pp 4402 - 4412; DOI: 10.1021/ic980289+ |
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The Aromaticity of Polyphosphaphospholes Decreases with the Pyramidality of the Tricoordinate Phosphorus Alk Dransfeld, László Nyulászi, and Paul von Ragué Schleyer pp 4413 - 4420; DOI: 10.1021/ic971385y |
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Interactions of Metal Ions with Water: Ab Initio Molecular Orbital Studies of Structure, Bonding Enthalpies, Vibrational Frequencies and Charge Distributions. 1. Monohydrates Mendel Trachtman, George D. Markham, Jenny P. Glusker, Philip George, and Charles W. Bock pp 4421 - 4431; DOI: 10.1021/ic971613o |
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Structural, Magnetic, and Photomagnetic Studies of a Mononuclear Iron(II) Derivative Exhibiting an Exceptionally Abrupt Spin Transition. Light-Induced Thermal Hysteresis Phenomenon Jean-François Létard, Philippe Guionneau, Louis Rabardel, Judith A. K. Howard, Andres E. Goeta, Daniel Chasseau, and Olivier Kahn pp 4432 - 4441; DOI: 10.1021/ic980107b |
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Theoretical Study of Stable Trans and Cis Isomers in [UO2(OH)4]2- Using Relativistic Density Functional Theory Georg Schreckenbach, P. Jeffrey Hay, and Richard L. Martin pp 4442 - 4451; DOI: 10.1021/ic980057a |
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Altering the Balance between Ligand-Based Radical Anion Formation and Dechelation in Electrochemically Reduced Binuclear Copper(I) Complexes: A Resonance Raman Spectroelectrochemical Study Simon E. Page, Keith C. Gordon, and Anthony K. Burrell pp 4452 - 4459; DOI: 10.1021/ic9715052 |
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Crown Ether Encapsulation Effects on the Optical Properties of Delocalized and Partially Localized Bridged Ruthenium Dimers Alessandro Ferretti, Alessandro Lami, and Giovanni Villani pp 4460 - 4465; DOI: 10.1021/ic9713691 |
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Synthesis and Structural Characterization of the One-Dimensional [Cu(3-Clpy)2(N3)2]n Complex (3-Clpy = 3-Chloropyridine): A Singular Ferrimagnetic Chain with Local SA = SB Albert Escuer, Ramon Vicente, Mohamed S. El Fallah, Mohamed A. S. Goher, and Franz A. Mautner pp 4466 - 4469; DOI: 10.1021/ic971569c |
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Hydrogen- and Covalent-Bond-Linked 3D Manganese Array Chang Seop Hong and Youngkyu Do pp 4470 - 4472; DOI: 10.1021/ic9715254 |
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Single-Thiolato-Bridged Pd2 or PdPt Binuclear Compounds: Crystal Structure of [{Pd(C6F5)phen}(-SC6F5){Pt(C6F5)dppe}]SO3CF3·CH2Cl2 Rafael Usón, Miguel A. Usón, Santiago Herrero, and Luis Rello pp 4473 - 4476; DOI: 10.1021/ic980015m |
Issue 18
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New Cleft-Containing Heterosubstituted Cyclophosphazanes Monte L. Helm, Bruce C. Noll, and Arlan D. Norman pp 4478 - 4479; DOI: 10.1021/ic971583p |
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Chemical Rearrangement under Hydrothermal Conditions: Formation of Polymeric Chains (CuX)2(dpiz) and (CuX)3(dpiz) (X = Cl, Br; dpiz = Dipyrido[1,2-a:2',3'-d]imidazole) and Crystal Structures of %@be@%1%@sxx@%%@mx@%%@be@%1%@sxx@%%@mx@% Jack Y. Lu, Brenda R. Cabrera, Ru-Ji Wang, and Jing Li pp 4480 - 4481; DOI: 10.1021/ic980453t |
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Synthesis and Structure of a Dichromatetraborane Derivative [{(OC)4Cr}2(4-H,H',H'',H'''-BH2BH2·PMe2CH2PMe2)] Mitsuhiro Hata, Yasuro Kawano, and Mamoru Shimoi pp 4482 - 4483; DOI: 10.1021/ic980535h |
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A Multistep Topotactic Route to the New Mixed-Valence Titanate, Na2-x+yCax/2La2Ti3O10. Electron Localization Effects in a Triple-Layered Perovskite John N. Lalena, Brian L. Cushing, Alexander U. Falster, William B. Simmons, Jr., Candace T. Seip, Everett E. Carpenter, Charles J. O'Connor, and John B. Wiley pp 4484 - 4485; DOI: 10.1021/ic980611g |
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Synthesis and Characterization of New Symmetrical Binucleating Ligands and Their -Phenoxo-Bridged Bicopper(II) Complexes: Structural, Electrochemical, and Magnetic Studies P. Amudha, M. Kandaswamy, L. Govindasamy, and D. Velmurugan pp 4486 - 4492; DOI: 10.1021/ic9714955 |
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Reactivity of the Verdoheme Analogues, 5-Oxaporphyrin Complexes of Cobalt(II) and Zinc(II), with Nucleophiles: Opening of the Planar Macrocycle by Alkoxide Addition To Form Helical Complexes Lechos aw Latos-Grayski, James Johnson, Saeed Attar, Marilyn M. Olmstead, and Alan L. Balchpp 4493 - 4499; DOI: 10.1021/ic971584h |
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The Synthesis of 15N- and 18O-Isotopically-Enriched Nitryl Bromide, IR Matrix Spectra, and Force Fields of BrNO2, cis-BrONO, and trans-BrONO Dieter Scheffler and Helge Willner pp 4500 - 4506; DOI: 10.1021/ic9803006 |
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Bridged Aminotroponiminate Complexes of Lanthanum Peter W. Roesky pp 4507 - 4511; DOI: 10.1021/ic980474n |
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Coordination of NO2 to Cu and Mg in M(NO2)2 Complexes. A Theoretical Study Luis Rodríguez-Santiago, Xavier Solans-Monfort, Mariona Sodupe, and Vicenç Branchadell pp 4512 - 4517; DOI: 10.1021/ic980187j |
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Proximate Nitroxide Ligands in the Coordination Spheres of Manganese(II) and Nickel(II) Ions. Precursors for High-Dimensional Molecular Magnetic Materials Karine Fegy, Nathalie Sanz, Dominique Luneau, Elie Belorizky, and Paul Rey pp 4518 - 4523; DOI: 10.1021/ic971618l |
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1D Manganese(II) Derivatives of an Imidazole-Substituted Nitronyl Nitroxide. An Approach toward Molecular Magnetic Materials of High Dimensionality Karine Fegy, Dominique Luneau, Elie Belorizky, Miguel Novac, Jean-Louis Tholence, Carley Paulsen, Thorsten Ohm, and Paul Rey pp 4524 - 4532; DOI: 10.1021/ic971619d |
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Efficient Light-to-Electrical Energy Conversion with Dithiocarbamate-Ruthenium Polypyridyl Sensitizers Roberto Argazzi, Carlo A. Bignozzi, Georg M. Hasselmann, and Gerald J. Meyer pp 4533 - 4537; DOI: 10.1021/ic980340+ |
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Vinylic C-H Bond Activation and Hydrogenation Reactions of Tp'Ir(C2H4)(L) Complexes Enrique Gutiérrez-Puebla, Ángeles Monge, M. Carmen Nicasio, Pedro J. Pérez, Manuel L. Poveda, Luis Rey, Caridad Ruíz, and Ernesto Carmona pp 4538 - 4546; DOI: 10.1021/ic9800785 |
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Transmission of Magnetic Interactions through an Organometallic Coupler: A Novel Family of Metallocene-Substituted -Nitronyl Aminoxyl Radicals O. Jürgens, J. Vidal-Gancedo, C. Rovira, K. Wurst, C. Sporer, B. Bildstein, H. Schottenberger, P. Jaitner, and J. Veciana pp 4547 - 4558; DOI: 10.1021/ic980495h |
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Characterization of Actinide Bonding in Th(S2PMe2)4 by Synchrotron X-ray Diffraction Bo B. Iversen, Finn K. Larsen, Alan A. Pinkerton, Anthony Martin, Alexander Darovsky, and Philip A. Reynolds pp 4559 - 4566; DOI: 10.1021/ic9715613 |
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Electronic, Spectral, and Electrochemical Properties of (TPPBrx)Zn Where TPPBrx Is the Dianion of -Brominated-Pyrrole Tetraphenylporphyrin and x Varies from 0 to 8 Francis D'Souza, Melvin E. Zandler, Pietro Tagliatesta, Zhongping Ou, Jianguo Shao, Eric Van Caemelbecke, and Karl M. Kadish pp 4567 - 4572; DOI: 10.1021/ic980336y |
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Synthesis and Electrochemistry of Tin(IV) Octaethylcorroles, (OEC)Sn(C6H5) and (OEC)SnCl Karl M. Kadish, Stefan Will, Victor A. Adamian, Burkhard Walther, Christoph Erben, Zhongping Ou, Ning Guo, and Emanuel Vogel pp 4573 - 4577; DOI: 10.1021/ic980283k |
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Coordination Chemistry of the Amonabactins, Bis(catecholate) Siderophores from Aeromonas hydrophila Jason R. Telford and Kenneth N. Raymond pp 4578 - 4583; DOI: 10.1021/ic980090x |
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Vertical Ionization Energies and Electron Affinities of Ions in Solution from Outer-Sphere Charge Transfer Transition Energies S. I. Gorelsky, V. Yu. Kotov, and A. B. P. Lever pp 4584 - 4588; DOI: 10.1021/ic980217i |
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Charge-Transfer Spectra and Bonding in Tetrahedral MnVI, CrV, and VIV and MnVII, CrVI, and VV Oxo Anions M. Atanasov, T. C. Brunold, H. U. Güdel, and C. Daul pp 4589 - 4602; DOI: 10.1021/ic971014h |
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The First Platinum(IV) Complexes with Glucopyranoside Ligands. A New Coordination Mode of Carbohydrates Henrik Junicke, Clemens Bruhn, Dieter Ströhl, Ralph Kluge, and Dirk Steinborn pp 4603 - 4606; DOI: 10.1021/ic9801692 |
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A Novel Mixed Macrocycle Complex of Nickel: Synthesis, Structure, and Redox Chemistry of [NiII([9]aneN3)([9]aneS3)](ClO4)2·CHCl3 ([9]aneN3 = 1,4,7-Triazacyclononane and [9]aneS3 = 1,4,7-Trithiacyclononane) A. McAuley, S. Subramanian, M. J. Zaworotko, and R. Atencio pp 4607 - 4610; DOI: 10.1021/ic980099z |
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Ligand Exchange or Reduction at Multiply Bonded Dimetal Units of Molybdenum and Rhenium by 2,6-Bis(diphenylphosphino)pyridine F. Albert Cotton, Evgeny V. Dikarev, Glenn T. Jordan IV, Carlos A. Murillo, and Marina A. Petrukhina pp 4611 - 4616; DOI: 10.1021/ic980455d |
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Synthesis of Nanoporous Cubic In(CN)3 and In1-xGax(CN)3 and Corresponding Inclusion Compounds Darrick Williams, J. Kouvetakis, and M. O'Keeffe pp 4617 - 4620; DOI: 10.1021/ic971638n |
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Base Hydrolysis of Methyltrioxorhenium. The Mechanism Revised and Extended: A Novel Application of Electrospray Mass Spectrometry James H. Espenson, Haisong Tan, Sahana Mollah, R. S. Houk, and Matthew D. Eager pp 4621 - 4624; DOI: 10.1021/ic980447x |
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Syntheses, Molecular Structures, and Spectroscopy of Gold(III) Dithiolate Complexes M. Adnan Mansour, Rene J. Lachicotte, Henry J. Gysling, and Richard Eisenberg pp 4625 - 4632; DOI: 10.1021/ic980032b |
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ESR Investigations of the Radicals {Li3[E(NtBu)3]2} (E = S, Se) and the Radical Anions SOx(NtBu)3-x- (x = 1, 2) Justin K. Brask, Tristram Chivers, Bruce McGarvey, Gabriele Schatte, Raymond Sung, and René T. Boeré pp 4633 - 4636; DOI: 10.1021/ic9803560 |
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One-Dimensional Coordination Polymers of Cobalt with 4,4'-Bipyridine: Syntheses and Structures Jian Lu, Carolyn Yu, Tianyan Niu, Tasneem Paliwala, Gerardo Crisci, Fernando Somosa, and Allan J. Jacobson pp 4637 - 4640; DOI: 10.1021/ic971614g |
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Correlation of a Solution-State Conformational Change between Mercuric Chloride Complexes of Tris[(2-(6-methylpyridyl))methyl]amine with X-ray Crystallographic Structures Deborah C. Bebout, James F. Bush II, Kathleen K. Crahan, Margaret E. Kastner, and Damon A. Parrish pp 4641 - 4646; DOI: 10.1021/ic980296y |
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Functionalized 2-Pyridyl-Substituted Metallo-1,2-enedithiolates. Synthesis, Characterization, and Photophysical Properties of (dppe)M{S2C2(2-pyridine(ium))(CH2CH2OR'')} and (dppe)M[{S2C2(CH2CH2-N-2-pyridinium)}]+ (R'' = H, Acetyl, Lauroyl; M = Pd, Pt; dppe = 1,2-Bis(diphenylphosphino)ethane) Kelly A. Van Houten, Danica C. Heath, Chris A. Barringer, Arnold L. Rheingold, and Robert S. Pilato pp 4647 - 4653; DOI: 10.1021/ic980273j |
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The Alkaline Transition of Bis(N-acetylated) Heme Undecapeptide Angela D. Carraway, Gregory T. Miller, Linda L. Pearce, and Jim Peterson pp 4654 - 4661; DOI: 10.1021/ic971391u |
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On the Reaction of Phosphorous Acid with Superacids and the Crystal Structure of H5O2+SbF6- and Me4N+HPF5- Rolf Minkwitz, Stefan Schneider, and Andreas Kornath pp 4662 - 4665; DOI: 10.1021/ic971252c |
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Formation of Lanthanide and Actinide Oxonium Ion Complexes with Crown Ethers from a Liquid Clathrate Medium Hany Hassaballa, Jonathan W. Steed, Peter C. Junk, and Mark R. J. Elsegood pp 4666 - 4671; DOI: 10.1021/ic9802597 |
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Mechanism of the Topotactic Formation of -Zirconium Phosphate Covalently Pillared with Diphosphonate Groups G. Alberti, E. Giontella, S. Murcia-Mascarós, and R. Vivani pp 4672 - 4676; DOI: 10.1021/ic980400b |
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Synthesis, Characterization, and Molecular Structures of Diethylnitrosamine Metalloporphyrin Complexes of Iron, Ruthenium, and Osmium Li Chen, Geun-Bae Yi, Li-Sheng Wang, Udeni R. Dharmawardana, Amelia C. Dart, Masood A. Khan, and George B. Richter-Addo pp 4677 - 4688; DOI: 10.1021/ic9801591 |
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Synthesis, Characterization, and Solid-State Molecular Structures of Nitrosoarene Complexes of Osmium Porphyrins Li Chen, Masood A. Khan, George B. Richter-Addo, Victor G. Young, Jr., and Douglas R. Powell pp 4689 - 4696; DOI: 10.1021/ic980463u |
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Hydrothermal Synthesis and Structure of a Potassium Tantalum Defect Pyrochlore Niangao Duan, Zheng-Rong Tian, William S. Willis, Steven L. Suib, John M. Newsam, and Steven M. Levine pp 4697 - 4701; DOI: 10.1021/ic980040s |
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Structural Variation in Manganase Complexes: Synthesis and Characterization of Manganese Complexes from Carboxylate-containing Chelating Ligands Hitoshi Iikura and Toshi Nagata pp 4702 - 4711; DOI: 10.1021/ic971184u |
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Heterodinuclear Complexes Containing d- and f-block Elements: Synthesis, Structural Characterization, and Metal-Metal Interactions of Novel Chromium(III)-Lanthanide(III) Compounds Bridged by Oxalate Takayuki Sanada, Takayoshi Suzuki, Takafumi Yoshida, and Sumio Kaizaki pp 4712 - 4717; DOI: 10.1021/ic971568k |
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Syntheses and Structure Determinations of Calcium Thiolates Scott Chadwick, Ulrich Englich, Bruce Noll, and Karin Ruhlandt-Senge pp 4718 - 4725; DOI: 10.1021/ic980086l |
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Monocyclopentadienyl-Titanium Aryloxide Sulfide Complexes Andrea V. Firth and Douglas W. Stephan pp 4726 - 4731; DOI: 10.1021/ic9800839 |
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Cyclopentadienyl-Bis-Aryloxide Titanium Complexes Andrea V. Firth and Douglas W. Stephan pp 4732 - 4734; DOI: 10.1021/ic9800841 |
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Synthesis, Crystal Structure, and Magnetic Properties of a One-Dimensional Polymeric Copper(II) Complex, Containing Unicoordinated Phthalato Bridges Evangelos G. Bakalbassis, Damianos G. Paschalidis, Catherine P. Raptopoulou, and Vasilis Tangoulis pp 4735 - 4737; DOI: 10.1021/ic980034w |
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Benefits of the Chelate Effect: Preparation of an Unsymmetrical ansa-Bis(imido)molybdenum Complex Containing a Seven-Membered Chelate Ring Ulrich Siemeling, Thomas Türk, Wolfgang W. Schoeller, Carl Redshaw, and Vernon C. Gibson pp 4738 - 4739; DOI: 10.1021/ic9800381 |
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Synthesis, Molecular Structure, and Properties of a Neutral Schiff Base Phenolic Complex of Magnesium Valery R. Polyakov, Vijay Sharma, Carolyn L. Crankshaw, and David Piwnica-Worms pp 4740 - 4742; DOI: 10.1021/ic971466u |
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Synthesis, Structure, Hydrolysis, and Film Deposition Studies of Complexes of the Formula [NbCl4(S2R2)2][NbCl6] Peggy J. McKarns, Mary Jane Heeg, and Charles H. Winter pp 4743 - 4747; DOI: 10.1021/ic980150z |
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Electron-Transfer Oxidation by Phase-Separating Reagents Robert E. Patterson, Scott W. Gordon-Wylie, Christine G. Woomer, Richard E. Norman, Susan T. Weintraub, Colin P. Horwitz, and Terrence J. Collins pp 4748 - 4750; DOI: 10.1021/ic9803661 |
Issue 19
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Crystal Structure and Vibrational Spectra of a New Viologen Gold(I) Iodide Zhongjia Tang, A. P. Litvinchuk, Hye-G. Lee, and Arnold M. Guloy pp 4752 - 4753; DOI: 10.1021/ic980141q |
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Phenyltris((tert-butylthio)methyl)borate: A Second Generation S3- Ligand That Enforces Tetrahedral Coordination Peter J. Schebler, Charles G. Riordan, Ilia A. Guzei, and Arnold L. Rheingold pp 4754 - 4755; DOI: 10.1021/ic980514n |
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Self-Assembly of 1-D Chains of Different Topologies Using the Hydrogen-Bonded Inorganic Supramolecular Synthons N-H···Cl2M or N-H···Cl3M Juan C. Mareque Rivas and Lee Brammer pp 4756 - 4757; DOI: 10.1021/ic9805269 |
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Isomeric Forms of [Mn12O12(O2CR)16(H2O)4] Single-Molecule Magnets Ziming Sun, Daniel Ruiz, Evan Rumberger, Christopher D. Incarvito, Kirsten Folting, Arnold L. Rheingold, George Christou, and David N. Hendrickson pp 4758 - 4759; DOI: 10.1021/ic980600n |
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An 17O-NMR Study of the Exchange of Water on AlOH(H2O)52+(aq) Jan P. Nordin, David J. Sullivan, Brian L. Phillips, and William H. Casey pp 4760 - 4763; DOI: 10.1021/ic980333l |
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Low-Temperature Syntheses and Characterization of Novel Layered Tellurites, A2Mo3TeO12 (A = NH4, Cs), and "Zero-Dimensional" Tellurites, A4Mo6Te2O24·6H2O (A = Rb, K) Vidyavathy Balraj and K. Vidyasagar pp 4764 - 4774; DOI: 10.1021/ic980102e |
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3D Extended Supramolecular Structures via H-Bonded Linkages of 2D Sheetlike or 1D Zigzag Coordination Polymers Zhong-Ning Chen, Hua-Xin Zhang, Kai-Bei Yu, Bei-Sheng Kang, Hu Cai, Cheng-Yong Su, Tian-Wei Wang, and Zhong-Lin Lu pp 4775 - 4781; DOI: 10.1021/ic980116k |
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Electropolymerized Films of Macromeric Assemblies Toru Kajita, Robert M. Leasure, Martin Devenney, Duane Friesen, and Thomas J. Meyer pp 4782 - 4794; DOI: 10.1021/ic971279w |
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Critical Evaluation of Metal Complex Molecular Mechanics. Part 1. Cobalt(III) Hexaamines Alexia M. T. Bygott and Alan M. Sargeson pp 4795 - 4806; DOI: 10.1021/ic971222+ |
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Synthesis and Reactivity of Nickel(II) Complexes of the Pyridine-Based Phosphorus-Containing Macrocycle 6-Phenyl-15-aza-6-phospha-3,9- dithiabicyclo[9,3,1]pentadeca-1(15),11,13-triene Lluis Escriche, José Antonio Muñoz, Joan Rosell, Raikko Kivekäs, Reijo Sillanpää, and Jaume Casabó pp 4807 - 4813; DOI: 10.1021/ic9714753 |
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1H NMR Study of the Reduced Cytochrome c' from Rhodopseudomonas palustris Containing a High-Spin Iron(II) Heme Moiety Ivano Bertini, Alexander Dikiy, Claudio Luchinat, Riccardo Macinai, and Maria Silvia Viezzoli pp 4814 - 4821; DOI: 10.1021/ic980531c |
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Transition Metal Derivatives of a ((Dimethylamino)ethyl)cyclopentadienyl Ligand. Synthesis and Structures of Amino-Containing Cyclopentadienyl Derivatives of Cobalt(I) and -(III) Including Water-Soluble Compounds A. I. Philippopoulos, R. Bau, R. Poilblanc, and N. Hadjiliadis pp 4822 - 4827; DOI: 10.1021/ic970740h |
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Heterometallic One-Dimensional Arrays Containing Cyanide-Bridged Lanthanide(III) and Transition Metals David W. Knoeppel, Jianping Liu, Edward A. Meyers, and Sheldon G. Shore pp 4828 - 4837; DOI: 10.1021/ic980449h |
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Effect of Protonation on Peroxo-Copper Bonding: Spectroscopic and Electronic Structure Study of [Cu2((UN-O-)(OOH)]2+ David E. Root, Mohammed Mahroof-Tahir, Kenneth D. Karlin, and Edward I. Solomon pp 4838 - 4848; DOI: 10.1021/ic980606c |
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An EPR Study of 2,3-Bis(diphenylphosphino)maleic Anhydride (BMA) Complexes and the BMA Radical Anion Noel W. Duffy, Ross R. Nelson, Michael G. Richmond, Anne L. Rieger, Philip H. Rieger, Brian H. Robinson, David R. Tyler, Jian Cheng Wang, and Kaiyuan Yang pp 4849 - 4856; DOI: 10.1021/ic980581h |
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Quantification of Outer-Sphere Macrochelate Formation in the Ternary cis-Diammine-Platinum(II)-Bis-2'-deoxyguanosine 5'-Monophosphate Complex, cis-(NH3)2Pt(dGMP)22-, and Formation of Quaternary Mixed Metal Ion Species with Magnesium(II), Copper(II), or Zinc(II) in Aqueous Solution Bin Song, Gerda Oswald, Jing Zhao, Bernhard Lippert, and Helmut Sigel pp 4857 - 4864; DOI: 10.1021/ic980126l |
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17O NMR Study of Solvent Exchange in Some Aqueous [Co(tren)(X)(OH2/OH)]n+, [Co(cyclen)(X)(OH2/OH)]n+, and [Co(N-Mecyclen)(X)(OH2/OH)]n+ Systems (X = NH3, OH2/OH; n = 3, 2, 1) Nicola E. Brasch, David A. Buckingham, Charles R. Clark, and Andrew J. Rogers pp 4865 - 4871; DOI: 10.1021/ic980221u |
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Kinetics of Hydrolysis of Phenyl Acetates Catalyzed by the Zinc(II) Complex of 1,5,9-Triazacyclododecane. Evidence for Attack of Water or Hydroxide Ion at the Coordinated Ester Junghun Suh, Sang Jun Son, and Myunghyun Paik Suh pp 4872 - 4877; DOI: 10.1021/ic980205x |
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Synthesis, Crystal and Network Structures, and Magnetic Properties of a Hybrid Layered Compound: [K(18-cr)(2-PrOH)2][{Mn(acacen)}2{Fe(CN)6}] (18-cr = 18-Crown-6-ether, acacen = N,N'-Ethylenebis(acetylacetonylideneiminate)) Hitoshi Miyasaka, Hisashi Okawa, Akira Miyazaki, and Toshiaki Enoki pp 4878 - 4883; DOI: 10.1021/ic980448p |
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Structural, Chemical, and Theoretical Evidence for the Electrophilicity of the [C6F5Xe]+ Cation in [C6F5Xe][AsF6] Hermann-J. Frohn, Angela Klose, Thorsten Schroer, Gerald Henkel, Volker Buss, Daniel Opitz, and Rainer Vahrenhorst pp 4884 - 4890; DOI: 10.1021/ic9801903 |
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Reactions of [t-Bu2SnO]3 with [t-BuX2Si]2 (X = F, Cl). Syntheses and Structures of Novel Stannasiloxanes and of [(t-Bu2FSn)2O]2, the First Fluorine-Containing Tetraorganodistannoxane Jens Beckmann, Monique Biesemans, Karl Hassler, Klaus Jurkschat, Jose C. Martins, Markus Schürmann, and Rudolph Willem pp 4891 - 4897; DOI: 10.1021/ic971504+ |
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Molecular Heme-Cyanide-Copper Bridged Assemblies: Linkage Isomerism, Trends in CN Values, and Relation to the Heme-a3/CuB Site in Cyanide-Inhibited Heme-Copper Oxidases Booyong S. Lim and R. H. Holm pp 4898 - 4908; DOI: 10.1021/ic9801793 |
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Metal-Metal Bonding in Pentanuclear Bow-Tie Metal Sulfido Clusters. Synthetic and Structural Studies on the Cationic Pentanuclear Clusters [(Cp*Ir)2(3-S)2M(3-S)2(IrCp*)2]n+ (M = Fe, Co, Ni; n = 1, 2) Zhen Tang, Yasuo Nomura, Shigeki Kuwata, Youichi Ishii, Yasushi Mizobe, and Masanobu Hidai pp 4909 - 4920; DOI: 10.1021/ic9806885 |
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Synthetic Ways to Tris(nucleobase) Complexes Derived from cis-Diammineplatinum(II) and a Platinum(II) Complex Containing Four Different Ligands, Three of Which Are Nucleobases Alexander Hegmans, Michal Sabat, Ivan Baxter, Eva Freisinger, and Bernhard Lippert pp 4921 - 4928; DOI: 10.1021/ic9802193 |
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Single-Crystal, Solid-State, and Solution 113Cd and 77Se NMR and X-ray Single-Crystal Study of a [Cd(SeR)2(N-donor)2] Complex Raju Subramanian, Nandakumar Govindaswamy, Rodolfo A. Santos, Stephen A. Koch, and Gerard S. Harbison pp 4929 - 4933; DOI: 10.1021/ic9709943 |
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Chelated Borates: Synthesis, Reactivity, and Cation Formation Pingrong Wei and David A. Atwood pp 4934 - 4938; DOI: 10.1021/ic971595a |
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Iron-Manganese Redox Processes and Synergism in the Mechanism for Manganese-Catalyzed Autoxidation of Hydrogen Sulfite Sture Fronaeus, Johan Berglund, and Lars I. Elding pp 4939 - 4944; DOI: 10.1021/ic980225z |
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Cyclic Three-, Four-, Five-, and Six-Coordinate Nitrogen-Containing Phosphorus Compounds Varying in Ring Size from Five- to Ten-Membered. P-N Donor Action Natalya V. Timosheva, A. Chandrasekaran, Roberta O. Day, and Robert R. Holmes pp 4945 - 4952; DOI: 10.1021/ic980660t |
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Computational Study of B4H10 Addition to Ethene. Baskets from Boranes Michael Bühl and Michael L. McKee pp 4953 - 4958; DOI: 10.1021/ic980352v |
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Bi-, Tri-, and Tetranuclear Metallomacrocycles Constructed by Metal-Directed Reactions Involving Resorcinol or Hydroquinone or by Addition of Octahedral Metal Centers to Tetrahexylcalix[4]resorcinarene: X-ray Crystal Structure of syn,syn-[Mo{HB(3,5-Me2C3HN2)3}(NO)(1,4-O2C6H4)]3 Ferida S. McQuillan, Timothy E. Berridge, Hongli Chen, Thomas A. Hamor, and Christopher J. Jones pp 4959 - 4970; DOI: 10.1021/ic9803659 |
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19F NMR and Structural Evidence for Spin-State Modulation of Six-Coordinate Cobalt(II) in a Weak Field Porphyrin Ligand Valeriy V. Smirnov, Eric K. Woller, and Stephen G. DiMagno pp 4971 - 4978; DOI: 10.1021/ic980156o |
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Molecular Rhenium(V) Oxotransferases: Oxidation of Thiols to Disulfides with Sulfoxides. The Case of Substrate-Inhibited Catalysis Mahdi M. Abu-Omar and Saeed I. Khan pp 4979 - 4985; DOI: 10.1021/ic980348j |
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Novel Cofacial Ruthenium(II) Porphyrin Dimers and Tetramers Kenji Funatsu, Taira Imamura, Akio Ichimura, and Yoichi Sasaki pp 4986 - 4995; DOI: 10.1021/ic971361r |
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Powder Structure Solutions of the Compounds Potassium Phenoxide-Phenol: C6H5OK·xC6H5OH (x = 2, 3) R. E. Dinnebier, M. Pink, J. Sieler, P. Norby, and P. W. Stephens pp 4996 - 5000; DOI: 10.1021/ic980350a |
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Substitution and Redox Chemistry of [Bu4N]2[Ta6Cl12(OSO2CF3)6] Nicholas Prokopuk, Vance O. Kennedy, Charlotte L. Stern, and Duward F. Shriver pp 5001 - 5006; DOI: 10.1021/ic980334d |
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K4Au(TlSn3): A Novel Zintl Phase with an Anionic Chain Daping Huang and John D. Corbett pp 5007 - 5010; DOI: 10.1021/ic980579q |
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Time-Resolved Resonance Raman Spectroscopy at Low Temperature. The Excited-State Metal-Metal Stretching Frequency of Rh2(TMB)42+ (TMB = 2,5-Dimethyl-2,5-diisocyanohexane) Richard F. Dallinger, Matt J. Carlson, Vincent M. Miskowski, and Harry B. Gray pp 5011 - 5013; DOI: 10.1021/ic980130x |
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Synthesis and Spectroscopic Characterization of Zinc Tetra(3,4-pyridine)Porphyrazine Entrapped within the Supercages of Y-Zeolite Witold S. Szulbinski and James R. Kincaid pp 5014 - 5020; DOI: 10.1021/ic971118s |
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Crystal Structures of a Series of Novel Alkylammonium Phosphates and Their Formation in Aluminophosphate Synthesis Mixtures Scott R. J. Oliver, Alan J. Lough, and Geoffrey A. Ozin pp 5021 - 5028; DOI: 10.1021/ic980069w |
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Stoichiometric and Metal-Deficient Copper(II) Complexes of a Dinucleating Macrocyclic Ligand. Structural Studies Sujit K. Dutta, Ulrich Flörke, Sasankasekhar Mohanta, and Kamalaksha Nag pp 5029 - 5032; DOI: 10.1021/ic971582x |
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Synthesis and Spectroscopic and Theoretical Characterization of the Elongated Dihydrogen Complex OsCl2(2-H2)(NH=CPh2)(PiPr3)2 Guada Barea, Miguel A. Esteruelas, Agustí Lledós, Ana M. López, and José I. Tolosa pp 5033 - 5035; DOI: 10.1021/ic980592a |
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1,3-Di(tert-butyl)-2,4-di(tert-butylamido)-2,4-di- methylcyclodisilazane: A Chelating Ancillary Diamide Ligand for Transition Metals Luke Grocholl, Lothar Stahl, and Richard J. Staples pp 5036 - 5038; DOI: 10.1021/ic9801140 |
Issue 20
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Four-Electron Reduction of Metal Sulfides by Alkynes and the Reversible Formation of Persulfides Jonathan T. Goodman and Thomas B. Rauchfuss pp 5040 - 5041; DOI: 10.1021/ic980596f |
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Crown-Ether-Functionalized Mn(III) Salicylaldimine Complexes as Ditopic Carriers. Efficient Transport of Tryptophan and Serotonin across a CHCl3 Barrier Dell T. Rosa, Victor G. Young, and D. Coucouvanis pp 5042 - 5043; DOI: 10.1021/ic9808910 |
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Mixed Adenine, Guanine Nucleobase Quartets: Metal-Modified Forms of an Open U and a Closed Rectangle Marc Sven Lüth, Eva Freisinger, Frank Glahé, and Bernhard Lippert pp 5044 - 5045; DOI: 10.1021/ic9808495 |
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Preparation, Structure, and Density Functional Calculation of the Solvent-Separated Ion Pair [(H5C2)Al(OC6H5)3-···Li+···-(H5C6O)3Al(C4H9)]-[Li+(DME)3] H. Bock, R. Beck, Z. Havlas, and H. Schödel pp 5046 - 5049; DOI: 10.1021/ic961484w |
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Heteroditopic Cryptands of Tunable Cavity Size: Imposition of Distorted Geometry onto Copper(II) and Nickel(II) and Molecular Recognition of Water Molecules Dillip K. Chand and Parimal K. Bharadwaj pp 5050 - 5055; DOI: 10.1021/ic9801746 |
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Regioselective Phosphine Addition to [(5-C5Me5)Ir(5-oxocyclohexadienyl)]+ and X-ray Structure of the Stable Phenol Tautomer Complex [(5-C5Me5)Ir(4-exo-2-(PMe3)C6H5O)]+: A Key Intermediate for the Nucleophilic Phenol Functionalization Reaction J. Le Bras, H. Amouri, and J. Vaissermann pp 5056 - 5060; DOI: 10.1021/ic971427i |
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Intramolecular Photoinduced Electron Transfer in Multicomponent Rhenium(I) Donor-Acceptor Complexes Raymond Ziessel, Alberto Juris, and Margherita Venturi pp 5061 - 5069; DOI: 10.1021/ic980570o |
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Silver-Thioether Crown Complexes as Templates for the Synthesis of Extended Polyiodide Networks: Synthesis and X-ray Crystal Structures of [Ag2([15]aneS5)2]I12, [Ag([18]aneS6)]I7, [Ag([18]aneS6)]I3, and [Ag([9]aneS3)2]I5 Alexander J. Blake, Robert O. Gould, Wan-Sheung Li, Vito Lippolis, Simon Parsons, Christian Radek, and Martin Schröder pp 5070 - 5077; DOI: 10.1021/ic980413p |
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Nitronyl Nitroxide Biradicals as Tetradentate Chelates: Unusually Large Metal-Nitroxide Ferromagnetic Interactions Dominique Luneau, Francisco M. Romero, and Raymond Ziessel pp 5078 - 5087; DOI: 10.1021/ic9803412 |
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Characterization of the Binary Uranium and Thorium Tellurides U7Te12 and Th7Te12 O. Tougait, M. Potel, and H. Noël pp 5088 - 5091; DOI: 10.1021/ic9802808 |
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Bonding Properties of Siloxanes: Gas Phase Structures of N,N-Bis(trifluoromethyl)-O-(trimethylsilyl)hydroxylamine, Me3SiON(CF3)2, and Trimethylsilyl Nitrate, Me3SiONO2 Thomas Hertel, Jens Jakob, Rolf Minkwitz, and Heinz Oberhammer pp 5092 - 5096; DOI: 10.1021/ic980480j |
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Perfluorinated Diindacycles Martin Tschinkl, Annette Schier, Jürgen Riede, and François P. Gabbaï pp 5097 - 5101; DOI: 10.1021/ic980403o |
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Different Ground Spin States in Iron(III) Complexes with Quadridentate Schiff Bases: Synthesis, Crystal Structures, and Magnetic Properties Rita Hernández-Molina, Alfredo Mederos, Sixto Dominguez, Pedro Gili, Catalina Ruiz-Pérez, Alfonso Castiñeiras, Xavier Solans, Francesc Lloret, and José Antonio Real pp 5102 - 5108; DOI: 10.1021/ic980297q |
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The Second Isolable B12-Thiolate Complex, (Pentafluorophenylthiolato)cobalamin: Synthesis and Characterization Tsui-Ling Carolyn Hsu, Nicola E. Brasch, and Richard G. Finke pp 5109 - 5116; DOI: 10.1021/ic9704750 |
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Reactions of Organotitanoxane Fluorides with AlR3 (R = Me, Et, CH2Ph) and Me3SiCl: X-ray Crystal Structures of [C5Me5Ti(-O)]4F[(-F)AlMe3]3, [C5Me5Ti(-O)]4F3[(-F)Al(CH2Ph)3], [C5Me5Ti(-O)Et]4, and (C5Me5)4Ti4O5X2 (X = Cl and F) Peihua Yu, Thomas Pape, Isabel Usón, Musa A. Said, Herbert W. Roesky, Mavis L. Montero, Hans-Georg Schmidt, and Alojz Demsar pp 5117 - 5124; DOI: 10.1021/ic980450g |
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Synthesis, Structural Characterization, and Luminescence Studies of Gold(I) and Gold(III) Complexes with a Triphosphine Ligand Manuel Bardají, Antonio Laguna, Víctor M. Orera, and M. Dolores Villacampa pp 5125 - 5130; DOI: 10.1021/ic9801342 |
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Synthesis, Characterization, and Bromine Substitution of Diamine Complexes of Carboxyborane and Methoxycarbonylborane. Diazabora Rings Containing B-Carboxyl and B-Carboxylato Groups Béla Györi, Zoltán Berente, and Zoltán Kovács pp 5131 - 5141; DOI: 10.1021/ic9713442 |
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Diacetoneglucose Complexes of Manganese(II) and Iron(II) and Their Organometallic Derivatization Umberto Piarulli, Carlo Floriani, Nazzareno Re, Giuliana Gervasio, and Davide Viterbo pp 5142 - 5148; DOI: 10.1021/ic980301y |
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Derivatization of Dinitrogen by Molybdenum in Triamidoamine Complexes Myra B. O'Donoghue, William M. Davis, and Richard R. Schrock pp 5149 - 5158; DOI: 10.1021/ic9803513 |
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Optically Detected Magnetic Resonance in the Lowest Triplet State of Pd(2-thpy)2 M. Glasbeek, R. Sitters, E. van Veldhoven, A. von Zelewsky, W. Humbs, and H. Yersin pp 5159 - 5163; DOI: 10.1021/ic980251x |
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CuClCu2TeS3: Synthesis, Structure Determination, and Raman Spectroscopic Characterization of a New Zincblende Derivative A. Pfitzner pp 5164 - 5167; DOI: 10.1021/ic9804521 |
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A Novel Nonairon(III) Citrate Complex: A "Ferric Triple-Decker" Avi Bino, Itzhak Shweky, Shmuel Cohen, Erika R. Bauminger, and Stephen J. Lippard pp 5168 - 5172; DOI: 10.1021/ic9715658 |
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Metalloradical Chemistry of Cobalt(II) Porphyrins. The Syntheses, Structure, and Reactivity of Triphenyltin(II)- and Trihalomethylcobalt(III) Octaethylporphyrin Yang Cao, Jeffrey L. Petersen, and Alan M. Stolzenberg pp 5173 - 5179; DOI: 10.1021/ic980538u |
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Molecular and Electronic Structure of Nitridochromium(V) Complexes with Macrocyclic Amine Ligands Karsten Meyer, Jesper Bendix, Eckhard Bill, Thomas Weyhermüller, and Karl Wieghardt pp 5180 - 5188; DOI: 10.1021/ic980302q |
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Unusual Phosphoryl Donor Properties of O=P(MeNCH2CH2)3N Xiao-Dong Liu and John G. Verkade pp 5189 - 5197; DOI: 10.1021/ic9714652 |
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A Reinvestigation by Circular Dichroism and NMR: Ruthenium(II) and Rhodium(III) Metallointercalators Do Not Bind Cooperatively to DNA Sonya J. Franklin, Christopher R. Treadway, and Jacqueline K. Barton pp 5198 - 5210; DOI: 10.1021/ic9801948 |
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Synthesis and Characterization of Sulfur-Bridged Binuclear -Diketonatoruthenium Complexes and a Monomeric Ruthenium Complex. Crystal and Molecular Structures of Racemic and Meso Isomers of [Ru(acac)2(-topd-O,S,O')Ru(acac)2] (acac = Acetylacetonato and topd = 3-Thioxo-2,4-pentanedione) Takeshi Hashimoto, Akira Endo, Noriharu Nagao, Gen P. Satô, Karuppannan Natarajan, and Kunio Shimizu pp 5211 - 5220; DOI: 10.1021/ic971240r |
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Utility of 2-Methoxyethanol in the Synthesis of Polyeuropium Complexes: {[Eu(OCH2CH2OMe)2(OC6H3R2-2,6)-][H+]}4 (R = Me, iPr) and [EuAl2(OCH2CH2OMe)3Me5]2 William J. Evans, Michael A. Greci, and Joseph W. Ziller pp 5221 - 5226; DOI: 10.1021/ic9803311 |
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Ab Initio Calculations of the Trigonal and Zero-Field Splittings in Trischelated Diketonato Complexes of Trivalent Chromium Carl Ribbing, Kristine Pierloot, and Arnout Ceulemans pp 5227 - 5232; DOI: 10.1021/ic980161s |
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Photolysis of FeOH2+ and FeCl2+ in Aqueous Solution. Photodissociation Kinetics and Quantum Yields Victor A. Nadtochenko and John Kiwi pp 5233 - 5238; DOI: 10.1021/ic9804723 |
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Void Geometry Driven Spin Crossover in Zeolite-Encapsulated Cobalt Tris(bipyridyl) Complex Ion Satish Kumar Tiwary and Sukumaran Vasudevan pp 5239 - 5246; DOI: 10.1021/ic9711473 |
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A New Preparation and Crystal Structure of Trifluoromethyl Iodine Difluoride CF3IF2 Rolf Minkwitz and Michael Berkei pp 5247 - 5250; DOI: 10.1021/ic980503u |
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Stepwise Assembly of Tris-Heteroleptic Polypyridyl Complexes of Ruthenium(II) S. M. Zakeeruddin, Md. K. Nazeeruddin, R. Humphry-Baker, M. Grätzel, and V. Shklover pp 5251 - 5259; DOI: 10.1021/ic980357s |
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Effects of Six-Membered-Ring Conformation on the Rotamer Distribution and Rate of Atropisomerization in Platinum(II)-Guanine Compounds: 2,4-Bis(methylamino)pentane Complexes Kevin M. Williams, Leonardo Cerasino, Francesco P. Intini, Giovanni Natile, and Luigi G. Marzilli pp 5260 - 5268; DOI: 10.1021/ic980354f |
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Synthetic and Structural Studies of Heteroatom-Polyborane Clusters: Simple, High-Yield Syntheses of nido-11-Vertex Thia- and Phosphaboranes, Thia- and Phosphadicarbaboranes, and the First Thiaphosphaborane Alexandra M. Shedlow and Larry G. Sneddon pp 5269 - 5277; DOI: 10.1021/ic980445c |
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Helical Silver(I)-2,4'-Bipyridine Chains Organized into 2-D Networks by Metal-Counterion or Metal-Metal Bonding. Structures of [Ag(2,4'-bipyridine)]X (X- = NO3- or ClO4-) Ming-Liang Tong, Xiao-Ming Chen, Bao-Hui Ye, and Seik Weng Ng pp 5278 - 5281; DOI: 10.1021/ic971579d |
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Bis-Catecholate, Bis-Dithiocatecholate, and Tetraalkoxy Diborane(4) Compounds: Aspects of Synthesis and Electronic Structure Fiona J. Lawlor, Nicholas C. Norman, Nigel L. Pickett, Edward G. Robins, Paul Nguyen, Gerry Lesley, Todd B. Marder, Jennifer A. Ashmore, and Jennifer C. Green pp 5282 - 5288; DOI: 10.1021/ic980425a |
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Structural Studies of Bis-Catecholate, Bis-Dithiocatecholate, and Tetraalkoxy Diborane(4) Compounds William Clegg, Mark R. J. Elsegood, Fiona J. Lawlor, Nicholas C. Norman, Nigel L. Pickett, Edward G. Robins, Andrew J. Scott, Paul Nguyen, Nicholas J. Taylor, and Todd B. Marder pp 5289 - 5293; DOI: 10.1021/ic9804317 |
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Copper Sites in Cu-ZSM-5 Zeolites. Part II. An Identification of Defective AlOCu+ Sites by FTIR L. Chen, H. Y. Chen, J. Lin, and K. L. Tan pp 5294 - 5298; DOI: 10.1021/ic980298i |
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Platinum Group Metal Complexes of Macrocyclic Oxathiaethers. The Crystal Structures of 18S4O2, [Pt(9S2O)2](PF6)2·2CH3NO2, [Pt(18S4O2)](PF6)2, and [Pd(9S2O)2](PF6)2·2CH3CN Gregory J. Grant, David F. Galas, Myron W. Jones, Kristi D. Loveday, William T. Pennington, George L. Schimek, Cassandra T. Eagle, and Donald G. VanDerveer pp 5299 - 5305; DOI: 10.1021/ic9715714 |
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Novel Coordination Behavior of fac-[ReBr3(CO)3]2- with 1,3,5-Triaza-7-phosphaadamantane (PTA). Systematic Investigation on Stepwise Replacement of the Halides by PTA Ligand. Phase Transfer Studies and X-ray Crystal Structure of [NEt4][ReBr2((PTA)(CO)3], [ReBr(PTA)2(CO)3], and [Re(PTA)3(CO)3]PF6 Roger Schibli, Kattesh V. Katti, Wynn A. Volkert, and Charles L. Barnes pp 5306 - 5312; DOI: 10.1021/ic980373p |
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Synthesis and Reactivity of Rhodium(I) and Iridium(I) Chloride Complexes of a Trisphosphinine Nicolas Mézailles, Narcis Avarvari, Louis Ricard, François Mathey, and Pascal Le Floch pp 5313 - 5316; DOI: 10.1021/ic980353n |
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Synthesis, Characterization, and Interlayer Distance Study of Zirconium Phosphonates with Stoichiometric Variation of Methyl and p-Aminobenzyl Pendant Groups Willem R. Leenstra and Jay C. Amicangelo pp 5317 - 5323; DOI: 10.1021/ic980664y |
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Syntheses and Structural Characterizations of Two Three-Dimensional Polymers: %@be@%3%@sxx@%%@mx@% Tianyan Niu, Jian Lu, Xiqu Wang, James D. Korp, and Allan J. Jacobson pp 5324 - 5328; DOI: 10.1021/ic980536+ |
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Use of Intraligand CH Coupling Constants to Assess Binding in Organometallic Compounds. Insight into Electronic and Steric Properties of Monodentate P-Donor Ligands Scott J. Moore and Luigi G. Marzilli pp 5329 - 5335; DOI: 10.1021/ic980261y |
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Mononuclear and Binuclear Tetrapyrido[2,3-a:3',2'-c:2'',3''-h:3''',2'''-j]phenazine (tphz) Ruthenium Complexes André Gourdon and Jean-Pierre Launay pp 5336 - 5341; DOI: 10.1021/ic980312r |
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Reactions of Dichloroperfluorocycloalkenes with Triazamacrocyclic Amines O. D. Gupta, Jianguo Chen, Robert L. Kirchmeier, and Jean'ne M. Shreeve pp 5342 - 5345; DOI: 10.1021/ic980460h |
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Molecular Modeling of Dimetal Systems. Part 2. Low-Order Dimolybdenum Jan C. A. Boeyens and Françoise M. M. O'Neill pp 5346 - 5351; DOI: 10.1021/ic960267s |
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Molecular Modeling of Dimetal Systems. Part 3. Dichromium Bonds Jan C. A. Boeyens and Francoise M. M. O'Neill pp 5352 - 5357; DOI: 10.1021/ic960268k |
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Nickel Complexes of Cysteine- and Cystine-Containing Peptides: Spontaneous Formation of Disulfide-Bridged Dimers at Neutral pH Steven A. Ross and Cynthia J. Burrows pp 5358 - 5363; DOI: 10.1021/ic971075f |
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Ternary Arsenide Ba0.8Hf12As17.7, a Variant of the Cr12P7 Structure Type with Inserted Arsenic Ribbons Robert Lam and Arthur Mar pp 5364 - 5368; DOI: 10.1021/ic980545i |
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Metal-Ligand Bond Distances in First-Row Transition Metal Coordination Compounds: Coordination Number, Oxidation State, and Specific Ligand Effects Ronald F. See, Rebecca A. Kruse, and William M. Strub pp 5369 - 5375; DOI: 10.1021/ic971462p |
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Heterobimetallic Complexes of Gold(I) with the Tetrathiovanadate Anion. Crystal Structure of [VS4(AuPPh3)2{Au(PPh3)2}] Fernando Canales, M. Concepción Gimeno, and Antonio Laguna pp 5376 - 5379; DOI: 10.1021/ic9712939 |
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Diastereoselective Self-Assembly and Crystal Structure of the Chiral, Anionic Molybdenum-Based [2+2] Molecular Square [{MoO2(C21H20O4)}2]4- Anne-K. Duhme, Sian C. Davies, and David L. Hughes pp 5380 - 5382; DOI: 10.1021/ic971349z |
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Binucleating Coordination of N,N'-Ethylenebis(salicylideneamine) (H2salen) to Low-Valent Group 6 Carbonyl Complexes Donald J. Darensbourg and Jennifer D. Draper pp 5383 - 5386; DOI: 10.1021/ic980173d |
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NH4VOPO4·H2O, a New One-Dimensional Ammonium Vanadium(IV) Phosphate Hydrate Zsolt Bircsk and William T. A. Harrison pp 5387 - 5389; DOI: 10.1021/ic971481z |
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Preparation and X-ray Analysis of Crystals of Azido- and Chlorocobalamin Containing LiCl: A Structural Model for the Interactions of the Corrin Ring with Ionic Species Lucio Randaccio, Michela Furlan, Silvano Geremia, and Miroslav Slouf pp 5390 - 5393; DOI: 10.1021/ic980181u |
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Metalation of a Bis(thiophenyl)carborane Giving Both Exo and Endo Products. Synthesis and Structural Characterization of RuCl{7,8-(SPh)2-7,8-nido-C2B9H10}(p-cymene) and 1,2-(SPh)2-3-(p-cymene)-3,1,2-RuC2B9H9 Francesc Teixidor, Clara Viñas, Miguel A. Flores, Georgina M. Rosair, Alan J. Welch, and Andrew S. Weller pp 5394 - 5395; DOI: 10.1021/ic980370c |
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Lanthanide Tris(tert-butylthiolates) and the Crystal Structure of [Yb(SBut)2(2-SBut)(Bipy)]2 Helen C. Aspinall, Sharron A. Cunningham, Patrick Maestro, and Pierre Macaudiere pp 5396 - 5398; DOI: 10.1021/ic9800684 |
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Reduced Variational Space Analysis of Methane Adducts Thomas R. Cundari and Thomas R. Klinckman pp 5399 - 5401; DOI: 10.1021/ic980639s |
Fixation of Co2 by Zinc(II) Chelates in Alcoholic Medium. X-ray Structures of {[Zn(cyclen)]3( 3-Co3)}(ClO4)4 and [An(cyclen)EtOH](ClO4]2Antje Schrodt, Anton Neubrand, and Rudi van Eldik pp 5402 - 5402; DOI: 10.1021/ic980050t |
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Spectroelectrochemical Characterization of the Two-Step Redox System {(-pz)[Os(CN)5]2}n- (n = 4, 5, 6; pz = Pyrazine). Similarities and Differences in Relation to the Creutz-Taube System Fridmann M. Hornung, Frank Baumann, WolfgangKaim, José A. Olabe, Leonardo D. Slep, and JanFiedler pp 5402 - 5402; DOI: 10.1021/ic980783d |
Issue 21
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Synthesis and Characterization of Molecular Rectangles Based upon Rhenium Thiolate Dimers Kurt D. Benkstein, Joseph T. Hupp, and Charlotte L. Stern pp 5404 - 5405; DOI: 10.1021/ic980513v |
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Self-Assembly of Ligand-Bridged Molecular Rectangles Containing fac-Re(CO)3 Corners Stephen M. Woessner, Jeffrey B. Helms, Yibing Shen, and B. Patrick Sullivan pp 5406 - 5407; DOI: 10.1021/ic9805168 |
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[Pt2Cl2(2-O2)2([9]aneN3)2]Cl2: A Novel Platinum(IV) Dimer with Two Bridging Peroxo Ligands that Provides Insight into the Mechanism of Aerial Oxidation of Platinum(II) Murray S. Davies and Trevor W. Hambley pp 5408 - 5409; DOI: 10.1021/ic9806479 |
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An Unusual Cyanide Bridging Lanthanide-Transition Metal Complex that Contains the One-Dimensional Cationic Array {[(DMF)16Yb6(6-O)(3-OH)8(-NC)Pd(-CN)(CN)2]6+} Jianping Liu, Edward A. Meyers, and Sheldon G. Shore pp 5410 - 5411; DOI: 10.1021/ic9805271 |
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Azolidene Carbenes Derived from Biologically Relevant Molecules.1 Synthesis and Characterization of Iridium Complexes of Imidazolidene Ligands Based upon the Antifungal Drugs Econazole and Miconazole James H. Davis, Jr., Charles M. Lake, and Melissa A. Bernard pp 5412 - 5413; DOI: 10.1021/ic9806277 |
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Detection of Metal-Bound Histidine in Ultraviolet Resonance Raman Spectra: Superoxide Dismutase Xiaojie Zhao, Daojing Wang, and Thomas G. Spiro pp 5414 - 5415; DOI: 10.1021/ic980705q |
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Preparation and Characterization of Chiral Copper 12-Metallacrown-4 Complexes, Inorganic Analogues of Tetraphenylporphyrinatocopper(II) Jason A. Halfen, Jeffrey J. Bodwin, and Vincent L. Pecoraro pp 5416 - 5417; DOI: 10.1021/ic9807386 |
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183W NMR Study of Peroxotungstates Involved in the Disproportionation of Hydrogen Peroxide into Singlet Oxygen (1O2, 1g) Catalyzed by Sodium Tungstate in Neutral and Alkaline Water V. Nardello, J. Marko, G. Vermeersch, and J. M. Aubry pp 5418 - 5423; DOI: 10.1021/ic971607s |
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Oxorhenium(V) and Oxotechnetium(V) Complexes of Cysteine Mita Chatterjee, Basudeb Achari, Satyabrata Das, Rahul Banerjee, Chandana Chakrabarti, Jiban K. Dattagupta, and Somenath Banerjee pp 5424 - 5430; DOI: 10.1021/ic970577q |
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Lanthanum Nickel Silicides with the General Formula La(n+1)(n+2)Nin(n-1)+2Sin(n+1) and Other Series of Hexagonal Structures with Metal:Metalloid Ratios Close to 2:1 Yurij M. Prots' and Wolfgang Jeitschko pp 5431 - 5438; DOI: 10.1021/ic980397w |
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Stepwise Cluster Assembly Using VO2(acac) as a Precursor: cis-[VO(OCH(CH3)2)(acac)2], [V2O2(-OCH3)2(acac)2(OCH3)2], [V3O3{,-(OCH2)3CCH3}2(acac)2(OC2H5)], and [V4O4(-O)2(-OCH3)2(3-OCH3)2(acac)2(OCH3)2]·2CH3CN Feilong Jiang, Oren P. Anderson, Susie M. Miller, John Chen, Mohammad Mahroof-Tahir, and Debbie C. Crans pp 5439 - 5451; DOI: 10.1021/ic980410c |
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Novel Pentacyano Complexes of Tri- and Tetravalent Platinum Mikhail Maliarik, Julius Glaser, and Imre Tóth pp 5452 - 5459; DOI: 10.1021/ic980186r |
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Molecular Structure, Acidic Properties, and Kinetic Behavior of the Cationic Complex (Methyl)(dimethyl sulfoxide)(bis-2-pyridylamine)platinum(II) Ion Raffaello Romeo, Nicola Nastasi, Luigi Monsù Scolaro, Maria Rosaria Plutino, Alberto Albinati, and Alceo Macchioni pp 5460 - 5466; DOI: 10.1021/ic980423q |
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Redox Reactivity as the Controlling Element in Coordination Polymer Stereochemistry: Redox-Switched Growth Mechanism in the [FeII-CN-PtIV]n System Clark Chang, David Ludwig, and Andrew Bocarsly pp 5467 - 5473; DOI: 10.1021/ic980390e |
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Heteronuclear Hexaplatinum Cluster Complexes: Structure as a Function of Electron Count Greg J. Spivak, Jagadese J. Vittal, and Richard J. Puddephatt pp 5474 - 5481; DOI: 10.1021/ic980555j |
Theoretical Investigation of the Chemisorption of H2 and CO on the ZnO(10 0) SurfaceMaurizio Casarin, Chiara Maccato, and Andrea Vittadini pp 5482 - 5490; DOI: 10.1021/ic980443s |
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Synthesis and Properties of Polyether Adducts of Hexafluoropentanedionatosilver(I) Jawwad A. Darr, Martyn Poliakoff, Alexander J. Blake, and Wan-Sheung Li pp 5491 - 5496; DOI: 10.1021/ic971206c |
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Ruthenium Carbonyl Clusters in Faujasite Cages: Synthesis and Characterization Guo-Cheng Shen, An Ming Liu, and Masaru Ichikawa pp 5497 - 5506; DOI: 10.1021/ic9709990 |
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Synthesis and Crystal Structure of a Self-Assembled, Octanuclear Oxo-Tantalum(V) Derivative Containing the First Example of a Transition Metal M8(-O)12 Cage Paola B. Arimondo, Fausto Calderazzo, Ralph Hiemeyer, Cäcilia Maichle-Mössmer, Fabio Marchetti, Guido Pampaloni, and Joachim Strähle pp 5507 - 5511; DOI: 10.1021/ic980408l |
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Unexpectedly Lengthened N-H···Co Hydrogen Bonds? Lee Brammer, Juan C. Mareque Rivas, and Dong Zhao pp 5512 - 5518; DOI: 10.1021/ic980317o |
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Formation and Deprotonation Kinetics of the Sitting-Atop Complex of Copper(II) Ion with 5,10,15,20-Tetraphenylporphyrin Relevant to the Porphyrin Metalation Mechanism. Structure of Copper(II)-Pyridine Complexes in Acetonitrile As Determined by EXAFS Spectroscopy Yasuhiro Inada, Yumi Sugimoto, Yuko Nakano, Yuki Itoh, and Shigenobu Funahashi pp 5519 - 5526; DOI: 10.1021/ic980420d |
Hole Distribution in Underdoped and Overdoped Y(Ba2-ySry)Cu3O6+ Compounds Studied by X-ray Absorption SpectroscopyR. S. Liu, C. Y. Chang, and J. M. Chen pp 5527 - 5531; DOI: 10.1021/ic980418m |
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Dithiocarbamate Ligands as Building-Blocks in the Coordination Chemistry of Gold Eduardo J. Fernández, José M. López-de-Luzuriaga, Miguel Monge, Elena Olmos, M. Concepción Gimeno, Antonio Laguna, and Peter G. Jones pp 5532 - 5536; DOI: 10.1021/ic971600a |
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Effects of Counterions in Heteropoly Electrolyte Chemistry. 1. Evaluations of Relative Interactions by NMR on Kozik Salts James F. Kirby and Louis C. W. Baker pp 5537 - 5543; DOI: 10.1021/ic971382l |
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Kinetics and Mechanism for Formation of Olefin Complexes in the Reaction between Palladium(II) and Maleic Acid Tiesheng Shi and Lars I. Elding pp 5544 - 5549; DOI: 10.1021/ic980072f |
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Triniobium Polytungstophosphates. Syntheses, Structures, Clarification of Isomerism and Reactivity in the Presence of H2O2 Mason K. Harrup, Gyu-Shik Kim, Huadong Zeng, Rhoma P. Johnson, Don VanDerveer, and Craig L. Hill pp 5550 - 5556; DOI: 10.1021/ic980467z |
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Structures of arachno- and hypho-B10 Clusters and Stability of Their Possible Lewis Base Adducts ([B10H12]2-, [B10H12·L]2-, [B10H12·2L]2-, [B10H13]-, [B10H13·L]-, [B10H12·2L]). An ab Initio/IGLO/NMR Investigation Matthias Hofmann and Paul von Ragué Schleyer pp 5557 - 5565; DOI: 10.1021/ic9805729 |
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Synthesis, Magnetic Properties, and Incomplete Double-Cubane Structure of Manganese(III)-Metal(II) Complexes [Mn(MeOH)L(OH)M(bpy)]2 (M = Zn, Cu, Ni, and Mn; H4L = 1,2-Bis(2-hydroxybenzamido)benzene; bpy = 2,2'-Bipyridine) Yukinari Sunatsuki, Hiromitsu Shimada, Toshihiro Matsuo, Masaaki Nakamura, Fumiaki Kai, Naohide Matsumoto, and Nazzareno Re pp 5566 - 5574; DOI: 10.1021/ic980543y |
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Continuous Symmetry Measures. 5. The Classical Polyhedra Mark Pinsky and David Avnir pp 5575 - 5582; DOI: 10.1021/ic9804925 |
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Flux Synthesis of LiAuS and NaAuS: "Chicken-Wire-Like" Layer Formation by Interweaving of (AuS)nn- Threads. Comparison with -HgS and AAuS (A = K, Rb) Enos A. Axtell, III, Ju-Hsiou Liao, and Mercouri G. Kanatzidis pp 5583 - 5587; DOI: 10.1021/ic980360b |
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Formic Acid Modified Ti(OCHMe2)4. Syntheses, Characterization, and X-ray Structures of Ti4(4-O)(-O)(OFc)2(-OR)4(OR)6 and Ti6(3-O)6(OFc)6(OR)6 (OFc = O2CH; OR = OCHMe2) Timothy J. Boyle, Todd M. Alam, Cory J. Tafoya, and Brian L. Scott pp 5588 - 5594; DOI: 10.1021/ic980601f |
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Neutral Guest Capture via Lewis Acid/Base Molecular Square Receptors. X-ray Crystal Structure of {Cyclobis[(cis-(dppp)Pt(4-ethynylpyridyl)2)(cis- (PEt3)2Pt)]Ag2}+6(phenazine)- (-OSO2CF3)6 Jeffery A. Whiteford, Peter J. Stang, and Songping D. Huang pp 5595 - 5601; DOI: 10.1021/ic980727c |
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Reactivity of Hydrides FeH2(CO)2P2 (P = Phosphites) with Aryldiazonium Cations: Preparation, Characterization, X-ray Crystal Structure, and Electrochemical Studies of Mono- and Binuclear Aryldiazenido Complexes Gabriele Albertin, Stefano Antoniutti, Alessia Bacchi, Davide Barbera, Emilio Bordignon, Giancarlo Pelizzi, and Paolo Ugo pp 5602 - 5610; DOI: 10.1021/ic980430e |
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Self-Assembling Synthesis of Cyclic Tri- and Tetranuclear Cobalt(III) Complexes Bridged by Purine-6-thione and Their Characterization by Electrospray Mass Spectrometry and X-ray Crystal Analysis Kazuaki Yamanari, Ito Fukuda, Tatsuya Kawamoto, Yoshihiko Kushi, Akira Fuyuhiro, Naoko Kubota, Tsuyoshi Fukuo, and Ryuichi Arakawa pp 5611 - 5618; DOI: 10.1021/ic9802146 |
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Synthesis of Heteropolyoxometalate-Pillared Mg/Al, Mg/Ga, and Zn/Al Layered Double Hydroxides via LDH-Hydroxide Precursors Mark R. Weir and Ronald A. Kydd pp 5619 - 5624; DOI: 10.1021/ic9805067 |
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Approaches to Alkaline Earth Metal-Organic Chemical Vapor Deposition Precursors. Synthesis and Characterization of Barium Fluoro--ketoiminate Complexes Having Appended Polyether "Lariats" Deborah A. Neumayer, John A. Belot, Richard L. Feezel, Charles Reedy, Charlotte L. Stern, Tobin J. Marks, Louise M. Liable-Sands, and Arnold L. Rheingold pp 5625 - 5633; DOI: 10.1021/ic980208+ |
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Experimental and Theoretical Studies of the Site Exchanges in Rh4(CO)12 and IrRh3(CO)12 Katya Besançon, Gábor Laurenczy, Tito Lumini, Raymond Roulet, Raf Bruyndonckx, and Claude Daul pp 5634 - 5640; DOI: 10.1021/ic9804162 |
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Synthesis and Characterization of Dimeric Mutually Coordinated Magnesium meso-2-Pyridylporphyrins Nikolay N. Gerasimchuk, Andrew A. Mokhir, and Kenton R. Rodgers pp 5641 - 5650; DOI: 10.1021/ic971421t |
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Construction of Copper(I) Coordination Polymers of 1,2,4,5-Tetracyanobenzene with Zigzag Sheet and Porous Frameworks Megumu Munakata, Gui Ling Ning, Takayoshi Kuroda-Sowa, Masahiko Maekawa, Yusaku Suenaga, and Takashi Horino pp 5651 - 5656; DOI: 10.1021/ic980427v |
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Metal-Ligand Bonding in Coinage Metal-Phosphine Complexes: The Synthesis and Structure of Some Low-Coordinate Silver(I)-Phosphine Complexes Robert E. Bachman and David F. Andretta pp 5657 - 5663; DOI: 10.1021/ic980726k |
Variable Reduction Sequences for Axial (L) and Chelate Ligands (N N) in Rhenium(I) Complexes [(NN)Re(CO)3(L)]nSascha Berger, Axel Klein, Wolfgang Kaim, and Jan Fiedler pp 5664 - 5671; DOI: 10.1021/ic980268f |
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Syntheses and Characterizations of the Novel Dodecanuclear Heterobimetallic Cage Clusters: [Et4N]2[(M2Cu2S2O2edt2)3(6-S2)]·CH2Cl2 (M = Mo, W; edt = -SC2H4S-) Ping Lin, Xintao Wu, Qun Huang, Quanming Wang, Tianlu Sheng, Wenjian Zhang, Jun Guo, and Jiaxi Lu pp 5672 - 5674; DOI: 10.1021/ic9704142 |
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Concealed Asymmetry in an Exchange-Coupled Trichromium(III) Cluster: Structure and Magnetic Spectrum of [Cr3O(OOCPh)6(py)3](py)0.5ClO4 Roderick D. Cannon, Upali A. Jayasooriya, Frank E. Sowrey, Claire Tilford, Alastair Little, John P. Bourke, Robin D. Rogers, John B. Vincent, and Gordon J. Kearley pp 5675 - 5677; DOI: 10.1021/ic980188b |
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Monothioether Complexes of Osmium: The trans-[OsBr4(SR2)2] Family and mer-[OsBr3(SR2)3] Precursors Kausikisankar Pramanik, Prasanta Ghosh, and Animesh Chakravorty pp 5678 - 5680; DOI: 10.1021/ic980142i |
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Larger Cyclophanes: Synthesis and Structural Characterization of [2.2.2.2]Paracyclophane Compounds with SbBr3 and BiBr3 Marisa Belicchi Ferrari, Maria Rita Cramarossa, Dario Iarossi, and Giorgio Pelosi pp 5681 - 5685; DOI: 10.1021/ic971314z |
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Synthesis, Structure, and Properties of a Tetrametallic Ferrocenecarboxylato-Bridged Copper(II) Complex Ramon Costa, Concepción López, Elies Molins, and Enric Espinosa pp 5686 - 5689; DOI: 10.1021/ic980409d |
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Bond Valence Sum Analysis of Metalloenzymes. 3. Predicting Bond Lengths in Adjacent Redox States Using Inner-Sphere Reorganizational Energies H. Holden Thorp pp 5690 - 5692; DOI: 10.1021/ic9804420 |
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Dimerized Nickel2+ Chain Compounds with Nitro-Nitrito Bridges and Unprecedented [Ln(NO3)4(CH3OH)2]- Anions (Ln = Lanthanide). Crystal Structure and Magnetic Properties T. M. Rajendiran, Olivier Kahn, Stéphane Golhen, Lahcène Ouahab, Zentaro Honda, and Koichi Katsumata pp 5693 - 5696; DOI: 10.1021/ic980458q |
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Carbidoheptarhenate Cluster Complexes of Mercury with Hydrosulfide or Functionalized Thiolate Ligands Udo Brand and John R. Shapley pp 5697 - 5699; DOI: 10.1021/ic980591i |
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Unusual Two-Dimensional Sheet Structure of the Solvent-Free Cesium Aryloxide Complex CsO-2,6-i-Pr2C6H3 David L. Clark, Damon R. Click, Rebecca V. Hollis, Brian L. Scott, and John G. Watkin pp 5700 - 5703; DOI: 10.1021/ic980630q |
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Solvent Reorganization Energies in Excited-State Electron-Transfer Reactions. Oxidative Quenching of the MLCT Excited States of Ru(II)-Diimine Complexes Cathleen E. Crowley, Catherine D. Clark, and Morton Z. Hoffman pp 5704 - 5706; DOI: 10.1021/ic980493x |
Issue 22
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Paddle-Wheel and Trilobate Isomers of the Hexagonal Prisms {Li[CE(Nt-Bu)(n-Bu)]}6 (E = S, O) Tristram Chivers, Andrew Downard, and Glenn P. A. Yap pp 5708 - 5709; DOI: 10.1021/ic980624u |
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Highlights from Recent Work on Metal-Metal Bonds F. Albert Cotton pp 5710 - 5720; DOI: 10.1021/ic9808302 |
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Structural Comparison of Five-Coordinate Thiolate-Ligated MII = FeII, CoII, NiII, and ZnII Ions Wrapped in a Chiral Helical Ligand Steven C. Shoner, Andrew M. Nienstedt, Jeffrey J. Ellison, Irene Y. Kung, David Barnhart, and Julie A. Kovacs pp 5721 - 5726; DOI: 10.1021/ic980882r |
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Platinum(II) 1,5-COD Oxo Complexes Hui Shan, Alan James, and Paul R. Sharp pp 5727 - 5732; DOI: 10.1021/ic980818+ |
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Synthesis and Characterization of Rhodium Complexes Containing 2,4,6-Tris(2-pyridyl)-1,3,5-triazine and Its Metal-Promoted Hydrolytic Products: Potential Uses of the New Complexes in Electrocatalytic Reduction of Carbon Dioxide Parimal Paul, Beena Tyagi, Anvarhusen K. Bilakhiya, Mohan M. Bhadbhade, Eringathodi Suresh, and G. Ramachandraiah pp 5733 - 5742; DOI: 10.1021/ic9709739 |
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Determination of Iron-Ligand Bond Lengths in Horse Heart Met- and Deoxymyoglobin Using Multiple-Scattering XAFS Analyses Anne M. Rich, Robert S. Armstrong, Paul J. Ellis, Hans C. Freeman, and Peter A. Lay pp 5743 - 5753; DOI: 10.1021/ic9714549 |
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The TiNiSi Family of Compounds: Structure and Bonding Gregory A. Landrum, Roald Hoffmann, Jürgen Evers, and Hans Boysen pp 5754 - 5763; DOI: 10.1021/ic980223e |
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Structural Properties of Silver(I) and Mercury(II) Complexes of D-Lactobionate: Self-Assembled Coordination Polymers Kwan Mook Kim, Soo Chang Song, Sang Beom Lee, Hak Chul Kang, and Youn Soo Sohn pp 5764 - 5768; DOI: 10.1021/ic980257m |
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EPR Spectra from "EPR-Silent" Species: High-Field EPR Spectroscopy of Aqueous Chromium(II) Joshua Telser, Luca A. Pardi, J. Krzystek, and Louis-Claude Brunel pp 5769 - 5775; DOI: 10.1021/ic9806683 |
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Cyanoisocyanoarene Metal Complexes as Building Blocks for Coordination Polymers: Structural Nonrigidity of a Metal-Nitrile Linkage Andreas Mayr and Li-Feng Mao pp 5776 - 5780; DOI: 10.1021/ic980019r |
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Solvent-Dependent Structures of Co(NO3)2 with 1,2-Bis(4-pyridyl)ethylene. Interconversion of Molecular Ladders versus Mononuclear Complexes Ok-Sang Jung, Sung Ho Park, Kwan Mook Kim, and Ho G. Jang pp 5781 - 5785; DOI: 10.1021/ic980278g |
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Paramagnetic Rh(III) Complexes from Reactions of Phosphines with Hydride-Bridged and Nonbridged Rhodium Phthalocyanine Dimers: Metal-to-Ligand Charge Transfer Induced by Phosphines M. J. Chen, L. M. Utschig, and J. W. Rathke pp 5786 - 5792; DOI: 10.1021/ic980338i |
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Syntheses and Structures of Mixed-Metal Sulfido Clusters Containing Trimetallic M2M'S4 (M = Mo, W; M' = Pd, Pt) and Tetrametallic Cubane-Type Mo2Pd2S4 Cores Tomotake Ikada, Shigeki Kuwata, Yasushi Mizobe, and Masanobu Hidai pp 5793 - 5797; DOI: 10.1021/ic980133+ |
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Synthesis and Axial Ligand Substitution Chemistry of Ru(TTP)(NO)X. Structures of Ru(TTP)(NO)X (X = ONO, OH) D. Scott Bohle, Chen-Hsiung Hung, and Bryan D. Smith pp 5798 - 5806; DOI: 10.1021/ic980182m |
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Concerning the Resistivity Anomaly in the Layered Pnictide Oxide Na2Ti2Sb2O Fabrizia Fabrizi de Biani, Pere Alemany, and Enric Canadell pp 5807 - 5810; DOI: 10.1021/ic980712e |
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Characterization and Crystal Structure of Nickel Complexes of Imine Oximes Containing Tautomerized Enolate Ligands James D. Martin, Khalil A. Abboud, and Klaus-Hermann Dahmen pp 5811 - 5815; DOI: 10.1021/ic980415+ |
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Variation in Charge-Transfer Photochemistry Clarified by a CASSCF/MR-CCI Comparative Study of the Low-Lying Excited States of M(R)(CO)3(H-DAB) (M = Mn, R = H, Methyl, Ethyl; M = Re, R = H; DAB = 1,4-Diaza-1,3-butadiene) D. Guillaumont, M. P. Wilms, C. Daniel, and D. J. Stufkens pp 5816 - 5822; DOI: 10.1021/ic9802552 |
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Indium Tris(alkylthiolate) Compounds Seigi Suh and David M. Hoffman pp 5823 - 5826; DOI: 10.1021/ic980671m |
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Two New Binary Calcium-Aluminum Compounds: Ca13Al14, with a Novel Two-Dimensional Aluminum Network, and Ca8Al3, an Fe3Al-Type Analogue Baoquan Huang and John D. Corbett pp 5827 - 5833; DOI: 10.1021/ic980656h |
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Topological Analysis of the Electron Density Distribution in the Crystal of 8,9,10,12-Tetrafluoro-o-carborane on the Basis of the High-Resolution X-ray Diffraction Data at 120 K Konstantin A. Lyssenko, Mikhail Yu. Antipin, and Viatcheslav N. Lebedev pp 5834 - 5843; DOI: 10.1021/ic9807644 |
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Syntheses, Structures, and Magnetic Properties of Metal(II) Phosphates with M(OH)(PO4)2- Layers (M = Ni, Co, Mg) Nobuaki Hamanaka and Hideo Imoto pp 5844 - 5850; DOI: 10.1021/ic980595n |
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Coordination Chemistry of a Tripodal S2ON Ligand: Syntheses, Structures, and Reactivity of the Molybdenum(VI) and Nickel(II) Complexes of Bis(2-mercaptoethyl)-2-amino-4-methylphenol (H3btap) and Comparison to VVO(btap) Charles R. Cornman, Kevin L. Jantzi, Joseph I. Wirgau, Thad C. Stauffer, Jeff W. Kampf, and Paul D. Boyle pp 5851 - 5855; DOI: 10.1021/ic9802956 |
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Controlled Stoichiometric Incorporation of Ti(IV) into a Zr(IV) Pinacolate Cecilia A. Zechmann, John C. Huffman, Kirsten Folting, and Kenneth G. Caulton pp 5856 - 5861; DOI: 10.1021/ic980714z |
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Mixed Chloride/Amine Complexes of Dimolybdenum(II). 1. Preparation, Characterization, and Crystal Structure of Mo2Cl4(NHEt2)4: A Quadruply-Bonded Dimolybdenum Compound with Diethylamine Ligands F. Albert Cotton, Evgeny V. Dikarev, and Santiago Herrero pp 5862 - 5868; DOI: 10.1021/ic980702d |
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Synthesis and Characterization of Three New Layered Phosphates, Na2MnP2O7, NaCsMnP2O7, and NaCsMn0.35Cu0.65P2O7 Qun Huang and Shiou-Jyh Hwu pp 5869 - 5874; DOI: 10.1021/ic980616d |
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Chelate-Ring-Dependent Shifts in Redox Isomerism for the Co(Me2N(CH2)nNMe2)(3,6-DBQ)2 (n = 1-3) Series, Where 3,6-DBQ Is the Semiquinonate or Catecholate Ligand Derived from 3,6-Di-tert-butyl-1,2-benzoquinone Ok-Sang Jung, Du Hwan Jo, Young-A Lee, Youn Soo Sohn, and Cortlandt G. Pierpont pp 5875 - 5880; DOI: 10.1021/ic9805372 |
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Na12K38Tl48Au2: A Metallic Zintl Phase with Naked Icosahedral Fragments Tl77- and Tl99- Plus Au- DaPing Huang, Zhen-Chao Dong, and John D. Corbett pp 5881 - 5886; DOI: 10.1021/ic9808293 |
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A Molecular Mechanics (MM3(96)) Force Field for Metal-Amide Complexes Benjamin P. Hay, Omoshile Clement, Giovanni Sandrone, and David A. Dixon pp 5887 - 5894; DOI: 10.1021/ic980641j |
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The Structures of [24-Pyrimidinium crown-6][Au(CN)2]4(NO3)2·2H2O, [24-Pyrimidinium crown-6][Au(CN)2]6·5H2O, and [16-Pyrimidinium crown-4][Au(CN)2]4·6.5 H2O, in Which Aurophilic Interactions Produce Trimers, Tetramers, and Chains of Au(CN)2- Ions Roger E. Cramer, David W. Smith, and William VanDoorne pp 5895 - 5901; DOI: 10.1021/ic980372x |
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The Gallium(III) and Indium(III) Complexes of Tris(2-mercaptobenzyl)amine and Tris(2-hydroxybenzyl)amine Ramunas J. Motekaitis, Arthur E. Martell, Stephen A. Koch, JungWon Hwang, Duncan A. Quarless, Jr., and Michael J. Welch pp 5902 - 5911; DOI: 10.1021/ic980227j |
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Metal Coordinated HF-A Unique Case Z. Mazej, H. Borrmann, K. Lutar, and B. emvapp 5912 - 5914; DOI: 10.1021/ic980716j |
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Mechanism of Complex Formation of Ruthenium(II) Aquacomplexes with H2C=CH2, MeCN, Me2SO, and CO: Metal-Water Bond Rupture as Rate-Determining Step Nicolas Aebischer, Raphaël Churlaud, Lilian Dolci, Urban Frey, and André E. Merbach pp 5915 - 5924; DOI: 10.1021/ic980628z |
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Modulation of Electronic Coupling across Dioxolene-Bridged Osmium and Ruthenium Dinuclear Complexes Tia E. Keyes, Robert J. Forster, Pradeep M. Jayaweera, Colin G. Coates, John J. McGarvey, and Johannes G. Vos pp 5925 - 5932; DOI: 10.1021/ic980293l |
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Photoinduced Charge Separation through a Negatively Charged Bridge Stefano Fanni, Tia E. Keyes, Sebastiano Campagna, and Johannes G. Vos pp 5933 - 5935; DOI: 10.1021/ic980347r |
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Vibronic Averaging Effect in ESEEM Spectra of (NH4)2Mg(SO4)2·6H2O Single Crystal Doped with Jahn-Teller Active Cu(H2O)6 Complexes Janina Goslar, Wojciech Hilczer, and Stanis aw K. Hoffmannpp 5936 - 5937; DOI: 10.1021/ic9805675 |
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Relationship of Hydride Fluxionality in Ir(H)2L(phosphine)2n+ to Properties of L: An Exceptional Range of Barrier Heights Alan C. Cooper and Kenneth G. Caulton pp 5938 - 5940; DOI: 10.1021/ic971625+ |
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Polymeric Helical Motifs from the Self-Assembly of Silver Salts and Pyridazine Lucia Carlucci, Gianfranco Ciani, Davide M. Proserpio, and Angelo Sironi pp 5941 - 5943; DOI: 10.1021/ic9805022 |
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Intramolecular Interactions Leading to Quasicubane Cages. Crystal Structure of [Mo2(NO)2(CO)4{-2;1-S2C(H)PCy3}2] Daniel Miguel, Víctor Riera, Mei Wang, Claudette Bois, and Sabine Halut pp 5944 - 5947; DOI: 10.1021/ic9713590 |
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Kinetics of 2-Halopyridine Substitution at Pentaammineaquaruthenium(II) Michael H. Schmidt, Grady Horton, and Ilan Tong pp 5948 - 5951; DOI: 10.1021/ic980584u |
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An X-ray Absorption Spectroscopic Structural Investigation of the Nickel Site in Escherichia coli NikA Protein Christian B. Allan, Long-Fei Wu, Zhijie Gu, Suranjan B. Choudhury, Faizah Al-Mjeni, Manju L. Sharma, Marie-Andrée Mandrand-Berthelot, and Michael J. Maroney pp 5952 - 5955; DOI: 10.1021/ic980407t |
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Synthesis and Crystal Structures of Magnesium and Calcium Triazenide Complexes Stacy Westhusin, Peter Gantzel, and Patrick J. Walsh pp 5956 - 5959; DOI: 10.1021/ic980580p |
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A Polymeric Binary Titanium(IV) Sulfide and Its Conversion to Molecular Lewis Base Adducts Atul K. Verma, Jun-Hong Chou, and Thomas B. Rauchfuss pp 5960 - 5963; DOI: 10.1021/ic980568x |
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Quantitative Photochemistry of (5-C5H5)Fe(CO)2I in Solution: Effective Heterolytic Fe-I Dissociation upon Long-Wavelength Excitation Charlene E. Borja, Vladimír Jakúbek, and Alistair J.Lees pp 5964 - 5964; DOI: 10.1021/ic9811401 |
Issue 23
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Buckled-layered Structure of Zinc Dicyanamide, ZnII[N(CN)2]2 Jamie L. Manson, Do W. Lee, Arnold L. Rheingold, and Joel S. Miller pp 5966 - 5967; DOI: 10.1021/ic980659u |
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Isolation and Structure of the First Azo Anion Radical Complexes of Ruthenium Maya Shivakumar, Kausikisankar Pramanik, Prasanta Ghosh, and Animesh Chakravorty pp 5968 - 5969; DOI: 10.1021/ic980719w |
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Titanium Imido Complexes with Tetradentate Schiff Base Ligands Jacqueline M. McInnes, Daniel Swallow, Alexander J. Blake, and Philip Mountford pp 5970 - 5977; DOI: 10.1021/ic9806986 |
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Synthesis, Structure, and Magnetic Properties of Mn(salpn)N3, a Helical Polymer, and Fe(salpn)N3, a Ferromagnetically Coupled Dimer (salpnH2 = N,N'-bis(Salicylidene)-1,3-diaminopropane) K. Rajender Reddy, M. V. Rajasekharan, and J.-P. Tuchagues pp 5978 - 5982; DOI: 10.1021/ic971592y |
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Single-Crystal EPR and X-Ray Studies of Magnetic Exchange Interactions and the Molecular Structure of Dipropylenetriamineethylenediaminecopper(II) Perchlorate, [Cu(dpt)(en)](ClO4)2 Murugesan Velayutham, Babu Varghese, and Sankaran Subramanian pp 5983 - 5991; DOI: 10.1021/ic980071n |
Synthesis and Characterization of a Stable trans-Dioxo Tungsten(IV) Complex and Series of Mono-Oxo Molybdenum(IV) and Tungsten(IV) Complexes. Structural and Electronic Effects of  -Bonding in trans-[M(O)(X)(dppe)2]+/0 SystemsJesper Bendix and Anders B gevigpp 5992 - 6001; DOI: 10.1021/ic980342u |
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Theoretical Evidence for Transannular Metal-Metal Interactions in Dinuclear Coinage Metal Complexes Eduardo J. Fernández, José M. López-de-Luzuriaga, Miguel Monge, Miguel A. Rodríguez, Olga Crespo, M. Concepción Gimeno, Antonio Laguna, and Peter G. Jones pp 6002 - 6006; DOI: 10.1021/ic980786q |
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Synthesis and Structure of PdII Complexes Containing the C,C-Chelating Bis-Ylide Ligand [Ph3P=C(H)]2CO. X-ray Crystal Structure of {Pd(-Cl){[C(H)PPh3]2CO}}2(ClO4)2·CH2Cl2 Larry R. Falvello, Susana Fernández, Rafael Navarro, Angel Rueda, and Esteban P. Urriolabeitia pp 6007 - 6013; DOI: 10.1021/ic980392z |
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Infrared Study of H10Si10O15 Chemisorbed on a Si(100)-2×1 Surface J. N. Greeley and M. M. Banaszak Holl pp 6014 - 6017; DOI: 10.1021/ic9803457 |
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Synthesis of an o-Carboranyl Derivative of 4-[5-(4-Methyl-1-piperazinyl)-2,5'-bi-1H-benzimidazol-2'-yl]phenol Mario Argentini, Deborah F. Dos Santos, Regin Weinreich, and Hans-Jürgen Hansen pp 6018 - 6022; DOI: 10.1021/ic980505e |
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Syntheses, Crystal Structures, Spectroscopic Characterization, and Electrochemical Studies of the Ditungsten(III) Complexes Cl3W(-L)3WCl3 and [Cl3W(-L)2(-Cl)WCl3]- (L = 1,4-Dithiane, 1,4-Thioxane, pms = Pentamethylene Sulfide). C-S Bond Cleavage of the Bridging Thioether(s) in Cl3W(-L)3WCl3 P. Michael Boorman, Naomi L. Langdon, Vivian J. Mozol, Masood Parvez, and Glenn P. A. Yap pp 6023 - 6029; DOI: 10.1021/ic971542t |
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207Pb NMR of Solid Solutions of Divalent Metal Nitrates Young-Sik Kye and Gerard S. Harbison pp 6030 - 6031; DOI: 10.1021/ic9805527 |
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The Crystal Structure and Raman Spectrum of Ge5Cl12·GeCl4 and the Vibrational Spectrum of Ge2Cl6 Ian R. Beattie, Peter J. Jones, Gillian Reid, and Michael Webster pp 6032 - 6034; DOI: 10.1021/ic9807341 |
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Mixed Chloride/Phosphine Complexes of the Dirhenium Core. 3. Novel Structures with Diethylphosphido-bridges and Terminal Diethylphosphines F. Albert Cotton, Evgeny V. Dikarev, and Marina A. Petrukhina pp 6035 - 6043; DOI: 10.1021/ic980701l |
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The Intra- and Intermolecular Oxidative Coupling of Ni(II)-meso-Octaethyl Mono(pyridine)-Tris(pyrrole) Complex Leading to C-C Bonds: Pathways to Oligomeric Porphyrinogens Raffaella Crescenzi, Euro Solari, Carlo Floriani, Angiola Chiesi-Villa, and Corrado Rizzoli pp 6044 - 6051; DOI: 10.1021/ic9806378 |
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Manganese Porphyrin Heterodimers and -trimers in Aqueous Solution Laurent Ruhlmann, Asao Nakamura, Johannes G. Vos, and Jürgen-Hinrich Fuhrhop pp 6052 - 6059; DOI: 10.1021/ic980241w |
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Synthesis of a Metallaborane Complex Containing Pd(III) and the First Doubly Charge Compensated Ollide Ion. X-ray Crystal Structure of 1,4-Br2-1,2,5-(PMe2Ph)3-closo-1-PdB11H8 Steve A. Jasper, Jr., John C. Huffman, and Lee J. Todd pp 6060 - 6064; DOI: 10.1021/ic980681n |
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Dinuclear and Hexanuclear Iron(III) Oxide Complexes with a Bis(bipyridine) Ligand: A New [Fe6(3-O)4]10+ Core Craig M. Grant, Michael J. Knapp, William E. Streib, John C. Huffman, David N. Hendrickson, and George Christou pp 6065 - 6070; DOI: 10.1021/ic980686k |
15R SrMn1-xFexO3- (x  0.1); A New Perovskite Stacking SequenceEdmund J. Cussen, Jeremy Sloan, Jaap F. Vente, Peter D. Battle, and Terence C. Gibb pp 6071 - 6077; DOI: 10.1021/ic980802j |
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Multitemperature Resonance-Diffraction and Structural Study of the Mixed-Valence Complex [Fe3O(OOCC(CH3)3)6(C5H5N)3] Guang Wu, Yuegang Zhang, Lynn Ribaud, Philip Coppens, Claire Wilson, Bo B. Iversen, and Finn Krebs Larsen pp 6078 - 6083; DOI: 10.1021/ic980556b |
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Design of Long-Lived Ru(II) Terpyridine MLCT States. Tricyano Terpyridine Complexes Maria Teresa Indelli, Carlo Alberto Bignozzi, Franco Scandola, and Jean-Paul Collin pp 6084 - 6089; DOI: 10.1021/ic980060u |
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Synthesis of the New Polydentate Phosphine Ligand 1-[(Diphenylphosphino)methyl]-4- (2-pyridyl)piperazine and Structural Characterization of Its Binuclear Silver(I) and Mononuclear Iron(0) Complexes Shan-Ming Kuang, Zheng-Zhi Zhang, Qi-Guang Wang, and Thomas C. W. Mak pp 6090 - 6092; DOI: 10.1021/ic9800482 |
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Reaction of -Diketones with P4S10 To Produce Novel Alkyl-Phosphorus-Sulfur Clusters Scott Flanagan, Henry A. Luten, and William S. Rees, Jr. pp 6093 - 6095; DOI: 10.1021/ic9709234 |
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Synthesis, Characterization, and Electronic Structure Analysis of (Et4N)4KAuAs4Te8 and Electron Counting for the Zintl Anion Containing a Square-Planar AuTe4 Unit Chwanchin Wang, Robert C. Haushalter, and Myung-Hwan Whangbo pp 6096 - 6099; DOI: 10.1021/ic980389f |
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Synthesis and Characterization of Low-Spin Bis(amino ester) Iron(III) Porphyrin Complexes Christophe Morice, Paul Le Maux, and Gérard Simonneaux pp 6100 - 6103; DOI: 10.1021/ic980473v |
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Six-Coordinate Thallium(III) Porphyrin Triflate: Synthesis, Physiochemical Characteristics, and X-ray Crystal Structure of (Trifluoromethanesulfonato)(tetrahydrofuran)(meso-tetraphenylporphyrinato)thallium(III) Tetrahydrofuran Solvate, [Tl(tpp)(OSO2CF3)(THF)·THF] Jo-Yu Tung, Jyh-Horung Chen, Feng-Ling Liao, Sue-Lein Wang, and Lian-Pin Hwang pp 6104 - 6108; DOI: 10.1021/ic9803199 |
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Reaction of Tetrahydroxo(2,2-dimethylpropane- diamine)platinum(IV) with Trimethylsilylchoride. Pentacoordinative Si···OH Interaction Labilizing the PtIV-OH Bond Kwan Mook Kim and Youn Soo Sohn pp 6109 - 6112; DOI: 10.1021/ic980203c |
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Unusual Coordination Mode of Thiosemicarbazone Ligand. Synthesis, Structure, and Redox Properties of Some Ruthenium and Osmium Complexes Falguni Basuli, Michael Ruf, Cortlandt G. Pierpont, and Samaresh Bhattacharya pp 6113 - 6116; DOI: 10.1021/ic980424i |
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Synthesis and Structure of a Polymeric Complex of Tl(III) Containing Bis(semiquinone) Bridging Ligands Gleb A. Abakumov, Vladimir K. Cherkasov, Vladimir I. Nevodchikov, Vyacheslav A. Kuropatov, Bruce C. Noll, and Cortlandt G. Pierpont pp 6117 - 6119; DOI: 10.1021/ic980364g |
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Photocatalyzed Oxidation of SO32- by Co(dimeth- ylglyoximato)(SO3)23- and Its {Co(dimethylglyox- imato)(SO3)23-, Cu(2,6-Me2pyo[14]-1,4,6-triene- 1,4,7,11,N4)2+} Adduct S. C. Gibney and G. Ferraudi pp 6120 - 6124; DOI: 10.1021/ic9803816 |
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Bis(triphenylphosphine)copper(I) Complexes of Orotate and L-Dihydroorotate Donald J. Darensbourg, David L. Larkins, and Joseph H. Reibenspies pp 6125 - 6128; DOI: 10.1021/ic980464m |
Issue 24
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Mechanistic Information from the First Volume Profile Analysis for Intramolecular Electron-Transfer Reactions: Tetraammine-Ruthenium(Ligand) Complexes of Cytochrome c Ji Sun, Chang Su, Martin Meier, Stephan S. Isied, James F. Wishart, and Rudi van Eldik pp 6129 - 6135; DOI: 10.1021/ic980999f |
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1,3,5-Triamino-1,3,5-trideoxy-cis-inositol and all-cis-2,4,6-Trimethoxycyclohexane- 1,3,5-triamine as Building Blocks for New Multidentate and Macrocyclic Ligands Kaspar Hegetschweiler, Michael Weber, Volker Huch, Rodney J. Geue, A. David Rae, Anthony C. Willis, and Alan M. Sargeson pp 6136 - 6146; DOI: 10.1021/ic980483w |
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Comparative Crystal Structure Studies on Distortion of iso-Butyl(aqua)cobaloxime Induced by -Cyclodextrin and -Cyclodextrin Hosts Lai-Bin Luo, Ying Chen, Hui-Lan Chen, Ze-Ying Zhang, Zhong-Yuan Zhou, and Thomas C. W. Mak pp 6147 - 6152; DOI: 10.1021/ic980378m |
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Speciation in Vanadium Bioinorganic Systems. 5. Interactions between Vanadate, Uridine, and Imidazole-An Aqueous Potentiometric, 51V, 17O, and 13C NMR Study Katarina Elvingson, Anastasios D. Keramidas, Debbie C. Crans, and Lage Pettersson pp 6153 - 6160; DOI: 10.1021/ic9712333 |
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Comparison of Hole-Transfer Superexchange in Dinuclear Mixed-Valence Ruthenium Complexes Christopher E. B. Evans, Glenn P. A. Yap, and Robert J. Crutchley pp 6161 - 6167; DOI: 10.1021/ic980576d |
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Physicochemical Characterization of -Bonded Aryl Iron(III) Porphycenes. X-ray Structures of (EtioPc)Fe(3,5-C6F2H3) and (EtioPc)In(C6H5), Where EtioPc Is the Dianion of 2,7,12,17-Tetraethyl-3,6,13,16-tetramethylporphycene Karl M. Kadish, Alain Tabard, Eric Van Caemelbecke, Ally M. Aukauloo, Philippe Richard, and Roger Guilard pp 6168 - 6175; DOI: 10.1021/ic980610o |
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Two-Electron Reduction of [{(bpy)2Ru(dmbbbpy)}3Ru]8+ from (BNA)2 via Photoinduced Electron Transfer [dmbbbpy = 2,2'-Bis(N-methylbenzimidazole-2-yl)-4,4'-bipyridine] Md. Meser Ali, Hiroyasu Sato, Masa-aki Haga, Koji Tanaka, Akio Yoshimura, and Takeshi Ohno pp 6176 - 6180; DOI: 10.1021/ic980586e |
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The Missing Link: Synthesis, Crystal Structure, and Thermogravimetric Studies of InPO4·H2O Xuejiao Tang and Abdessadek Lachgar pp 6181 - 6185; DOI: 10.1021/ic980548v |
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Synthesis, Structures, and Magnetic Properties of Carboxylate-Bridged Tetranuclear Copper(II)-Lanthanoid(III) Complexes [Cu2Ln2(betaine)10(H2O)8](ClO4)10·2H2O and [Cu2Ln2(betaine)12(ClO4)2](ClO4)8 Xiao-Ming Chen, Yu-Luan Wu, Yang-Yi Yang, Sheila M. J. Aubin, and David N. Hendrickson pp 6186 - 6191; DOI: 10.1021/ic980525g |
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Cycloalkylaminocyclo- and Polyphosphazenes: X-ray Crystal Structures of gem-Tetrakis(cyclohexylamino)dichlorocyclotriphosphazene and Octakis(cyclopropylamino)cyclotetraphosphazene V. Chandrasekhar, K. Vivekanandan, S. Nagendran, G. T. Senthil Andavan, N. R.Weathers, J. C. Yarbrough, and A. W. Cordes pp 6192 - 6198; DOI: 10.1021/ic980520j |
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Detailed Structural and Theoretical Studies of the Bonding in Edge-Bridged Halide and Oxyhalide Octahedral Niobium and Tantalum Clusters François Ogliaro, Stéphane Cordier, Jean-François Halet, Christiane Perrin, Jean-Yves Saillard, and Marcel Sergent pp 6199 - 6207; DOI: 10.1021/ic980328h |
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IR and UV Absorption Cross Sections, Vibrational Analysis, and the Molecular Structure of Trifluoromethyl Peroxynitrate, CF3OONO2 Rodion Kopitzky, Helge Willner, Hans-Georg Mack, Angelika Pfeiffer, and Heinz Oberhammer pp 6208 - 6213; DOI: 10.1021/ic980776p |
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Mechanisms of Ligand Substitution Reactions in Ternary Dioxouranium(VI) Complexes Zoltán Szabó and Ingmar Grenthe pp 6214 - 6221; DOI: 10.1021/ic9804364 |
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Reactions of N-Methylated Amino Acids and Benzylammonium Ions with P73- and As73-: Unusual Stereospecific Alkyl Group Transfers in the Synthesis of R2P7- and R2As7- Ions Sundeep P. Mattamana, Kumpeeh Promprai, James C. Fettinger, and Bryan W. Eichhorn pp 6222 - 6228; DOI: 10.1021/ic9804770 |
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Pr4Mo9O18, an Atypical, Novel, Ternary Reduced Molybdenum Oxide Containing Unusual Mo7, Mo13, and Mo19 Clusters. Synthesis, Crystal Structure, and Physical Properties J. Tortelier and P. Gougeon pp 6229 - 6236; DOI: 10.1021/ic980500h |
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Mono(pentamethylcyclopentadienyl)titanium and -zirconium Complexes Supported by Chiral Diolate Ligands. X-ray Crystal Structures of [(-C5Me5)TiCl(-1,1-2-CF3-dpbd)]2 and [HNEt3][(-C5Me5)2Zr2Cl2(-Cl)(-1,2-3,5-Me2-dpbd)2] David L. Clark, Damon R. Click, Steven K. Grumbine, Brian L. Scott, and John G. Watkin pp 6237 - 6243; DOI: 10.1021/ic980645o |
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Metal-to-Ligand Charge Transfer Photochemistry: Homolysis of the Mn-Cl Bond in the mer-Mn(Cl)(CO)3(-diimine) Complex and Its Absence in the fac-Isomer Angela Rosa, Giampaolo Ricciardi, Evert Jan Baerends, and Derk J. Stufkens pp 6244 - 6254; DOI: 10.1021/ic980757f |
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Solid State and Solution Characterization of Chiral, Conformationally Mobile Tripodal Ligands James W. Canary, Craig S. Allen, Jesus M. Castagnetto, Yu-Hung Chiu, Paul J. Toscano, and Yihan Wang pp 6255 - 6262; DOI: 10.1021/ic9803098 |
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Characterization of the Solid-Solid Phase Transition of Co2(CO)6(AsPh3)2 Piero Macchi, Luigi Garlaschelli, Secondo Martinengo, and Angelo Sironi pp 6263 - 6268; DOI: 10.1021/ic9807240 |
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Steric Aspects of the Binding of Monofunctional Platinum(II) Complexes to Sites on Nucleobases: Metal Complex "Flatness" as a Structural Element of Speciation Elizabeth Yuriev and John D. Orbell pp 6269 - 6275; DOI: 10.1021/ic980729x |
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Comparative Thermochemistry of Metalloporphyrin Isomers as a Function of Metal Ion Size. A Possible Insight into Nature's Choice of Porphyrin over Isomeric Ligands Abhik Ghosh and Torgil Vangberg pp 6276 - 6280; DOI: 10.1021/ic9807994 |
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Dinuclear Nickel(II) Complexes of an Unsymmetric "End-Off" Compartmental Ligand: Conversion of Urea into Cyanate at a Dinuclear Nickel Core Syunsuke Uozumi, Hideki Furutachi, Masaaki Ohba, Hisashi kawa, David E. Fenton, Kenji Shindo, Susumu Murata, and David J. Kitkopp 6281 - 6287; DOI: 10.1021/ic9807689 |
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[MPy]+ and [MxPy]- Clusters Generated by Laser Ablation and Investigated by Fourier Transform Ion Cyclotron Resonance Mass Spectrometry P. F. Greenwood, I. G. Dance, K. J. Fisher, and G. D. Willett pp 6288 - 6294; DOI: 10.1021/ic980699y |
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Synthesis of Poly- and the First Perfluoroalkyl-N(SO2F)2 Derivatives: Improved Methods for the Preparation of XN(SO2F)2 (X = H, Cl) and Single-Crystal Diffraction Studies of HN(SO2Cl)2, HN(SO2F)2, and CF3CH2N(SO2F)2 Burkhard Krumm, Ashwani Vij, Robert L. Kirchmeier, and Jean'ne M. Shreeve pp 6295 - 6303; DOI: 10.1021/ic9800031 |
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Layered Zincophosphate Materials Prepared from a Molecular Zinc Di(tert-butyl)phosphate Complex in Organic Solvents Claus G. Lugmair and T. Don Tilley pp 6304 - 6307; DOI: 10.1021/ic980501+ |
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Low Temperature Solid-State Reactions of (NH4)2[MS4] (M = W, Mo) with [Cu(CH3CN)4](PF6) and CuBr in the Presence of Bis(diphenylphosphino)methane (dppm): Crystal Structures of [MS4Cu4(dppm)4](PF6)2 (M = W, Mo), [WS4Cu3(dppm)3]X (X = PF6, Br), [Cu3(dppm)3Br2]Br, [WS4Cu2(dppm)3], and [(n-Bu)4N][WS4Cu3Br2(dppm)2] Jian-Ping Lang and Kazuyuki Tatsumi pp 6308 - 6316; DOI: 10.1021/ic980566c |
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Experimental Charge Density and Neutron Structural Study of cis-HMn(CO)4PPh3: Comprehensive Analysis of Chemical Bonding and Evidence for a C-H···H-Mn Hydrogen Bond Yuriy A. Abramov, Lee Brammer, Wim T. Klooster, and R. Morris Bullock pp 6317 - 6328; DOI: 10.1021/ic9809660 |
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Structural Displacement of Phosphites, Phosphates, and Pentaoxyphosphoranes to Higher Coordinate Geometries by Sulfur and Oxygen Donor Action Paul Sood, A. Chandrasekaran, Roberta O. Day, and Robert R. Holmes pp 6329 - 6336; DOI: 10.1021/ic9804418 |
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Iron-Mediated Cleavage of Coordinated 1,1,1,5,5,5-Hexafluoropentane-2,4-dione by the 2,2,6,6-Tetramethylpiperidine-1-oxyl Nitroxyl Radical Caroline Ahlers and Michael H. Dickman pp 6337 - 6340; DOI: 10.1021/ic980489l |
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Intermetallic Frameworks: Synthesis, Characterization, and Bonding of K0.4Cd2 and Na26Cd141 Evgeny Todorov and Slavi C. Sevov pp 6341 - 6345; DOI: 10.1021/ic980777h |
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Magnetic Interactions in Dimeric Transition Metal Complexes: Basic erythro-Chromium(III) Sonia Flores and D. E. Ellis pp 6346 - 6353; DOI: 10.1021/ic981049x |
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Structures and Spectroscopic Properties of Chain Polymeric Complexes of Copper(II) Halides with 2,3,5,6-Tetrafluoro-1,4-bis(2-pyridylsulfenyl)benzene and Its 4-Pyridylsulfenyl Analogue David M. L. Goodgame, David A. Grachvogel, Michael A. Hitchman, Nicholas J. Long, Horst Stratemeier, Andrew J. P. White, Joseph L. M. Wicks, and David J. Williams pp 6354 - 6360; DOI: 10.1021/ic980479k |
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Synthesis and Molecular Structure of 12-Iodo-1-(4-pentylquinuclidin-1-yl)-1-carba-closo-dodecaborane Andrew G. Douglass, Zbynek Janousek, Piotr Kaszynski, and Victor G. Young, Jr. pp 6361 - 6365; DOI: 10.1021/ic980775x |
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Synthesis and Characterization of Group 4 Amido Silyl Complexes Free of Anionic -Ligands Zhongzhi Wu, Jonathan B. Diminnie, and Ziling Xue pp 6366 - 6372; DOI: 10.1021/ic980821t |
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Charge-Transfer Band Splittings in Electronic Spectra of Mixed Ligand Halogeno Osmium(IV) Complexes Hans-Herbert Schmidtke and Nicolai Lehnert pp 6373 - 6381; DOI: 10.1021/ic980168+ |
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N- versus S-Metalation of Nitridobis(3,4-toluenedithiolato)osmium(VI) Wa-Hung Leung, Joyce L. C. Chim, and Wing-Tak Wong pp 6382 - 6384; DOI: 10.1021/ic980136m |
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Stepwise Formation of a Nonsymmetric Dinuclear Copper Complex of Ochratoxin A Ivan G. Gillman, Cynthia S. Day, and Richard A. Manderville pp 6385 - 6388; DOI: 10.1021/ic980274b |
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Oxovanadium(IV)-Promoted Peptide-Amide Deprotonation in Aqueous Solution T. Kiss, K. Petrohán, P. Buglyó, D. Sanna, G. Micera, J. Costa Pessoa, and C. Madeira pp 6389 - 6391; DOI: 10.1021/ic9802202 |
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Influence of Na+ on the Stoichiometry of Carbonated Hydroxyapatite Obtained by the Hydrolysis of Octacalcium Phosphate Ilse Y. Pieters, Erna A. P. De Maeyer, and Ronald M. H. Verbeeck pp 6392 - 6395; DOI: 10.1021/ic9802810 |
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Synthesis and Characterization of the Five-Coordinate Sixteen-Electron Manganese(I) Complex [Mn(CO)3(S-C6H4-NH)]- Wen-Feng Liaw, Chien-Ming Lee, Gene-Hsiang Lee, and Shie-Ming Peng pp 6396 - 6398; DOI: 10.1021/ic9809153 |
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A Palladium Complex Promoted Asymmetric Synthesis of a Novel P-Chiral Diphosphine Containing an Ester Functional Group Yongcheng Song, K. F. Mok, Pak-Hing Leung, and Soh-Ha Chan pp 6399 - 6401; DOI: 10.1021/ic980943l |
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Theoretical Study of Transition Metal Compounds with Molybdenum- and Tungsten-Phosphorus Triple Bonds Thomas Wegener and Gernot Frenking pp 6402 - 6402; DOI: 10.1021/ic981203f |
Issue 25
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Sodium Salt of a Cyclic Aluminophosphonate: Model Compound for the Six-Ring Secondary Building Units of Molecular Sieves Yu Yang, Jiri Pinkas, Mathias Noltemeyer, and Herbert W. Roesky pp 6404 - 6405; DOI: 10.1021/ic980720v |
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Remote Control of NO Reactivity through Redox Switching in Dinuclear Cyano-Bridged Complexes Paula Forlano, Alejandro R. Parise, and José A. Olabe pp 6406 - 6407; DOI: 10.1021/ic981024y |
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PH-Functional Phosphines with 1,1'-Biphenyl-2,2'-bis(methylene) and 1,1'-Binaphthyl-2,2'-bis(methylene) Backbones Frank Bitterer, Oliver Herd, Michael Kühnel, Othmar Stelzer, Norbert Weferling, William S. Sheldrick, Jutta Hahn, Sabine Nagel, and Notker Rösch pp 6408 - 6417; DOI: 10.1021/ic980346z |
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Copper(II) Complexes with Unusual Axial Phenolate Coordination as Structural Models for the Active Site in Galactose Oxidase: X-ray Crystal Structures and Spectral and Redox Properties of [Cu(bpnp)X] Complexes Mathrubootham Vaidyanathan, Rathinam Viswanathan, Mallayan Palaniandavar, T. Balasubramanian, P. Prabhaharan, and Thomas P. Muthiah pp 6418 - 6427; DOI: 10.1021/ic971567s |
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Synthesis of Heterobimetallic Fe-M (M = Ni, Pd, Pt) Complexes Containing the 1,1'-Ferrocenedithiolato Ligand and Their Conversion to Trinuclear Complexes Shin Takemoto, Shigeki Kuwata, Yoshiaki Nishibayashi, and Masanobu Hidai pp 6428 - 6434; DOI: 10.1021/ic9806129 |
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Peripheral Palladium(II) and Platinum(II) Complexes of Bis(dimethylamino)porphyrazine Steven J. Lange, Hanlin Nie, Charlotte L. Stern, Anthony G. M. Barrett, and Brian M. Hoffman pp 6435 - 6443; DOI: 10.1021/ic980791u |
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Highly Chlorinated, Brominated, and Iodinated Icosahedral Carborane Anions: 1-H-CB11X11-, 1-CH3-CB11X11- (X = Cl, Br, I); 1-Br-CB11Br11- Zuowei Xie, Chi-Wing Tsang, Eric Tung-Po Sze, Qingchuan Yang, Dominic T. W. Chan, and Thomas C. W. Mak pp 6444 - 6451; DOI: 10.1021/ic9805628 |
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Ion-Pair Charge-Transfer Complexes Based on (o-Phenylenebis(oxamato))cuprate(II) and Cyclic Diquaternary Cations of 1,10-Phenanthroline and 2,2'-Bipyridine: Synthesis, Crystal Structure, and Physical Properties Iosu Unamuno, Juan M. Gutiérrez-Zorrilla, Antonio Luque, Pascual Román, Luis Lezama, Rafael Calvo, and Teófilo Rojo pp 6452 - 6460; DOI: 10.1021/ic9805224 |
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Active Role of a Germylene Ligand in Promoting Reactions of Platinum Complexes with Oxygen and Sulfur Dioxide K. E. Litz, M. M. Banaszak Holl, J. W. Kampf, and G. B. Carpenter pp 6461 - 6469; DOI: 10.1021/ic9808044 |
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Yttrium-Based Porous Materials Templated by Anionic Surfactant Assemblies Mitsunori Yada, Hirohumi Kitamura, Masato Machida, and Tsuyoshi Kijima pp 6470 - 6475; DOI: 10.1021/ic980147f |
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Water Oxidation by [(tpy)(H2O)2RuIIIORuIII(H2O)2(tpy)]4+ Estelle L. Lebeau, S. Ajao Adeyemi, and Thomas J. Meyer pp 6476 - 6484; DOI: 10.1021/ic970908z |
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Synthesis, Characterization, and Crystal Structure of Dicalcium Glutarylbis(phosphonate) Dihydrate: A Covalently Pillared Layer Structure with the Potential for Epitaxial Growth on Hydroxyapatite Mathai Mathew, Bruce O. Fowler, Eli Breuer, Gershon Golomb, Ivan S. Alferiev, and Naomi Eidelman pp 6485 - 6494; DOI: 10.1021/ic980374h |
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Composition Space Diagrams for Mixed Transition Metal Oxide Fluorides Alexander J. Norquist, Kevin R. Heier, Charlotte L. Stern, and Kenneth R. Poeppelmeier pp 6495 - 6501; DOI: 10.1021/ic9807238 |
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Application of the Spherical Harmonic Model to the Study of the Terminal (CO) Spectra of Transition Metal Carbonyl Clusters S. F. A. Kettle, E. Diana, R. Rossetti, and P. L. Stanghellini pp 6502 - 6510; DOI: 10.1021/ic9807339 |
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Iminoacylation. 1. Addition of Ketoximes or Aldoximes to Platinum(IV)-Bound Organonitriles Vadim Yu. Kukushkin, Tatyana B. Pakhomova, Yuri N. Kukushkin, Rudolf Herrmann, Gabriele Wagner, and Armando J. L. Pombeiro pp 6511 - 6517; DOI: 10.1021/ic9807745 |
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Syntheses and Properties of Homoleptic Carbonyl and Trifluorophosphane Niobates: [Nb(CO)6]-, [Nb(PF3)6]- and [Nb(CO)5]3 Mikhail V. Barybin, John E. Ellis, Marie K. Pomije, Mary L. Tinkham, and Garry F. Warnock pp 6518 - 6527; DOI: 10.1021/ic980752i |
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Synthesis and Characterization of [Ru(dpop')2](PF6)2. A Ruthenium(II) Complex with the Novel Mixed-Denticity Bridging Ligand Dipyrido(2,3-a:3',2'-j)phenazine (dpop') Ronald R. Ruminski, Sina Underwood, Kristen Vallely, and Sandra J. Smith pp 6528 - 6531; DOI: 10.1021/ic980530k |
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Characterization and Crystal Structure of a Chiral Ruffled Basket-Handle Porphyrin Philippe Richard, Eric Rose, and Bernard Boitrel pp 6532 - 6534; DOI: 10.1021/ic980499m |
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Copper-Mediated Oxygenation of Nitronate to Nitrite and Acetone in a Copper(I) Nitronate Complex Éva Balogh-Hergovich, Gábor Speier, Gottfried Huttner, and László Zsolnai pp 6535 - 6537; DOI: 10.1021/ic980246t |
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(Et4N)2[(Mo2O2Se6)0.20(Mo2O2Se7)0.18(Mo2O2Se8)0.62], a New Dimeric Molybdenum Polyselenide Containing a [Mo2O2(-Se)2] Core Guo-Cong Guo and Thomas C. W. Mak pp 6538 - 6540; DOI: 10.1021/ic9804824 |
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Synthesis and Structural Characterization of the Solvent-Free Potassium Derivative of a Terphenyl-Substituted Primary Phosphane: [(2,6-Dimesitylphenyl)P(H)K]4 Gerd W. Rabe, Sohrab Kheradmandan, and Glenn P. A. Yap pp 6541 - 6543; DOI: 10.1021/ic980585m |
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Proposed Boron Nanotubes Asta Gindulyt  , William N. Lipscomb, and Lou Massapp 6544 - 6545; DOI: 10.1021/ic980559o |
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Quantum Chemical Calculations of Proposed Multicage Boron Fullerenes Asta Gindulyt , Namby Krishnamachari, William N. Lipscomb, and Lou Massapp 6546 - 6548; DOI: 10.1021/ic980560n |
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Synthesis and X-ray Crystal Structure Determination of the First Transition Metal Complexes of the Tetracycles Formed by Tetraazamacrocycle-Glyoxal Condensation: PdL*Cl2 (L = Cyclam-Glyoxal Condensate (1), Cyclen-Glyoxal Condensate (2)) Timothy J. Hubin, James M. McCormick, Nathaniel W. Alcock, and Daryle H. Busch pp 6549 - 6551; DOI: 10.1021/ic9806380 |
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Triethylenetetramine-N, N, N,,N,,,N,,,,N,,,-hexaacetic Acid (TTHA) and TTHA-Bis(butanamide) as Chelating Agents Relevant to Radiopharmaceutical Applications Benbrahim Achour, Judite Costa, Rita Delgado, Emmanuelle Garrigues, Carlos F. G. C. Geraldes, Nikolaus Korber, Françoise Nepveu, and M. Isabel Prata pp 6552 - 6552; DOI: 10.1021/ic981268i |
Issue 26
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The First Synthesis and Structural Characterization of Alkylperoxo Complex of Manganese(II) Hidehito Komatsuzaki, Naoko Sakamoto, Minoru Satoh, Shiro Hikichi, Munetaka Akita, and Yoshihiko Moro-oka pp 6554 - 6555; DOI: 10.1021/ic980509j |
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The First Fused Dimer Metallacrown NiII2(mcpa)2(CH3OH)3(H2O)[12-MCNiIIN(shi)2(pko)2-4][12-MCNiIIN(shi)3(pko)-4] George Psomas, Catherine Dendrinou-Samara, Maria Alexiou, Alexandros Tsohos, Catherine P. Raptopoulou, Aris Terzis, and Dimitris P. Kessissoglou pp 6556 - 6557; DOI: 10.1021/ic980614t |
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Supermacrochelate Complexes Containing an Artificial Nucleic Acid Backbone and Derived from Excellent Ligands Formed by Treating Platinum Anticancer Agents with Nucleotide Triphosphates Anvarhusein A. Isab and Luigi G. Marzilli pp 6558 - 6559; DOI: 10.1021/ic980946y |
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Preparation, Structure and Stability of cis-{Cr(phen)2[OP(O)(OC6H5)2](H2O)}2+ as a Model for Cr(III)-DNA Adducts Alba D. Q. Ferreira, Avi Bino, and Dan Gibson pp 6560 - 6561; DOI: 10.1021/ic981095x |
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K2Ag3CeTe4: A Semiconducting Tunnel Framework Made from the Covalent "Link-Up" of [Ag2CeTe4]3- Layers with Ag Rhonda Patschke, Paul Brazis, Carl R. Kannewurf, and Mercouri Kanatzidis pp 6562 - 6563; DOI: 10.1021/ic981177l |
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Synthesis, Spectroscopic Properties, and Reactivities of Bis(tosylimido)osmium(VI) Porphyrin Complexes. X-ray Crystal Structure of [OsVI(TPP)(NSO2C6H4-pCH3)2] (TPP = Tetraphenylporphyrinato) Sze-Man Au, Wai-Hong Fung, Jie-Sheng Huang, Kung-Kai Cheung, and Chi-Ming Che pp 6564 - 6567; DOI: 10.1021/ic980256u |
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Calculation of Zero-Field Splittings, g-Values, and the Relativistic Nephelauxetic Effect in Transition Metal Complexes. Application to High-Spin Ferric Complexes Frank Neese and Edward I. Solomon pp 6568 - 6582; DOI: 10.1021/ic980948i |
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Preparation and Characterization of a Bis(silsesquioxane)tungsten Complex Peter Smet, Bart Devreese, Francis Verpoort, Tania Pauwels, Ingrid Svoboda, Sabine Foro, Jozef Van Beeumen, and Ludo Verdonck pp 6583 - 6586; DOI: 10.1021/ic980175y |
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Coordination Chemistry of N-Alkylbenzamide-2,3-dithiolates as an Approach to Poly(dithiolate) Ligands: 1,4-Bis[(2,3-dimercaptobenzamido)methyl]benzene and Its Chelate Complex with the (C5H5)Ti Fragment Wolfram W. Seidel, F. Ekkehardt Hahn, and Thomas Lügger pp 6587 - 6596; DOI: 10.1021/ic9706616 |
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Modeling Tyrosinase Monooxygenase Activity. Spectroscopic and Magnetic Investigations of Products Due to Reactions between Copper(I) Complexes of Xylyl-Based Dinucleating Ligands and Dioxygen: Aromatic Ring Hydroxylation and Irreversible Oxidation Products Debalina Ghosh and Rabindranath Mukherjee pp 6597 - 6605; DOI: 10.1021/ic9713689 |
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Synthesis and Characterization of Palladium(II) Complexes with New Polydentate Nitrogen Ligands. Dynamic Behavior Involving Pd-N Bond Rupture. X-ray Molecular Structure of [{Pd(3-C4H7)}2(Me-BPzTO)](4-MeC6H4SO3) [Me-BPzTO = 4,6-Bis(4-methylpyrazol-1-yl)-1,3,5-triazin-2-olate] Felipe Gómez-de la Torre, Antonio de la Hoz, Félix A. Jalón, Blanca R. Manzano, Antonio Otero, Ana M. Rodríguez, M. Carmen Rodríguez-Pérez, Aurea Echevarría, and José Elguero pp 6606 - 6614; DOI: 10.1021/ic980307n |
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Synthesis and Characterization of a Family of Systematically Varied Tris(2-pyridyl)methoxymethane Ligands: Copper(I) and Copper(II) Complexes Robert T. Jonas and T. D. P. Stack pp 6615 - 6629; DOI: 10.1021/ic9713487 |
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A Preorganized Siderophore: Thermodynamic and Structural Characterization of Alcaligin and Bisucaberin, Microbial Macrocyclic Dihydroxamate Chelating Agents Zhiguo Hou, Kenneth N. Raymond, Brendon O'Sullivan, Todd W. Esker, and Takayuki Nishio pp 6630 - 6637; DOI: 10.1021/ic9810182 |
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H2GaN3 and Derivatives: A Facile Method to Gallium Nitride Jeff McMurran, Dingguo Dai, K. Balasubramanian, Cory Steffek, J. Kouvetakis, and John L. Hubbard pp 6638 - 6644; DOI: 10.1021/ic981022d |
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Dinuclear Oxovanadium(IV) N-(Phosphonomethyl)iminodiacetate Complexes: Na4[V2O2{(O)2P(O)CH2N(CH2COO)2}2]·10H2O and Na8[V2O2{(O)2P(O)CH2N(CH2COO)2}2]2·16H2O Debbie C. Crans, Feilong Jiang, Oren P. Anderson, and Susie M. Miller pp 6645 - 6655; DOI: 10.1021/ic9808697 |
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Trigonal Bipyramidal M2Ch32- (M = Sn, Pb; Ch = S, Se, Te) and TlMTe33- Anions: Multinuclear Magnetic Resonance, Raman Spectroscopic, and Theoretical Studies, and the X-ray Crystal Structures of (2,2,2-crypt-K+)3TlPbTe33-·2en and (2,2,2-crypt-K+)2Pb2Ch32-·0.5en (Ch = S, Se) Horst Borrmann, Janette Campbell, David A. Dixon, Hélène P. A. Mercier, Ayaaz M. Pirani, and Gary J. Schrobilgen pp 6656 - 6674; DOI: 10.1021/ic980574t |
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The Structure of the Hydrated Gallium(III), Indium(III), and Chromium(III) Ions in Aqueous Solution. A Large Angle X-ray Scattering and EXAFS Study Patric Lindqvist-Reis, Adela Muñoz-Páez, Sofia Díaz-Moreno, Sidhartha Pattanaik, Ingmar Persson, and Magnus Sandström pp 6675 - 6683; DOI: 10.1021/ic980750y |
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Tridentate Coordination Modes of Functionalized Titanocene Thiolates. Crystal Structure of [(5-C5H4SiMe3)Ti(-5:-P-C5H4PPh2)(-SPh)2W(CO)3] Esther Delgado, M. Angeles García, Enrique Gutierrez-Puebla, Elisa Hernández, Noelia Mansilla, and Félix Zamora pp 6684 - 6689; DOI: 10.1021/ic9804972 |
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Lanthanide(III) Complexes of Tripodal N-Donor Ligands: Structural Models for the Species Involved in Solvent Extraction of Actinides(III) Raphaël Wietzke, Marinella Mazzanti, Jean-Marc Latour, Jacques Pécaut, Pierre-Yves Cordier, and Charles Madic pp 6690 - 6697; DOI: 10.1021/ic980192n |
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Trinuclear Lanthanoid Complexes of 1,3,5-Triamino-1,3,5-trideoxy-cis-inositol with a Unique, Sandwich-Type Cage Structure Roman Hedinger, Michele Ghisletta, Kaspar Hegetschweiler, Eva Tóth, André E. Merbach, Roberta Sessoli, Dante Gatteschi, and Volker Gramlich pp 6698 - 6705; DOI: 10.1021/ic980685s |
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Reaction of Octachlorodirhenate with a Redox-Active Tetrathiafulvalene Phosphine Ligand: Spectroscopic, Magnetic, and Structural Characterization of the Unusual Paramagnetic Salt [ReCl2(o-P2)2][Re2Cl6(o-P2)] (o-P2 = o-{P(C6H5)2}2(CH3)2TTF) Calvin E. Uzelmeier, Stuart L. Bartley, Marc Fourmigué, Robin Rogers, Giulio Grandinetti, and Kim R. Dunbar pp 6706 - 6713; DOI: 10.1021/ic9808192 |
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Structural and Magnetic Properties of M(mnt)2 Salts (M = Ni, Pt, Cu) with a Ferrocene-Based Cation, [FcCH2N(CH3)3]+. Interplay between M···M and M···S Intermolecular Interactions Anthony E. Pullen, Christophe Faulmann, Konstantin I. Pokhodnya, Patrick Cassoux, and Madoka Tokumoto pp 6714 - 6720; DOI: 10.1021/ic980876v |
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The Solution Structure of a Copper(II) Compound of a New Cyclic Octapeptide by EPR Spectroscopy and Force Field Calculations Peter Comba, Rodney Cusack, David P. Fairlie, Lawrence R. Gahan, Graeme R. Hanson, Uli Kazmaier, and Anne Ramlow pp 6721 - 6727; DOI: 10.1021/ic9809299 |
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Transition Metal Complexes of Guanidinate Dianions: Reactions between Guanidines and M(NMe2)5 (M = Ta, Nb) Ma K. T. Tin, Glenn P. A. Yap, and Darrin S. Richeson pp 6728 - 6730; DOI: 10.1021/ic980736l |
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An Amide-Linked Ferrocene Dimer, [(CH3CONHC5H4)Fe(C5H4CONHC5H4)Fe(C5H4CONHCH3)]. Formation of Inter- and Intramolecular NH···O=C Hydrogen Bonds Taka-aki Okamura, Keiko Sakauye, Norikazu Ueyama, and Akira Nakamura pp 6731 - 6736; DOI: 10.1021/ic9806939 |
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Synthesis of -Imino Carbonyl Enolato Complexes by Reaction of Nickel(II), Palladium(II), and Copper(II) Acetates with the Enaminodiones (MeOCO)(RCO)CC(R')NH2 (R = Me, OMe; R' = Et, EtOCO) Marino Basato, Umberto Vettori, Augusto C. Veronese, Alfonso Grassi, and Giovanni Valle pp 6737 - 6745; DOI: 10.1021/ic9716114 |
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Synthesis and Characterization of the First Cyclic Monothioether Derivative of 1,2-o-Carborane and Its Reactivity toward Phosphine Transition Metal Complexes Clara Viñas, M. Rosa Cirera, Francesc Teixidor, Raikko Kivekäs, Reijo Sillanpää, and Joan Llibre pp 6746 - 6750; DOI: 10.1021/ic980329+ |
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Novel Square Arrangements in Tetranuclear and Octanuclear Iron(III) Complexes with Asymmetric Iron Environments Created by the Unsymmetric Bridging Ligand N,N,N'-Tris((N-methyl)-2-benzimidazolylmethyl)-N'-methyl-1,3-diamino-2-propanol Joe H. Satcher, Jr., Marilyn M. Olmstead, Michael W. Droege, Sean R. Parkin, Bruce C. Noll, Leopold May, and Alan L. Balch pp 6751 - 6758; DOI: 10.1021/ic9802404 |
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Preparation and Structural Characterization of Nickel(II) Catecholates Christian Brückner, Dana L. Caulder, and Kenneth N. Raymond pp 6759 - 6764; DOI: 10.1021/ic980620p |
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The Large closo-Borane Dianions, BnHn2- (n = 13-17) Are Aromatic, Why Are They Unknown? Paul von Ragué Schleyer, Katayoun Najafian, and Alexander M. Mebel pp 6765 - 6772; DOI: 10.1021/ic980359c |
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Synthesis of Alkynechalcogenolato Complexes of Titanocene(IV) and Samarocene(III) and Formation of a Ti2Ni Trinuclear Cluster [Cp2Ti(-SCCPh)2]2Ni Hiroyasu Sugiyama, Yuji Hayashi, Hiroyuki Kawaguchi, and Kazuyuki Tatsumi pp 6773 - 6779; DOI: 10.1021/ic980901x |
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Enantioselective Sulfoxidation Catalyzed by Vanadium Haloperoxidases Hilda B. ten Brink, Antonin Tuynman, Henk L. Dekker, Wieger Hemrika, Yoshikazu Izumi, Takashi Oshiro, Hans E. Schoemaker, and Ron Wever pp 6780 - 6784; DOI: 10.1021/ic9806075 |
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Model Studies of the Interaction of Vanadium(III) and Oxovanadium(IV/V) with the Carbonyl Amide Oxygen Kalliopi D. Soulti, Anastasios Troganis, Aggelos Papaioannou, Themistoklis A. Kabanos, Anastasios D. Keramidas, Yiannis G. Deligiannakis, Catherine P. Raptopoulou, and Aris Terzis pp 6785 - 6794; DOI: 10.1021/ic9714302 |
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Metal-Metal Bonding in d1d1 and d2d2 Bioctahedral Dimer Systems: A Density Functional Study of Face-Shared M2X93- (M = Ti, Zr, Hf, V, Nb, Ta) Complexes Robert Stranger, John E. McGrady, and Timothy Lovell pp 6795 - 6806; DOI: 10.1021/ic971511y |
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Neutral trans-Dioxorhenium(V) Complexes with the Anionic Tetrakis(pyrazolyl)borate Ligand António Paulo, K. Rajender Reddy, Ângela Domingos, and Isabel Santos pp 6807 - 6813; DOI: 10.1021/ic980422y |
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Mixed-Valence CuI-CuII and Heterodimetallic CuI-MII Bis(carboxylate-bridged) Complexes: Structural, Electrochemical, and Spectroscopic Investigations Daniel D. LeCloux, Roman Davydov, and Stephen J. Lippard pp 6814 - 6826; DOI: 10.1021/ic980763b |
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Oxidation of Alcohols by Hydrogen Peroxide, Catalyzed by Methyltrioxorhenium (MTO): A Hydride Abstraction Timothy H. Zauche and James H. Espenson pp 6827 - 6831; DOI: 10.1021/ic9806784 |
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Macrocyclic Heterodinuclear ZnIIPbII Complexes: Synthesis, Structures, and Hydrolytic Function toward Tris(p-nitrophenyl) Phosphate Masako Yamami, Hideki Furutachi, Takushi Yokoyama, and Hisashi kawapp 6832 - 6838; DOI: 10.1021/ic9804869 |
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Structure of LaMo2O5 Containing Both Isolated Mo6O18 Clusters and Sheets of Fused Triangular Mo3 Clusters Simon J. Hibble, Steven P. Cooper, Alex C. Hannon, Saban Patat, and William H. McCarroll pp 6839 - 6846; DOI: 10.1021/ic980313j |
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Design and Synthesis of New Biomimetic Materials by Sol-Gel: A CuII(histidine)2 Complex Covalently Bonded on a Silica Matrix Maria Louloudi, Yiannis Deligiannakis, and Nick Hadjiliadis pp 6847 - 6851; DOI: 10.1021/ic980665q |
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Syntheses, Structures, FAB Mass Spectra, and Magnetic Properties of Chromium Chalcogenide Cluster Complexes [Cr6Se8(PEt3)6], [Cr6Se8(H)(PEt3)6], and [Cr6S8(H)(PEt3)6] Satoshi Kamiguchi, Hideo Imoto, Taro Saito, and Teiji Chihara pp 6852 - 6857; DOI: 10.1021/ic9807700 |
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Molecular Structures, Vibrational Spectroscopy, and Normal-Mode Analysis of M2(CCR)4(PMe3)4 Dimetallatetraynes. Observation of Strongly Mixed Metal-Metal and Metal-Ligand Vibrational Modes Kevin D. John, Vincent M. Miskowski, Michael A. Vance, Richard F. Dallinger, Louis C. Wang, Steven J. Geib, and Michael D. Hopkins pp 6858 - 6873; DOI: 10.1021/ic980866u |
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Functionalized Rhodium Intercalators for DNA Recognition Robert H. Terbrueggen, Timothy W. Johann, and Jacqueline K. Barton pp 6874 - 6883; DOI: 10.1021/ic980837j |
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Bonding and Geometry of OCF3-, ONF3, and Related Molecules in Terms of the Ligand Close Packing Model Ronald J. Gillespie, Edward A. Robinson, and George L. Heard pp 6884 - 6889; DOI: 10.1021/ic981037b |
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Strong Trans Influence Methoxymethyl Ligand in B12 Cobaloxime and Imine/Oxime Model Complexes: Structural, Spectroscopic, and Molecular Mechanics Investigations Renzo Cini, Scott J. Moore, and Luigi G. Marzilli pp 6890 - 6897; DOI: 10.1021/ic980666i |
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Chirality-Controlling Chelate (CCC) Ligands in Analogues of Platinum Anticancer Agents. Influence of N9 Substituents of Guanine Derivatives (G) on the Distribution of Chiral Conformers of (CCC)PtG2 with CCC = N,N'-Dimethyl-2,3-diaminobutane Luigi G. Marzilli, Francesco P. Intini, Danita Kiser, Hing C. Wong, Susan O. Ano, Patricia A. Marzilli, and Giovanni Natile pp 6898 - 6905; DOI: 10.1021/ic980843f |
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Reaction of the Primary Alane (2,4,6-t-Bu3H2C6AlH2)2 with Nitriles, Isonitriles, and Primary Amines Rudolf J. Wehmschulte and Philip P. Power pp 6906 - 6911; DOI: 10.1021/ic9810992 |
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An Octahedral Template Based on a New Molecular Turn: Synthesis and Structure of a Model Complex and a Reactive, Diphenolic Ligand and Its Metal Complexes Andrew L. Vance, Nathaniel W. Alcock, Joseph A. Heppert, and Daryle H. Busch pp 6912 - 6920; DOI: 10.1021/ic9714201 |
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Structural Comparison of Iron Tetrapolyvanadate Fe2V4O13 and Iron Polyvanadomolybdate Fe2V3.16Mo0.84O13.42: A New Substitution Mechanism of Molybdenum(VI) for Vanadium(V) Xiandong Wang, Kevin R. Heier, Charlotte L. Stern, and Kenneth R. Poeppelmeier pp 6921 - 6927; DOI: 10.1021/ic980942t |
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Pyramidal Inversion at Phosphorus Facilitated by the Presence of Proximate Lewis Acids. Coordination Chemistry of Group 13 Elements with the Macrocyclic Bis(amidophosphine) Ligand [P2N2] ([P2N2] = [PhP(CH2SiMe2NSiMe2CH2)2PPh]) Michael D. Fryzuk, Garth R. Giesbrecht, and Steven J. Rettig pp 6928 - 6934; DOI: 10.1021/ic9805978 |
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B-DNA Binding with Cobalt(III) and Vanadyl(2+) Derivatives of Tetracationic 5,10,15,20-Tetrakis(4-N-methylpyridyl)porphine: Combined CD, Optical, and Electronic MCD Spectra N. Randy Barnes and Anton F. Schreiner pp 6935 - 6938; DOI: 10.1021/ic980349b |
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Synthesis and Stereochemistry of Homoleptic Transition Metal Thiobenzoate Complexes, (Ph4P)[M(SC{O}Ph)3] (M = Mn, Co, and Ni) Rema Devy, Jagadese J. Vittal, and Philip A. W. Dean pp 6939 - 6941; DOI: 10.1021/ic980394j |
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Sulfur Site Iodine Adduct of a Nickel Thiolate Complex Erica J. Lyon, Ghezai Musie, Joseph H. Reibenspies, and Marcetta Y. Darensbourg pp 6942 - 6946; DOI: 10.1021/ic980852o |